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LHS-321723-01.0 Pavement Markings Product Data
Date Printed: 2/2/2021 Product: 882000 Safety Data Sheet Section 1. Identification Product Code:882000 Product Name:TM BC2000 WHT HYD EXT Product Type:Thermoplastic Recommended Use:Traffic Markings Supplied by:Ennis-Flint, Inc. 4161 Piedmont Parkway, Suite 370 Greensboro, NC 27410 T: 800.331.8118 Emergency Telephone:Chemtrec 1-800-424-9300 2. Hazards Identification EMERGENCY OVERVIEW:This product contains a component suspected of causing cancer. However, it is in a non-respirable form and inhalation is unlikely to occur from exposure. This classification is relevant when exposed to dust or powder form only (e.g. sanding, grinding). GHS Classification Carc. 1B Symbol(s) of Product Signal Word Danger GHS HAZARD STATEMENTS Carcinogenicity, category 1B H350 May cause cancer. GHS PRECAUTIONARY STATEMENTS P201 Obtain special instructions before use. P281 Use personal protective equipment as required. P308+P313 IF exposed or concerned: Get medical advice/attention. 3. Composition/Information on Ingredients Chemical Name CAS-No.Wt. %GHS Symbols GHS Statements Calcium Carbonate 1317-65-3 25-50 No Information No Information Glass Oxide; Glass 65997-17-3 25-50 No Information No Information Crystalline Silica, Quartz 14808-60-7 10-25 GHS08 H351 Titanium Dioxide 13463-67-7 2.5-10 No Information No Information Distillates, hydrotreated heavy paraffinic 64742-54-7 1.0-2.5 GHS08 H350 Page 1 / 7 Date Printed: 2/2/2021 Product: 882000 4. First-aid Measures FIRST AID -GENERAL ADVICE:Consult a physician if symptoms persist. FIRST AID -INHALATION:Move to fresh air. FIRST AID -INGESTION:Do NOT induce vomiting. If conscious, rinse mouth and drink plenty of water. Never give anything by mouth to an unconscious person. Consult a physician. FIRST AID -SKIN CONTACT:In case of BURNS, remove patient from heat source. Immediately cool affected skin for as long as possible with cold water. Remove smoldering clothing, including shoes, boots and jewelry unless adhering to skin. Do not remove clothing if adhering to skin. Do not attempt to remove the molten thermoplastic from the skin. Removal could result in severe tissue damage. Cover patient with dry clean sheet. Conduct primary survey. If indicated, transport patient to emergency treatment facility. Wash affected area immediately with soap and plenty of water. Remove contaminated clothing and launder before reuse. Consult a physician if symptoms persist. FIRST AID -EYE CONTACT:Contact with molten materials requires immediate medical assistance. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult a physician if symptoms persist. MOST IMPORTANT SYMPTOMS AND EFFECTS:None under normal processing. NOTES TO PHYSICIAN:None known based on information supplied. 5. Fire-fighting Measures UNUSUAL FIRE AND EXPLOSION HAZARDS:None expected. SPECIAL FIREFIGHTING PROCEDURES:As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. EXTINGUISHING MEDIA:Alcohol Foam, Carbon Dioxide, Dry Chemical, Foam, Water Fog 6. Accidental Release Measures STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:Ensure adequate ventilation. Take up mechanically. Keep in suitable and closed containers for disposal. Avoid dust formation. Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANUP:Allow molten material to cool. Then dispose of according to federal and state regulations. ENVIRONMENTAL PRECAUTIONS:Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. EMERGENCY ADVICE:Under normal usage or contained spills, this material should not pose a significant emergency risk. PERSONAL PRECAUTIONS:Use personal protective equipment. 7. Handling and Storage HANDLING:Ensure adequate ventilation. Avoid breathing vapor, mists or dust. Avoid contact with eyes, skin, and clothing. Wear appropriate personal protective equipment. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Observe good industrial hygiene practices. Avoid dust formation. Fine dust dispersed in air may ignite. Do not reheat product packaged in light metal containers. The light metal containers will not safely support the movement or transfer of the product in a hot, molten form. Do not heat over 260°C/500°F in a closed container. This product when heated to above 260°C/500°F can lead to flashing. Appropriate protective equipment must be worn when mixing and applying this product. The thermoplastic bag can be hazardous when empty, because it can retain product residue. Therefore do not reuse container for food, clothing, or products for human or animal consumption or where skin contact may occur. Always obey hazard warnings and handle containers as if they were full. The meltable bag is compatible with the thermoplastic allowing them to melt and become part of the hot melt mixture at application temperature. STORAGE:Keep container tightly closed in a dry and well-ventilated place. Keep in properly labeled containers. Page 2 / 7 Date Printed: 2/2/2021 Product: 882000 8. Exposure Controls/Personal Protection Ingredients with Occupational Exposure Limits Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING Calcium Carbonate N.E.N.E.15 mg/m3 N.E. Glass Oxide; Glass N.E.N.E.N.E.N.E. Crystalline Silica, Quartz 0.025 mg/m3 N.E.0.05 mg/m3 N.E. Titanium Dioxide 10 mg/m3 N.E.15 mg/m3 N.E. Distillates, hydrotreated heavy paraffinic N.E.N.E.N.E.N.E. Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation Sk = Skin Sensitizer N.E. = Not Established Personal Protection RESPIRATORY PROTECTION:If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. SKIN PROTECTION:Protective gloves/clothing. Use of long sleeved shirts is required when handling molten material. EYE PROTECTION:Safety glasses with side-shields. Use of a faceshield is recommended when handling molten material. OTHER PROTECTIVE EQUIPMENT:Eyewash stations, safety showers, ventilation systems. HYGIENIC PRACTICES:When using, do not eat, drink or smoke. Provide regular cleaning of equipment, work area and clothing. Wash hands before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practice. ENGINEERING CONTROLS:Use in a well ventilated area. 9. Physical and Chemical Properties Physical State:Appearance:White Solid Odor Threshold:Odor:Odorless Not Established pH:Density, g/cm3:1.917 Not Applicable Viscosity:Freeze Point, °C:Not Applicable No Information Partition Coefficient, n-octanol/ water: Solubility in Water:Insoluble Not Applicable Decomposition temperature, °C Not Applicable Explosive Limits, %:Not Determined Not DeterminedBoiling Range, °C:Flash Point, °C:Combustibility:Does not Support Combustion >260Auto-Ignition Temperature, °CEvaporation Rate:N/A >260 Vapor Pressure, mmHg:Vapor Density:Heavier than air Not Applicable (See "Other information" Section for abbreviation legend) 10. Stability and Reactivity REACTIVITY:Stable under normal conditions. Page 3 / 7 Date Printed: 2/2/2021 Product: 882000 STABILITY:Stable under recommended storage conditions. CONDITIONS TO AVOID:Avoid temperatures above 260 °C. Dust formation. Dust may form explosive mixture in air. Heat, flames and sparks. INCOMPATIBILITY:None known based on information supplied. HAZARDOUS DECOMPOSITION PRODUCTS:Carbon oxides. Nitrogen oxides. 11. Toxicological Information Practical Experiences MOST IMPORTANT SYMPTOMS AND EFFECTS:None under normal processing. EFFECT OF OVEREXPOSURE -INHALATION:Inhalation of dust in high concentration may cause irritation of respiratory system. In molten state, the material does not give off fumes that are toxic or injurious to persons or property. However, excessive inhalation of vapors in molten state can cause nose and throat irritation, may cause nervous system depression characterized by headache, dizziness, nausea, staggering gait, confusion and unconsciousness. EFFECT OF OVEREXPOSURE -INGESTION:Ingestion may cause irritation to mucous membranes. EFFECT OF OVEREXPOSURE -SKIN CONTACT:Direct skin contact may cause irritation. The molten product can cause serious burns. EFFECT OF OVEREXPOSURE -EYE CONTACT:Direct eye contact may cause irritation. The molten product can cause serious burns. EFFECT OF OVEREXPOSURE -CHRONIC HAZARDS:This product contains titanium dioxide in a non-respirable form. Inhalation of titanium dioxide is unlikely to occur from exposure to this product. Inhalation exposure to respirable levels of crystalline silica may cause respiratory impairment and lung damage. This product contains crystalline silica (quartz) in a non-respirable form. Inhalation of crystalline silica is unlikely to occur from exposure to this product. Crystalline silica (quartz) has been classified by the International Agency for Research on Cancer (IARC) as a known human carcinogen. CARCINOGENICITY:This product contains one or more substances which are classified by IARC as carcinogenic to humans (Group I), probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B). PRIMARY ROUTE(S) OF ENTRY:Eye Contact, Inhalation, Skin Contact Acute Toxicity Values The acute effects of this product have not been tested. Data on individual components are tabulated below CAS-No.Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 1317-65-3 Calcium Carbonate > 2000 mg/kg > 2000 mg/kg >20001 ppm (Gas/Mist) 65997-17-3 Glass Oxide; Glass >2000 mg/kg > 2000 mg/kg >20001 ppm (Gas/Mist) 14808-60-7 Crystalline Silica, Quartz >2000 mg/kg > 2000 mg/kg >20001 ppm (Gas/Mist) 13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I.>20001 ppm (Gas/Mist) 64742-54-7 Distillates, hydrotreated heavy paraffinic 15000 mg/kg Rat > 2000 mg/kg >20001 ppm (Gas/Mist) N.I. = No Information 12. Ecological Information ECOLOGICAL INFORMATION:The environmental impact of this product has not been fully investigated. Do not contaminate ponds, waterways or ditches with this material. PRESISTENCE AND DEGRADABILITY:No Information BIOACCUMULATIVE POTENTIAL:No Information MOBILITY:No Information OTHER ADVERSE ECOLOGICAL EFFECTS:No Information Page 4 / 7 Date Printed: 2/2/2021 Product: 882000 13. Disposal Information Product DISPOSAL METHOD:This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). Dispose of contents/ container in accordance with the local/regional/national/international regulations. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:Ensure adequate ventilation. Take up mechanically. Keep in suitable and closed containers for disposal. Avoid dust formation. Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry. CONTAMINATED PACKAGING:Dispose of contents/ container in accordance with the local/regional/national/international regulations. 14. Transport Information SPECIAL TRANSPORT PRECAUTIONS:When in use, this product is elevated temperature liquid, n.o.s. (compound pavement marking), UN3257, Hazard Class 9, Packing Group III. Road Transport UN Number:Not Regulated Shipping Name:Not Regulated Transport Hazard Class:Not Regulated Packing Group:Not Applicable ERG No:Not Regulated Sea Transport UN Number:Not Regulated Shipping Name:Not Regulated IMDG Class:Not Regulated Packing Group:Not Applicable EmS-No:Not Regulated Marine Pollutant:Not A Marine Pollutant Air Transport UN Number:Not Regulated Shipping Name:Not Regulated IATA Class:Not Regulated Packing Group:Not Applicable 15. Regulatory Information U.S. Federal Regulations: CERCLA - SARA Hazard Category This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: Carcinogenicity SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Page 5 / 7 Date Printed: 2/2/2021 Product: 882000 No Sara 313 components exist in this product. TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: No TSCA components exist in this product. U.S. State Regulations: NEW JERSEY RIGHT-TO-KNOW: The following materials are hazardous or among the top five components in this product. Chemical Name CAS-No. Calcium Carbonate 1317-65-3 Glass Oxide; Glass 65997-17-3 Crystalline Silica, Quartz 14808-60-7 Petroleum Hydrocarbon Resin 64742-16-1 Titanium Dioxide 13463-67-7 Distillates, hydrotreated heavy paraffinic 64742-54-7 PENNSYLVANIA RIGHT-TO-KNOW The following non-hazardous ingredients are present in the product at greater than 3%. Chemical Name CAS-No. Calcium Carbonate 1317-65-3 Glass Oxide; Glass 65997-17-3 Crystalline Silica, Quartz 14808-60-7 Petroleum Hydrocarbon Resin 64742-16-1 Titanium Dioxide 13463-67-7 Low Density Polyethylene Wax 9002-88-4 Distillates, hydrotreated heavy paraffinic 64742-54-7 CALIFORNIA PROPOSITION 65 CARCINOGENS WARNING Warning: The following ingredients present in the product are known to the state of California to cause Cancer: Chemical Name CAS-No. Crystalline Silica, Quartz 14808-60-7 Titanium Dioxide 13463-67-7 CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS WARNING Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other reproductive hazards. No Proposition 65 Reproductive Toxins exist in this product. International Regulations: As follows - CANADIAN WHMIS: This SDS has been prepared in compliance with Controlled Product Regulations. Page 6 / 7 Date Printed: 2/2/2021 Product: 882000 16. Other Information Revision Date:2/2/2021 Supersedes Date:12/11/2020 Datasheet produced by:Regulatory Department HMIS Ratings: Health:3 Flammability:1 Reactivity:0 Personal Protection:X NFPA Ratings: Health:1 Flammability:1 Reactivity:0 Hazards:N.I. Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined The information on this sheet corresponds to our present knowledge. It is not a specification and it does not guarantee specific properties. The information is intended to provide general guidance as to health and safety based upon our knowledge of the handling, storage, and use of the product. It is not applicable to unusual or non-standard uses of the product where instructions and recommendations are not followed. Any use of the product not in conformance with this SDS or in combination with any other product or process is the responsibility of the user. Page 7 / 7 Page: 1 MATERIAL SAFETY DATA SHEET FOR COATINGS, RESINS & RELATED MATERIALS SECTION I PRODUCT IDENTIFICATION Manufacturer Ennis Paint, Inc. Information Ph: 800-331-8118 P.O. Box 404 Emergency Ph: 800-424-9300 Ennis, Texas 75120 Revised: 11/30/05 Product Class: Thermoplastic Roadmarking Compound Hydrocarbon Type Trade Name: CAS. Number: Ennis Paint Thermoplastic N/A – Formula Mixture HAZARD RATINGS: HTH 1 NONE-EXTREME FIRE 1 0 - 4 REACTIVITY 1 SECTION II HAZARDOUS INGREDIENTS Applies to Leaded Yellow Only Exposure Limits INGREDIENTS CAS # wt % ACGIH/TLV OSHA/PEL Silica Encapsulated Pigment Yellow 34 * 116565-74-3 10.0 MAX Not Established Not Established *Contains 2-10% chrome yellow pigment (encapsulated lead chromate and other lead compounds). As noted in OSHA lead standard, repeated prolonged exposure to lead chromate may cause delayed effects involving the blood, gastrointestinal, nervous and reproductive systems. However, this product contains encapsulated lead chromate, a much safer form. White and lead free yellow products do not contain any hazardous ingredients. SECTION III PHYSICAL DATA BOILING POINT: Not Applicable VAPOR DENSITY: Not Applicable EVAPORATION RATE: Not Applicable VAPOR PRESSURE: Not Applicable APPEARANCE: Solid Powder or Block SOLUBILITY IN WATER: Not Applicable SPECIFIC GRAVITY: 1.70 - 2.20 MELTING POINT: R&B 95-120°C Odor: Odorless SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASHPOINT-COC >500°F LEL: N/A UEL: N/A EXTINQUISHING MEDIA: Water, Dry Chemical, CO2, Foam SPECIAL FIREFIGHTING PROCEDURES: DURING EMERGENCY CONDITIONS, OVEREXPOSURE TO THERMAL DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZZARD. AN APPROVED SELF-CONTAINED BREATHING APPARATUS SHOULD BE WORN. UNUSUAL FIRE & EXPLOSION HAZARDS: WHEN EXPOSEED TO FLAME, EMITS ACRID FUMES. Page: 2 DUST MAY FORM EXPLOSIVE MIXTURE WITH AIR. SECTION V REACTIVITY DATA STABILITY: UNSTABLE ; STABLE HAZARDOUS POLYMERIZATION: MAY OCCUR ; WILL NOT OCCUR INCOMPATIBILITY: Strong Oxidation Agents CONDITIONS TO AVOID: Temperatures Above 500°F, Open Flame. HAZARDOUS DECOMPOSITION PRODUCTS: May include CO, Co2, and Aliphatic Aldehydes. SECTION VI HEALTH HAZARD DATA PERMISSABLE EXPOSURE LEVEL: • SEE SECTION II FOR INFORMATION ABOUT INDIVIDUAL INGREDIENTS. ACUTE EXPOSURE: • INHALATION: OVEREXPOSURE TO NUISANCE DUST CAN LEAD TO DIFFICULITY IN BREATHING AND MAY IRRITATE SKIN, EYES, AND RESPIRATORY SYSTEM. • EYES: POWDER OR DUST MAY CAUSE IRRITATION. • SKIN: MOLTEN MATERIAL CAN CAUSE SERIOUS BODILY BURNS. • INGESTION: NONE KNOWN CHRONIC EXPOSURE: • Inhalation: NO CHRONIC EXPOSURE EFFECTS ARE KNOWN. EMERGENCY AND FIRST AID PROCEDURES: • EYES: FLUSH THOROUGHLY WITH WATER, GET IMMEDIATE MEDICAL ATTENTION IF CONTACT OCCURRED WITH MOLTEN MATERIAL OR IF IRRATION PERSISTS. • SKIN: WASH EXPOSED AREAS WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. IF CONTACT OCCURRED WITH MOLTEN THERMOPLASTIC APPLY WATER OR ICE PACK IMMEDIATELY. DO NOT ATTEMPT TO REMOVE LARGE PATCHES OF AFFIXED THERMOPLASTIC FROM SKIN, SEEK PROMT MEDICAL ATTENTION • INHALATION: MOVE VICTIM AWAY FROM SOURCE OF EXPOSURE AND INTO FRESH AIR IF SYMPTOMS OF OVEREXPOSURE DEVELOP, GET MEDICAL ATTENTION. GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. • INGESTION: IF LARGE AMOUNTS ARE INGESTED, INDUCE VOMITING. SEEK APPROPRIATE MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON SECTION VII SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: • Sweep, Shovel, or Vacuum into container for disposal or reuse. WASTE DISPOSAL METHOD: • Dispose of in accordance with local, state and federal regulations. • Avoid discharge to natural waters. Page: 3 SECTION VIII SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: • WEAR APPROPRIATE, PROPERLY FITTED RESPIRATOR (NIOSH/OSHA APPROVED) DURING APPLICATION. IF APPLICATION IS LIKELY TO EXCEED ACCEPTABLE CRITERIA. SPECIFICALLY A NIOSH APPROVED ORGANIXC VAPOR/DUST FILTRATION TYPE IS RECCOMENDED VENTILATION: • ADEQUATE VENTILATION IS NECESSARY WHEN APPLYING OR MIXING AND EXHAUST WITH PROPER AIRFLOW IS ALWAYS RECOMMENDED. • AVOID ANY DIRECT INHALATION OF HEATED MATERIAL. EYE PROTECTION: • WEAR APPROVE SAFETY FACE SHIELD, THIS WILL HELP PREVENT EYE INJURY. OTHER PROTECTIVE EQUIPMENT: • GLOVES, LONG SLEEVES, HATS AND FACE SHIELDS ARE RECOMMENDED TO PREVENT THE POSSIBILITY OF BURNS. • TRAIN AND EDUCATE EMPLOYEES IN THE SAFE USE OF THE PRODUCT. SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: • PROTECT FROM MOISTURE DAMAGE WITH APPROPIATE COVERINGS • REMOVE ALL INGNITION SOURCES FROM MATERIAL HANDLING, TRANSFER, AND PROCESSSING AREAS. MECHANICAL AND LOCAL EXHAUST SHOULD BE PROVIDED IN UNVENTILATED WORK AREAS. SECTION X ADDITIONAL REGULATORY INFORMATION DOT CLASSIFICATION SOLID STATE, GRANULAR OR BLOCK FORM: NOT DOT REGULATED. DOT PROPER SHIPPING NAME: COMPOUND PAVEMENT MARKING DOT CLASSIFICATION MOLTEN LIQUID STATE, TEMPERATURES ABOVE 100°C , IS DOT REGULATED. DOT PROPER SHIPPING NAME: ELEVATED TEMPERATURE MATERIAL, LIQUID, N.O.S. 9, UN 3257, III. TSCA-U.S. TOXIC SUBSTANCES CONTROL ACT: ALL COMPONENTS OF THIS MIXTURE ARE IN COMPLIANCE WITH THE INVENTORY LISTING REQUIREMENTS OF THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCES INVENTORY. The following applies to Leaded Yellow Only; White and Lead Free Yellow products do not contain lead or chromium SARA TITLE III SECTION 313: THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW ACT OF 1986 AND OF 40 CFR 372: CAS# CHEMICAL NAME PERCENT BY WEIGHT 7440-47-3 Elemental Chromium 1.2 Maximum 7440-92-1 Elemental Lead 5.3 Maximum PROP 65 (CARCINOGEN): WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. CAS# CHEMICAL NAME PERCENT BY WEIGHT Page: 4 7440-47-3 Elemental Chromium 1.2 Maximum 7440-92-1 Elemental Lead 5.3 Maximum PROP 65 (TERATOGEN): WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. CAS# CHEMICAL NAME PERCENT BY WEIGHT 7440-47-3 Elemental Chromium 1.2 Maximum 7440-92-1 Elemental Lead 5.3 Maximum PROP 65 (BOTH CARCINOGEN AND TERATOGEN): WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. CAS# CHEMICAL NAME PERCENT BY WEIGHT 7440-47-3 Elemental Chromium 1.2 Maximum 7440-92-1 Elemental Lead 5.3 Maximum This statement and exact wording is included as required by the State of California. The conclusion that all chromium (IV) and lead compounds have the same toxicological properties is not supported by current toxicological data for lead chromate pigments. SECTION XI MISCELLANEOUS INFORMATION THE INFORMATION OFFERED HEREIN IS, TO THE BEST OF OUR KNOWLEDGE, TRUE AND ACCURATE, BUT ALL RECOMMENDATIONS ARE MADE WITHOUT WARRANTY, EXPRESS OR IMPLIED, SINCE THE CONDITIONS OF USE ARE BEYOND OUR CONTROL, NEITHER ENNIS PAINT, INC., NOR ITS AGENTS SHALL BE LIABLE FOR ANY INJURY, LOSS OR DAMAGE, DIRECT OR CONSEQUENTIAL, ARISING FROM THE USE OR THE INABILITY TO USE THE PRODUCT DESCRIBED HEREIN. NO PERSON IS AUTHORIZED TO MAKE ANY STATEMENT OR RECOMMENDATION NOT CONTAINED IN THE MATERIAL DATA SHEET, AND ANY SUCH STATEMENT OR RECOMMENDATION, IF MADE SHALL NOT BIND THE CORPORATION. 1 Description 3M Connected Roads All Weather Elements (“Elements”) have been designed for use on roadways and highways, primarily as long line pavement markings. They can be used in either new marking applications or as parts of maintenance marking applications. Elements, when used with compatible binders, form markings that are highly visible, day and night, under both dry and wet weather conditions. Table 1. 3M Connected Roads All Weather Elements product family. Series Names Dry White 50 90 Wet White Dry Yellow 51 91 Wet Yellow Dry M White 50M 70M Wet M White Dry M Yellow 51M 71M Wet M Yellow Dry E White 50E 70E Wet E White Dry E Yellow 51E 71E Wet E Yellow Transportation Safety Division 3M™ Connected Roads All Weather Elements Product Bulletin CR AWE January 2022 Replaces Product Bulletin CR AWE Dated May 2019 2 3M™ Connected Roads All Weather Elements January 2022 2 Composite Optic Construction Elements consist of an outer layer of microcrystalline ceramic beads partially embedded into composite cores to provide optimal performance under dry and/or wet conditions. 3 Specifications 3.1 Retroreflectivity Elements, when tested according to the methods below, shall have the minimum wet and dry cup brightness values presented in Table 2. 3.2 Retroreflectivity Measurements 3.2.1 Equipment and Supplies • 8 to 24 ounce (200 to 800 mL) glass jar and lid • No. 30 US mesh 8" (200 mm) sieve or close equivalent •Sieve pan • Sieve lid • 400 mL glass beaker • Glass stir rod or metal spatula • Large glass or plastic funnel (greater than 5 in. / 130 mm top opening) • Balance, accurate to 0.1 gram • Metal or plastic sample weighing pans • Concentrated Simple Green ® All Purpose Cleaner • Drying oven, set to 150 °F (65 °C) • Sample cups - Glass petri dishes, approximately 2 to 4 in. (50 to 100 mm) diameter and at least ½ in. (12 mm) high •RoadVista® 932 retroreflectometer or equivalent conforming to CIE Publication 054.2–2001 and/or ASTM E1709, capable of pointing nearly vertically down onto a sample resting on a horizontal surface with -4.0° entrance angle and 0.2° observation angle • Wash bottle with water and soap solution - 200:1 water to pH neutral household dish-washing detergent (5 g/L) 3.2.2 Sample Preparation 1. Collect a representative sample of Elements. 2. Measure out 100 grams of sample using balance. 3. Place 100 grams sample of Elements in clean glass jar and screw on lid. 4. Shake vigorously by hand for one minute to remove fines. 5. Attach sieve pan to bottom of sieve. 6. Empty jar contents onto the sieve. 7. Place lid on sieve, then swirl and shake sieve and contents for 30 seconds. 8. Remove sieve pan and lid and discard pan contents. 9. Transfer sieve contents into a clean 400 mL glass beaker, using funnel if necessary. 10. Pour or spray Simple Green ® over the Elements until Elements are barely submerged. 11. Swiftly stir submerged Elements with glass rod or spatula for 20 seconds and let stand for 20 minutes. Fill the beaker to at least half way with clean water, then stir for 20 seconds. Table 2. Minimum initial coefficients of retroreflection [cd/lx/m2]. Property/test method Series Dry, Dry E, Dry M Series 50, 50E, 50M Series 90, 70E, 70M Series Wet, Wet E, Wet M Dry Cup Brightness RA, cd/lx/m2 White: 18.6 Yellow: 11.5 White: 7.4 Yellow: 4.6 White: 1.8 Yellow: 1.1 N/A Wet Cup Brightness RA, cd/lx/m2 N/A White: 2.4 Yellow: 1.2 White: 4.2 Yellow: 2.1 White: 6.0 Yellow: 3.0 3 3M™ Connected Roads All Weather Elements January 2022 12. Decant as much liquid from the beaker as possible without pouring out Elements. 13. Refill beaker containing Elements to at least half way with clean water, stir for 20 seconds, then decant as much liquid as possible. Repeat until rinse water is clean and clear (3–5 times). 14. Pour the Elements from the beaker onto the sieve, to remove any excess water, and spread them out evenly on the sieve screen to form a thin layer. Rinse the Elements in the sieve tray with clean water to remove any remaining debris and cleaning solution. Tilt the sieve slightly to allow excess retained water to run out of the sieve. 15. Place the sieve with Elements in the 150 °F (65 °C) drying oven and leave until thoroughly dry (allow at least 30 minutes). 16. Remove sieve and Elements from the oven and allow to cool to room temperature. 17. Transfer enough of the cooled Elements from the sieve to a glass petri dish, using a funnel if necessary, to form an even layer of Elements about ¼ in. (6 mm) deep. 3.2.3 Dry Cup Brightness Test Procedure 1. Calibrate retroreflectometer according to manufacturer's recommendations. 2. Use manufacturer-supplied stabilizing devices to ensure proper alignment of retroreflectometer with the sample in the petri dish. 3. Set the retroreflectometer to take measurements using -4.0° entrance angle and 0.2° observation angle. 4. Place the dish and sample on a flat, level surface. 5. Carefully rest the instrument on the rim of the petri dish with its measurement area positioned over the Elements. 6. Take a measurement and record the RA value in cd/lx/m2. 7. Repeat the procedure for 2 more samples from each batch or lot and report values as the averages of the three samples. 3.2.4 Wet Cup Brightness Test Procedure 1. Calibrate retroreflectometer according to manufacturer's recommendations. 2. Use manufacturer-supplied stabilizing devices to ensure proper alignment of retroreflectometer with the sample in the petri dish. 3. Set the retroreflectometer to take measurements using -4.0° entrance angle and 0.2° observation angle. 4. Place the dish and sample on a flat, level surface. 5. Using the wash bottle, gently flood and cover the Elements in the petri dish with the soap and water solution. Manually press down any Elements that float to ensure a smooth, even liquid surface above the Elements, across the entire petri dish. 6. Carefully rest the instrument on the rim of the petri dish with its measurement area positioned over the Elements. 7. Take a measurement and record the RA value in cd/lx/m2. 8. Repeat the procedure for 2 more samples from each batch or lot and report values as the averages of the three samples. 3.3 Gradation The gradation of Elements shall meet or be within the limits in Table 3. Table 3. Element gradation. US Mesh Micron Mass Percent of Elements Passing ASTM D1921 10 2000 95–100 14 1410 0–40 20 850 0–5 4 3M™ Connected Roads All Weather Elements January 2022 4 Elements Use and Binder Compatibility Table 4 presents the general compatibilities of Elements with several common pavement marking binders. 4.1 Reflective Elements for High Build Waterborne Paint Elements Series Dry, 50, 90, and Wet are generally compatible with paints formulated with Dow® FASTRACK™ HD21-A binder. Since formulations may vary, users should test for ultimate compatibility and performance. Markings should be applied at a target wet thickness of at least 25 mils (0.025 inches). 4.2 Reflective Elements for Thermoplastic Markings Elements Series Dry, 50, 90, and Wet are generally compatible with formulations based on alkyd and hydrocarbon binders with a target thickness greater than 90 mils. At a minimum, these materials should meet AASHTO M249 specifications. Since formulations may vary, users should test for ultimate compatibility and performance. 4.3 Reflective Elements for Epoxy and Polyurea Markings Elements Series Dry E, 50E, 70E, and Wet E are generally compatible with formulations of epoxy and polyurea pavement markings. Since formulations may vary, users should test for ultimate compatibility and performance. 4.4 Reflective Elements for 3M LPM 5000 Markings Elements Series Dry, 50, 90, and Wet are compatible with 3M LPM 5000 markings. Please see 3M Product Bulletin 3M LPM 5000 for further information. 4.5 Reflective Elements for Methyl Methacrylate (MMA) Markings Elements Series Dry M, 50M, 70M, and Wet M are generally compatible with MMA pavement markings. Since formulations may vary, users should test for ultimate compatibility and performance. 5 Installation 5.1 Weather and Pavement Conditions Elements should be applied according to the manufacturers' application guidelines for the appropriate binders. 5.2 Installation Equipment Elements must be installed using a double-drop Element/bead delivery system. The Elements must be installed as the first drop of the two drop system and at a truck speed of no greater than 8 mph to minimize loss, prevent rolling, and ensure adequate sink. Contact 3M Technical Service at 1-800-553-1380 for additional information on modifying existing equipment. Table 4. General compatibilities of 3M Connected Roads All Weather Elements. Binder Target Thickness, final dry/cured (mils, 0.001") Elements series for high dry reflectivity Elements series for balanced wet and dry reflectivity Elements series for high wet reflectivity Elements series for all wet reflectivity High build water-borne paint 18–25+ Dry 50 90 Wet Thermoplastic ≥90 Dry 50 90 Wet 3M LPM 5000 18–25+ Dry 50 90 Wet Epoxy and Polyurea (excluding LPM 5000)18–25+ Dry E 50E 70E Wet E Methyl Methacrylate (MMA)20–150+ Dry M 50M 70M Wet M 5 3M™ Connected Roads All Weather Elements January 2022 5.3 Binder Thickness Elements should be applied at target binder thicknesses according to the guidelines presented in Table 4. Contact 3M Technical Service for product recommendations and additional application information and restrictions. 5.4 Placement of Elements and Beads Elements and accompanying second drop beads should be applied to pavement marking binders such that the Elements and beads do not roll, thus ensuring that their exposed portions are free of binder material. Elements and beads should be embedded (sunk) into binders to a depth of approximately 50% of their diameter. Under- sinking the Elements and beads will result in their premature loss and the optical failure of the marking. Over- sinking the Elements will result in low dry and wet brightnesses. 5.5 Typical Properties Typical average initial retroreflectance values are shown in Table 5. Some variance should be expected across applications, and all values represent initial properties unless otherwise noted. Elements with “E” and “M” designations have been treated to prevent them from over-sinking into the binder and to slow the wicking of the binder onto the Elements. This treatment causes a temporary reduction in retroreflectivity that is regained after exposure to weather and vehicle traffic. Retroreflectivity recovery may take up to 5 weeks, depending on the weather and vehicle traffic levels. Data presented in Table 5 were, therefore, taken after the treatment was cleaned off. Similarly, users should take initial retroreflectivity readings on E and M type Elements after the treatment has been cleaned off by exposure to weather and vehicle traffic. However, if spot checks are required for markings containing “E” or “M” Elements at the time of application, they should only be performed upon fully hardened markings and after the treatment has been manually cleaned off of the Elements. To remove the treatment, soak the line section to be measured with Concentrated Simple Green® All Purpose Cleaner. Let stand for 2 minutes, then rinse clean with water. Blot the line with a clean, dry cotton towel to remove excess water and allow to dry completely before performing dry or wet retroreflectivity tests. Table 6 show typical properties for markings made with Elements. Table 5. Typical average initial coefficients of retroreflected luminancea [mcd/m2/lx]. a. Typical retroreflectivity results represent average performance for smooth pavement surfaces. Results may vary due to differences in pavement type and surface roughness. Initial readings taken of “M” or “E” Elements must be performed after the treatment has been cleaned off of the Elements. Increased Elements drop rate may be necessary to compensate for increased surface area characteristic of rough pavement surfaces. Wet retroreflectivity testing of markings applied in grooved or recessed surfaces is difficult since water pools in recesses. In such cases, consider installing sections of pavement markings for testing on either a smooth section of the pavement surface, or on rigid panels (50 mil aluminum). If markings are applied to panels, allow them to cure, then move them carefully for retroreflectivity testing - make sure to protect the optics when transporting. Property/test method Series Dry, Dry E, Dry M Series 50, 50E, 50M Series 90, 70E, 70M Series Wet, Wet E, Wet M Retroreflectivity, Dry Average ASTM E1710 White: 1250 Yellow: 900 White: 700 Yellow: 525 White: 500 Yellow: 375 N/A Retroreflectivity, Wet Recovery Average ASTM E2177 N/A White: 275 Yellow: 225 White: 375 Yellow: 300 White: 400 Yellow: 325 Retroreflectivity, Wet Continuous Average ASTM E2832 N/A White: 200 Yellow: 150 White: 275 Yellow: 225 White: 300 Yellow: 250 Table 6. Other typical properties of 3M Connected Roads All Weather Elements. Property Test Method Expected Result Index of refraction of ceramic beads ASTM E1967-98 1.89 for Dry, 2.4 for Wet Acid resistance of glass 24-hr exposure of microcrystalline ceramic beads to 1% solution (by weight) sulfuric acid No more than 15% of beads showing distinct opaque surface upon microscopic examination 6 3M™ Connected Roads All Weather Elements January 2022 5.6 Traffic Marking Binder Material The marking binder shall be of quality and type as designated by governing agency. The quality binder shall be thoroughly mixed, homogeneous, and applied to the road surface per manufacturer's specifications. 5.7 3M Connected Roads All Weather Elements The Element type must be selected based on marking binder type, according to the criteria described in Table 4, and the Elements be the same color as the binder. The Elements must be installed using the double-drop Element/bead delivery system, with Elements being the first drop. Contact 3M application engineering for additional installation questions. 5.8 3M Connected Roads All Weather Elements Application Rates Minimum Elements application rates for smooth or densely-packed pavement surfaces are presented in Table 7. The application rates stated provide good initial retroreflectivity and match the longevity, or restripe frequency, of most pavement marking binder systems to which the Elements are installed. More heavily traveled roads will require greater quantities of Elements to achieve similar longevities. Rough pavement surfaces (open-graded mixes, large stone mixes, etc.) can have up to 50% more surface area than smooth surfaces. As a result, rough pavement surfaces require greater quantities of marking materials (binder, Elements, and beads) than smooth surfaces to achieve similar coverages. Table 7. 3M Connected Roads All Weather Elements application rates. Units Minimum for Durable Markings on Smooth Surface Minimum for Temporary Markings on Smooth Surface Pounds per 4-inch lineal foot 0.018 0.009 Pounds per mile, 4-inch width 93 46.5 Grams per 4-inch lineal foot 8 4 Grams per square foot 24 12 Grams per square meter 260 130 Pounds per gallon - 20 mils ~240 ft/gal 4.2 2.1 Pounds per gallon - 25 mils ~ 190 ft/gal 3.4 1.7 Pounds/100 Sq ft 5.3 2.6 Element count per square inch, average 35–40 18–20 7 3M™ Connected Roads All Weather Elements January 2022 5.9 Second Drop Glass Beads A second drop of glass beads is necessary to improve physical characteristics, durabilities of finished markings, and assure expected track-free times. Glass beads usually provide some measure of increased visibility during dry conditions as well. Many different glass bead gradations are currently used for pavement markings. Table 8 presents glass bead gradations appropriate for temporary and durable applications to paint, polyurea, epoxy, 3M LPM 5000, MMA, and thermoplastic. The gradation of the second drop must meet or be within the limits in Table 8. Typical glass bead application rate ranges are shown in Table 9. 5.10 Quality of Second Drop Glass Beads The required glass beads shall have an index of refraction of 1.5 when tested by the immersion method at 25 ºC (77 ºF). The glass beads shall be surface treated for optimal performance with the liquid binder traffic marking. The glass beads shall have a minimum of 70% rounds as measured according to ASTM D1155. The surfaces of the glass beads shall be free of pits and scratches. The glass beads retained on a #40 U.S. mesh sieve (425 microns) shall have a minimum crush strength of 30 pounds, in accordance with ASTM D1213. Table 8. Typical gradations of second drop glass beads. Common bead types with liquid pavement markings Bead gradations - mass percent passing (ASTM D1214) US Mesh Microns Temporary Pavement Markings Durable Pavement Markings AASHTO M247 Type 1 Missouri Specification Type Pa a. A minimum of 15% of the total weight shall be from direct melt glass. All +30 US mesh beads shall be 85% minimum rounds and have a minimum crush strength of 30 lbs. in accordance with ASTM D1213. FP03 718.19 Type 3 18/50 (Utah) Performance Specification 12 1700 100 14 1410 95–100 16 1180 100 80–95 18 1000 10–40 65–80 20 850 95–100 90–97 0–5 25 710 0–2 30 600 75–95 60–87 0–30 40 425 50 300 15–35 0–15 0–5 70 212 0–5 80 180 100 150 0–5 Table 9. Typical glass bead application rates. Binder Type Units High Build Waterborne Paint Polyurea / 3M LPM 5000 Epoxya a. Bead drop rate may be adjusted to achieve adequate track-free time. MMA Thermoplastic Pounds per 4" lineal foot 0.026–0.053 0.033–0.053 0.05–0.0917 0.033–0.053 0.033–0.053 Grams per 4" lineal foot 12–24 15–24 22.7–41.6 15–24 15–24 Pounds per gallon - 20 mils ~240 ft/gal 6.4–12.8 8.0–12.8 12–22 Pounds per gallon - 25 mils ~ 190 ft/gal 5.1–10.2 6.4–10.2 9.5–17.4 Pounds/100 Sq ft 7.94–15.87 9.92–15.87 15–27.5 9.92–15.87 9.92–15.87 Preferred bead type Missouri Type P or 18/50 (Utah) 18/50 (Utah) or FP -3 #718.19 Type 3 8 3M™ Connected Roads All Weather Elements January 2022 6Storage For best results, store Elements, covered and off the ground, in a cool (40–100 ºF, 4–38 ºC), dry area, indoors or outdoors. Use Elements within one year of receipt. Follow binder and glass bead manufacturers' instructions for storage. 7 Health and Safety Information Read all health hazard, precautionary, and first aid statements found in the Safety Data Sheet (“SDS”) and/or product labels of chemicals prior to handling or use. Refer to SDSs for information regarding volatile organic compound (“VOC”) contents of chemical products. Consult local regulations and authorities for possible restrictions on product VOC content and/or VOC emissions. 8 Quality Policy and Warranty Information 8.1 3M Basic Product Warranty 3M has no control over application methods or the quality of the surface to which materials are applied. Therefore, 3M's warranty for Elements shall be limited to the quality of materials supplied. Elements are warranted (“Basic Warranty”) to be free of defects in materials and manufacture at the time of shipment and to meet the specifications stated in this product bulletin. If the Elements are proven not to have met the Basic Warranty on their shipment date, then a buyer's exclusive remedy, and 3M's sole obligation, at 3M's option, will be refund or replacement of the Elements. 8.2 Disclaimer THE 3M WARRANTY IS MADE IN LIEU OF ALL OTHER WARRANTIES OR CONDITIONS, EXPRESS OR IMPLIED, INCLUDING BUT NOT LIMITED TO ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY, OR FITNESS FOR A PARTICULAR PURPOSE, OR ANY IMPLIED WARRANTY ARISING OUT OF A COURSE OF DEALING OR OF PERFORMANCE, CUSTOM, OR USAGE OF TRADE. 8.3 Limitation of Liability Except for the limited remedy stated above, and except where prohibited by law, 3M will not be liable for any loss or damage arising from the use of or the inability to use the Elements or any 3M product, whether direct, indirect, special, incidental, or consequential damages (including but not limited to lost profits, business, or revenue in any way), regardless of the legal theory asserted including warranty, contract, negligence, or strict liability. Before using, the user shall determine the suitability of Elements for his/her intended use and the user assumes all risk and liability whatsoever in connection therewith. 3M assumes no responsibility for any injury, loss, or damage arising out of the use of a product that is not of our manufacture. Where reference is made in our literature to a commercially available product made by another manufacturer (for example, application equipment), it shall be the user's responsibility to ascertain its effectiveness and to take any precautionary measures required for its use, as outlined by the product's manufacturer. 9 Other Product Information Always confirm that you have the most current version of the applicable product bulletin, information folder, or other product information from 3M’s Website at http://www.3M.com/roadsafety. 9 3M™ Connected Roads All Weather Elements January 2022 10 Literature References 3M IF 5.18 Application Guidelines for Pavement Markings in Grooved Pavement Surfaces 3M IF 5.22 All Weather Paint Application Guidelines for Elements and Glass Beads on a High-Build Waterborne Traffic Marking Paint 3M IF 5.23 3M™ Connected Roads All Weather Elements Application Guidelines for 3M Connected Roads All Weather Elements 3M IF 5.24 3M™ All Weather Thermoplastic Pavement Markings Application Guidelines 3M IF 5.28 Liquid Pavement Marking Application Guidelines Series 5000 3M PB AWP All Weather Paint 3M PB AWT All Weather Thermoplastic 3M PB LPM 5000 3M™ Liquid Pavement Marking Series 5000 ASTM Test Methods are available from ASTM International, West Conshohocken, PA. For Information or Assistance Call: 1-800-553-1380 In Canada Call: 1-800-3M HELPS (1-800-364-3577) Internet: http://www.3M.com/roadsafety 3M, and Science. Applied to Life., are trademarks of 3M. Used under license in Canada. All other trademarks are the property of their respective owners. Simple Green is a registered trademark of Sunshine Makers, Inc., RoadVista is a registered trademark of Gamma Scientific Inc. Dow is a registered trademark of DowDuPont. FASTRACK is a trademark of DowDuPont. All other trademarks are the property of their respective owners. 3M assumes no responsibility for any injury, loss, or damage arising out of the use of a product that is not of our manufacture. Where reference is made in literature to a commercially available product, made by another manufacturer, it shall be the user’s responsibility to ascertain the precautionary measures for its use outlined by the manufacturer. Important Notice All statements, technical information and recommendations contained herein are based on tests we believe to be reliable at the time of this publication, but the accuracy or completeness thereof is not guaranteed, and the following is made in lieu of all warranties, or conditions express or implied. Seller's and manufacturer's only obligation shall be to replace such quantity of the product proved to be defective. Neither seller nor manufacturer shall be liable for any injury, loss or damage, direct, indirect, special, or consequential, arising out of the use of or the inability to use the product. Before using, user shall determine the suitability of the product for his/her intended use, and user assumes all risk and liability whatsoever in connection therewith. Statements or recommendations not contained herein shall have no force or effect unless in an agreement signed by officers of seller and manufacturer. Transportation Safety Division 3M Center, Building 0225-04-N-14 St. Paul, MN 55144-1000 USA Phone 1-800-553-1380 Web 3M.com/roadsafety Please recycle. Printed in USA © 3M 2022. All rights reserved. Electronic Only 3M Brownwood Plant 4501 Hwy 377 South Brownwood, TX 76801-5907 325-646-3551 October 12, 2022 Document Received From: Phu Trac Quality Specialist 3M Transportation Safety Division CERTIFICATE OF CONFORMANCE TO: Stripe Rite THIS IS TO CERTIFY THAT THE MATERIAL SHIPPED AS INDICATED HEREIN ALSO COMPLIES TO THE SPECIFICATION LISTED BELOW: MATERIAL: 3MTM All Weather Elements MATERIAL: LOT NO QUANTITY CR AWE SERIES 50 22271ESB1 10 Bags CR AWE SERIES 51 22276ESB5 5 Bags PURCHASE ORDER NO: ELEMENTS DOCUMENT DELIVERY NO: 8072354982 SPECIFICATIONS: 3M Specifications for All Weather Elements