HomeMy WebLinkAboutSWP272704 (2) W
SEDIMENT AND SOIL
CHARACTERIZATION REPORT
Olympic Pipeline
Culvert Replacement Project
Prepared for
R.W. Beck, Inc.
and
City of Renton
April 1998
HERRERA
ENVIRONMENTAL
CONSULTANTS
I
SEDIMENT AND SOIL
CHARACTERIZATION REPORT
Olympic Pipeline
Culvert Replacement Project
Prepared for
R.W. Beck, Inc.
1001 Fourth Avenue, Suite 2500
Seattle, WA 98154
and
City of Renton
Department of Public Works
200 Mill Avenue South
Renton, WA 98055
Prepared by
Herrera Environmental Consultants, Inc.
2200 Sixth Avenue, Suite 601
Seattle, Washington 98121
Telephone: 206/441-9080
April 13, 1998
Olympic Pipeline Culvert Replacement Project
Sediment and Soil Characterization Report
Introduction
The city of Renton is planning improvements to surface water drainage conveyances along SW
23rd Street at Lind Avenue SW. Preliminary drawings of the improvements proposed for the
east side of Lind Avenue are shown in Figure 1. Preliminary drawings of the improvements
proposed for the west side of Lind Avenue are shown in Figure 2. At the time of this
investigation, the planned improvements shown in Figures 1 and 2 were preliminary in nature
and were anticipated to be revised during final design.
It is anticipated that these improvements will require the removal of between 2 and 3 feet of
sediments which have accumulated in two 9-foot high by 14-foot wide culverts located beneath
Lind Avenue on the south side of 23rd Street. Sediments will also be removed from two ponds,
one located at the east end(upstream) and one at the west end(downstream) ends of these
culverts. In addition, two 18-inch culverts located immediately west of the west pond will be
replaced with a 10-foot wide by 4-foot high box culvert. This will require removal of soils in the
vicinity of three existing petroleum pipelines that are owned and used by the Olympic Pipe Line
Company for the transport of refined petroleum products (e.g., gasoline, diesel,jet fuel, and
kerosene).
Sediments and soils planned for removal have been sampled and characterized to determine the
disposal options available. This technical memorandum briefly describes methods of sample
collection and analysis, and presents and discusses the analytical results.
Methods
Two sediment samples and one soil sample were collected on June 4, 1997. One sediment
sample (SD-East) was collected from the sediment surface to a depth of 2 feet at two locations in
the pond adjacent to the east end(upstream) of each 14-by 9-foot culvert (see Figure 1). The
second sediment sample (SD-West)was collected from the sediment surface to a depth of 1 foot
at one location on the west side of the pond adjacent to the west end(downstream) of the 4-by 9-
foot culverts (see Figure 2).
The soil sample (S-1)was collected from five locations within the area proposed for excavation
and replacement of the 18-inch culverts (see Figure 2). At each location, soils were collected at a
depth interval of 3.5 to 4 feet below the ground surface, which is approximately equal to the
depth of the petroleum pipelines and the average depth of the 9-foot deep excavation required for
installation of the box culvert. Soils collected from each of the five locations were composited
into one soil sample (S-1) for analysis.
.ynaw.a.o.�
April 13, 1998 1 Herrera Environmental Consultants
Sediment sample SD-East (Figure 1) was collected with a 2-inch diameter aluminum corer.
Sediment sample SD-West and the soil samples (Figure 2) were collected with a 2.5-inch
diameter stainless steel auger. Each sample was placed in a stainless steel bowl for thorough
mixing with a spoon, and recording of physical characteristics (e.g., color, grain size, and the
presence of unusual characteristics such as a petroleum sheen or odor). Samples were then placed
in appropriate jars provided by the laboratory. The corer, auger, bowl, and spoon were
decontaminated prior to use according to the following procedure:
■ Scrub with phosphate-free detergent
■ Rinse several times with warm tap water
■ Rinse once with 10 percent reagent-grade nitric acid
■ Rinse once with reagent-grade propanol
■ Rinse several times with deionized water.
The three samples were stored with ice in a cooler and delivered to the laboratory with a chain--
of-custody form requesting the following analyses:
■ Washington total petroleum hydrocarbons-diesel (WTPH-D) extended by U.S.
Environmental Protection Agency(U.S. EPA) method 8015 modified
■ Total Resource Conservation and Recovery Act (RCRA) metals by U.S. EPA
methods 6010, 7470, and 7471
■ Toxicity characteristic leaching procedure (TCLP) metals by U.S. EPA
methods 1311, 6010, and 7470
■ Semivolatile organic compounds by U.S. EPA method 8270
■ Organochlorine pesticides and polychlorinated biphenyls (PCBs) by U.S. EPA
method 8081.
The laboratory analyzed the samples as requested according to approved methods and quality
control procedures.
Results and Discussion
The sediment samples were described as dark brown organic silt underlain by gray silt. The
surface organic layer was approximately 1.5 feet thick in sample SD-East, and 0.5 feet thick in
sample SD-West. Sample SD-West exhibited an oil sheen and a strong petroleum odor similar to
diesel fuel. Sample SD-East did not exhibit a presence of petroleum. Soil sample S-1 was
described as gray silt, and did not exhibit the presence of petroleum. Laboratory tests of moisture
content indicate that the sediment samples were approximately 30 percent water and the soil
sample was approximately 25 percent water.
April 13, 1998 2 Herrera Environmental Consultants
M
The laboratory reports and chain-of-custody records are provided in Appendix A. The laboratory
reports include quality control data which were briefly reviewed and found acceptable. The
analytical results are presented in Table 1.
The analytical results indicate low concentrations of contaminants with the exception of high
hydrocarbon concentrations in sediment sample SD-West (i.e., 210 mg/kg for diesel range
hydrocarbons and 290 mg/kg for motor oil hydrocarbons). The results of all other analyses
indicated contaminant concentrations which are less than the Model Toxics Control Act (MTCA)
cleanup levels (Table 2) and recommended end use criteria for petroleum-contaminated soils
(Table 3). In addition, all analytical results are less than dangerous waste criteria for toxic
constituents (Table 4).
These results indicate that sediment removed from the pond located west of the 14-by 9-foot
culverts must be either treated for petroleum contamination (e.g., at a permitted facility such as
Holnam, Inc. in Seattle or TPS Technologies, Inc. in Tacoma) or disposed at a municipal landfill
(e.g., Cedar Hills landfill). These results also indicate that other excavated sediments and soils
may be appropriately disposed on land without treatment.
Likely sources of petroleum in the pond sediments include petroleum in stormwater runoff,
spills, or discharges of petroleum products near the site. Leakage from the petroleum pipelines
does not appear to be a source because the pipelines are not used to transport motor oil, and
refined petroleum products such as diesel were not detected in the soil sample collected adjacent
to the pipelines. Additional monitoring could be conducted prior to or during excavation of pond
sediments to further characterize the extent of petroleum contamination and disposal
requirements.
wp4lJNpxdrrp.dcr
April 13, 1998 3 Herrera Environmental Consultants
16.4
ENTERLINE MONUM T :.::.:.....:.
EL'121.32 (PIN INSID A: � � SDMH NO 1
MONUMENT CASE) / /.....•. ..............
IE 11.47 BOUNDARY OF WETLAND
rV
_ \
FO —^ �,\ F;?3FR : nE
PROPOSED 30` CULVERT
�....-•--OA%'.'rid•;
EXCAVATE 2'-3'... TE - -
4' WIDE x 8'?HIGH CULVERT ' ! ! '� '...
:::WITHIN THIS AREA
REMOVE SILT IN CULVERT ; - -
____. _.._... »...._.»»_f.... _. ..:.... BOUNDARY OF WETLAND
........../..
1
IE 6.5
I `
_.. _. ..........:. 6.3f_. ...-_..............._. i..._. I
�14' WIDE x 9' HIGH CULVERT \
EMOVE SILT IN CULVERT
I �
e.05
X
� f
f
L { i
7 t
0
Legend
0
6
N
Locations of sediment sample SD-East(composite depth 0 to 2 feet)
Scale: 1,inch equals 30 feet
o Datum:NAVD88
Figure 1. Sediment sampling locations east of Lind Avenue SW in the city of Renton for
the Olympic Pipeline Culvert Replacement Project.
J6.4 e
WETLAND IMP�AC'C AREX—.... _...___-....___._..._..
l
2111-4" CULE1"T'va`•.
I WING µTALL ITIP
%1 i'-
REMOVE;EXISTING 18' CULVERTS
IE 7.1 -1�8
,`'tea•�;-.' � ..., .. \ �� lQ
:k
'.BOUNDARY OF WETLAND...........:...........
...................
10' WOE x 3' HIGH CULVERT �
.: ''OR 10 x 4 ALTERNATIVE : IE 7.2
( ) .
i
HANG WALL.:
l '
-••�•••''- :v i •i tt
.:.:.:I •r i i i
EXCAVATE 2'-3' WITHIN
,f
j:';;:' - THIS AREA (WETLANb
1.....{ —
=f IMPACT AREA) ',
: .:
wf
; :'' I - i l r
( :; :.:!BOUNDARY_
f ?; ^ OF WETLAND...'
v[ l
:/ r ..._.._....
x : �W0 9!xt4
w atv
'.....
�:'•' ram•
.`.'.
.................'..'.'.'. .....
..........................................__....»..._._.__..__.
...—....._ .._....._—.._........_.__
{(� r
� f
$ Legend
0
Location of sediment sample SD-West(composite depth 0 to 1 foot)
g Locations of soil sample S-1 (composite depth 3.5 to 4 feet)
Scale: 1 inch equals 30 feet
0
Datum: NAVD88
Figure 2. Sediment and soil sampling locations west of Lind Avenue SW in the city of
Renton for the Olympic Pipeline Culvert Replacement Project.
Table 1. Analytical results of sediment and soil samples collected for the
Olympic Pipeline Culvert Replacement Project.
Sediment Sediment Soil
Sample Sample Sample
SD-East SD-West S-1
Petroleum Hydrocarbons(mg/kg dry weight)
Diesel Range Hydrocarbons 16 210 6.8 U
Motor Oil 58 290 26
Total Metals(mg/kg dry weight)
Arsenic 7 U 6 U 6 U
Barium 64.6 63 75.3
Cadmium 0.6 0.3 0.2 U
Chromium 29.9 32.2 33.1
Lead 11 10 10
Mercury 0.07 U 0.06 U 0.05 U
Selenium 7 U 7 6 U
Silver 0.4 U 0.4 U 0.3 U
TCLP Metals(mg/L)
Arsenic 0.05 U 0.05 U 0.05 U
Barium 0.250 B 0.272 B 0.580 B
Cadmium 0.002 U 0.002 0.002 U
Chromium 0.005 U 0.005 U 0.005 U
Lead 0.02 U 0.02 U 0.02 U
Mercury 0.0001 U 0.0001 U 0.0001 U
Selenium 0.05 U 0.05 U 0.05 U
Silver 0.003 U 0.003 U 0.003 U
Semivolatile Organic Compounds(ug/kg dry weight)
Phenol 180 U 190 U 180 U
Bis-(2-Chloroethyl)Ether 180 U 190 U 180 U
2-Chlorophenol 90 U 94 U 88 U
1,3-Dichlorobenzene 90 U 94 U 88 U
1,4-Dichlorobenzene 90 U 94 U 88 U
Benzyl Alcohol 450 U 470 U 440 U
1,2-Dichlorobenzene 90 U 94 U 88 U
2-Methylphenol 180 U 190 U 180 U
2,2'-Oxybis(1-Chloropropane) 90 U 94 U 88 U
4-Methylphenol 90 U 94 U 88 U
N-Nitroso-Di-N-Propylamine 180 U 190 U 180 U
Hexachloroethane 180 U 190 U 180 U
Nitrobenzene 90 U 94 U 88 U
Isophorone 90 U 94 U 88 U
2-Nitrophenol 450 U 470 U 440 U
2,4-Dimethylphenol 270 U 280 U 260 U
Benzoic Acid 900 U 940 U 880 U
bis(2-Chloroethoxy)Methane 90 U 94 U 88 U
2,4-Dichlorophenol 270 U 280 U 260 U
p9seddat.xls
April 13, 1998 Herrera Environmental Consultants
Table 1. Analytical results of sediment and soil samples collected for the
Olympic Pipeline Culvert Replacement Project (continued).
Sediment Sediment Soil
Sample Sample Sample
SD-East SD-West S-1
Semivolatile Organic Compounds(ug/kg dry weight)(continued)
1,2,4-Trichlorobenzene 90 U 94 U 88 U
Naphthalene 90 U 94 U 88 U
4-Chloroaniline 270 U 280 U 260 U
Hexachlorobutadiene 180 U 190 U 180 U
4-Chloro-3-methylphenol 180 U 190 U 180 U
2-Methylnaphthalene 90 U 94 U 88 U
Hexachlorocyclopentadiene 450 U 470 U 440 U
2,4,6-Trichlorophenol 450 U 470 U 440 U
2,4,5-Trichlorophenol 450 U 470 U 440 U
2-Chloronaphthalene 90 U 94 U 88 U
2-Nitroaniline 450 U 470 U 440 U
Dimethylphthalate 90 U 94 U 88 U
Acenaphthylene 90 U 94 U 88 U
3-Nitroaniline 540 U 560 U 530 U
Acenaphthene 90 U 94 U 88 U
2,4-Dinitrophenol 900 U 940 U 880 U
4-Nitrophenol 450 U 470 U 440 U
Dibenzofuran 90 U 94 U 88 U
2,6-Dinitrotoluene 450 U 470 U 440 U
2,4-Dinitrotoluene 450 U 470 U 440 U
Diethylphthalate 90 U 94 U 88 U
4-Chlorophenyl-phenylether 90 U 94 U 88 U
Fluorene 90 U 94 U 88 U
4-Nitroaniline 450 U 470 U 440 U
4,6-Dinitro-2-Methylphenol 900 U 940 U 880 U
N-Nitrosodiphenylamine 90 U 94 U 88 U
4-Bromophenyl-phenylether 90 U 94 U 88 U
Hexachlorobenzene 90 U 94 U 88 U
Pentachlorophenol 450 U 470 U 440 U
Phenanthrene 90 U 94 U 88 U
Carbazole 90 U 94 U 88 U
Anthracene 90 U 94 U 88 U
Di-n-Butylphthalate 90 U 94 U 88 U
Fluoranthene 90 U 190 88 U
Pyrene 90 U 190 88 U
Butylbenzylphthalate 90 U 94 U 88 U
3,3'-Dichlorobenzidine 450 U 470 U 440 U
B enzo(a)anthracene 90 U 94 U 88 U
bis(2-Ethylhexyl)phthalate 290 B 750 B 100 B
Chrysene 90 U 130 88 U
Di-n-Octyl phthalate 90 U 94 U 88 U
Benzo(b)fluoranthene 90 U 110 88 U
Benzo(k)fluoranthene 90 U 97 88 U
p9seddat.xis
April 13, 1998 Herrera Environmental Consultants
Table 1. Analytical results of sediment and soil samples collected for the
Olympic Pipeline Culvert Replacement Project (continued).
Sediment Sediment Soil
Sample Sample Sample
SD-East SD-West S-1
Semivolatile Organic Compounds(ug/kg dry weight)(continued)
Benzo(a)pyrene 90 U 94 U 88 U
Indeno(1,2,3-cd)pyrene 90 U 94 U 88 U
Dibenz(a,h)anthracene 90 U 94 U 88 U
Benzo(g,h,i)perylene 90 U 94 U 88 U
Pesticides/PCBs(ug/kg dry weight)
alpha-BHC 2.3 U 2.4 U 2.3 U
beta-BHC 2.3 U 2.4 U 2.3 U
delta-BHC 5.3 Y 2.4 U 2.3 U
gamma-BHC(Lindane) 2.3 U 2.4 U 2.3 U
Heptachlor 2.3 U 2.4 U 2.3 U
Aldrin 2.3 U 2.4 U 2.3 U
Heptachlor Epoxide 2.3 U 2.4 U 2.3 U
Endosulfan I 2.3 U 2.4 U 2.3 U
Dieldrin 4.5 U 4.8 U 4.5 U
4,4'-DDE 4.5 U 4.8 U 4.5 U
Endrin 4.5 U 4.8 U 4.5 U
Endosulfan II 4.5 U 4.8 U 4.5 U
4,4'-DDD 4.5 U 4.8 U 4.5 U
Endosulfan Sulfate 4.5 U 4.8 U 4.5 U
4,4'-DDT 4.5 U 4.8 U 4.5 U
Methoxychlor 23 U 24 U 23 U
Endrin Ketone 4.5 U 4.8 U 4.5 U
Endrin Aldehyde 4.5 U 4.8 U 4.5 U
gamma Chlordane 2.3 U 2.4 U 2.3 U
alpha Chlordane 2.3 U 2.4 U 2.3 U
Toxaphene 230 U 240 U 230 U
Aroclor 1016 45 U 48 U 45 U
Aroclor1242 45 U 48 U 45 U
Aroclor1248 45 U 48 U 45 U
Aroclor1254 45 U 48 U 45 U
Aroclor 1260 45 U 48 U 45 U
Data qualifier definitions:
U Indicates compound was undetected at the listed concentration.
B Indicates possible/probable blank contamination. Flagged when the analyte is detected
in the sample as well as the method blank.
Y Analyte may be present at or below the listed concentration,but in the opinion of the
analyst confirmation was inadequate.
p9seddat.x1s
April 13, 1998 Herrera Environmental Consultants
Table 2. Model Toxics Control Act (MTCA) cleanup levels for soils.
Hazardous Substance Method A Cleanup Level Method A Cleanup Level
(residential)(mg/kg) (industrial)(mg/kg)
Arsenic 20.0 200.0
Benzene 0.5 0.5
Cadmium 2.0 10.0
Chromium 100.0 500.0
DDT 1.0 5.0
Ethylbenzene 20.0 20.0
Ethylene dibromide 0.001 0.001
Lead 250.0 1,000.0
Lindane 1.0 20.0
Methylene chloride 0.5 0.5
Mercury(inorganic) 1.0 1.0
PAHs(carcinogenic) 1.0 20.0
PCB mixtures 1.0 10.0
Tetrachloroethylene 0.5 0.5
Toluene 40.0 40.0
TPH(gasoline) 100.0 100.0
TPH(diesel) 200.0 200.0
TPH(other) 200.0 200.0
1,1,1 Trichloroethane 20.0 20.0
Trichloroethylene 0.5 0.5
Xylenes 20.0 20.0
a Caution on misusing method A tables. Method A tables have been developed for specific purposes. They are
intended to provide conservative cleanup levels for sites undergoing routine cleanup actions or those sites with
relatively few hazardous substances. The tables may not be appropriate for defining cleanup levels at other
sites. For these reasons,the values in these tables should not automatically be used to define cleanup levels that
must be met for financial, real estate, insurance coverage or placement, or similar transactions or purposes.
Exceedances of the values in these tables do not necessarily trigger requirements for cleanup action under
WAC 173-340.
Source: WAC 173-340.
April 13, 1998 9 Herrera Environmental Consultants
Table 3. Recommended end use criteria for petroleum-contaminated soils'.
Analytical Soil Class(ppm)
Analyte Method 1 2 3 4
Heavy fuel WTPH-418.1 <60 60-200 200-2,000 >2,000
hydrocarbons mod.
(C24-C30)
Diesel WTPH-D <25 25-200 200-500 >500
(C 12-C24)
Gasoline WTPH-G <5 5-100 100-250 >250
(C6-C 12)
Benzene 8020 <0.005 0.005-0.5 50.5 >0.5
Ethylbenzene 8020 <0.005 0.005-20 :520 >20
Toluene 8020 <0.005 0.005-40 :540 >40
Xylenes(total) 8020 <0.005 0.005-20 :520 >20
'Treatment is recommended for all class 3 and 4 soils.
Class 1 soil uses:
Any use which will not cause threat to human health or the environment
Class 2 soil uses:
Backfill at the cleanup site
Fill in commercial or industrial areas
Cover or fill in permitted landfills
Road subgrade or other road construction fill
Fill in or near wetlands, surface water, ground water, drinking water wells, or utility trenches is not
recommended. Use as residential topsoil is also not recommended.
Class 3 soil uses:
Treatment
Disposal at the original site(no solid waste disposal permit needed)
Road construction(no solid waste disposal permit needed)
Use or disposal in permitted municipal landfills
Permitted as a new petroleum contaminated soil(PCS)landfill
(An evaluation should be made to ensure that disposal will not cause a threat to human health or the
environment,e.g.,use near water bodies).
Class 4 soil uses:
Treatment
Disposal in a permitted municipal landfill
Permitted as a new PCS landfill
Source:
Guidance for Remediation of Petroleum Contaminated Soils, Washington State Department of Ecology Toxics
Cleanup Program,April 1994.
.pMJ6gmimvdar
April 13, 1998 10 Herrera Environmental Consultants
Table 4. Dangerous waste criteria for constituents analyzed by the toxicity characteristic
leaching procedure (TCLP).
Toxic Constituent Maximum Extract Maximum Waste
Concentration(mg/L) Concentration'(mg/kg)
Arsenic 5.0 100
Barium 100.0 2,000
Benzene 0.5 10
Cadmium 1.0 20
Carbon tetrachloride 0.5 10
Chlordane 0.03 0.6
Chlorobenzene 100.0 2,000
Chloroform 6.0 120
Chromium 5.0 100
o-Cresol 200.0 4,000
m-Cresol 200.0 4,000
p-Cresol 200.0 4,000
Cresol 200.0 4,000
2,4-D 10.0 200
1,4-Dichlorobenzene 7.5 150
1,2-Dichloroethane 0.5 10
1,1-Dichloroethylene 0.7 14
2,4-Dinitrotoluene 0.13 2.6
Endrin 0.02 0.4
Heptachlor(and its epoxide) 0.008 0.16
Hexachlorobenzene 0.13 2.6
Hexachloro-1,3-butadiene 0.5 10
Hexachloroethane 3.0 60
Lead 5.0 100
Lindane 0.4 8
Mercury 0.2 4
Methoxychlor 10.0 200
Methyl ethyl ketone 200.0 4,000
Nitrobenzene 2.0 40
Pentachlorophenol 100.0 2,000
Pyridine 5.0 100
Selenium 1.0 20
Silver 5.0 100
Tetrachloroethylene 0.7 14
Toxaphene 0.5 10
Trichloroethylene 0.5 10
2,4,5-Trichlorophenol 400.0 8,000
2,4,6-Trichlorophenol 2.0 40
2,4,5-TP(Silvex) 1.0 20
Vinyl chloride 0.2 4
a Maximum waste concentration is based on wet weight assuming all of the constituent is extractable,which
is a worst-case assumption used when results of the toxicity characteristic leaching procedure are not available.
Source: WAC 173-303
April 13, 1998 11 Herrera Environmental Consultants
APPENDIX A
Laboratory Report
Analytical Resources, Incorporated
Analytical Chemists and Consultants ,
27 June 1997
Rob Zisette
Herrera Environmental Consultants, Inc.
2200 Sixth Avenue, Suite 601
Seattle,WA 98121-1820
RE: Project: P9 Sediment
ARI Jobs: S739
Dear Rob:
Please find enclosed sample custody records and analytical results for the above
referenced project. Three sediment samples were received in good condition on
June 4, 1997.
The semivolatile organics method blank showed a trace concentration of bis (2-
ethylhexyl) phthalate. This analyte is a common lab contaminant. All sample
concentrations of bis (2-ethylhexyl) phthalate have been flagged with a "B" qualifier.
The TCLP metals method blank showed a trace concentration of barium. We have
determined that low levels of barium leach out of the filters that we use for TCLP
extract filtration. As the barium levels in the samples and in the blank are well below
the TCLP regulatory level of 100 mg/L, no corrective action was necessary.
Copies of the reports and all associated raw data will be kept on file at ARI. If you
have any questions or require additional information, please contact me at your
convenience.
Sincerely,
ANALYTICAL RESOURCES, INC.
;;�<Z
Jeff J. Reitan
Project Manager
jeff@arilabs.com
JJR/kg
enclosure '
11997
i
333 Ninth Avenue North • Seattle WA 98109-5187 • 206-621-6490 • 206-621-7523 fax
Chain of Custody Record & Date: Analytical Resources, Incorporated
Analytical Chemist and Consultants
Laboratory Analysis Request Page of 400 Ninth Avenue North
Number of coolers: Seattle, WA 98109-4708
ARI Client: V Phone#: 7 j �aVb Cooler Temp: (206) 621-6490
Rad. Survey: (206) 621-7523 (Fax)
Client Contact: O i al*is Requir Notes/Comments
Client Project ID:
Samplers: c/Vl G
No Lab %P q� -`�
Sample ID Date Time Matx Cont ID
l
1
2 - bjV5F ��a s A x x X
3 S� t 3 6 X X X
4
5
6
7
ARI Project No Relinquished by:,01 Relinquished by: Relinquished by:
(Signature (Signature) (Signature)
Comments/Special Instru tions: Printed Nam Printed Name: Printed Name:
Company-
L�� Company: Company:
Date-((�� Time: Date: Time: Date: Time:
Received b Received by: Received by:
(Signatur �it.,Upti? (Signature) (Signature)
Pri ed m - / Printed Name: Printed Name:
r o o
Compan Company: Company:
2.�
Date: Time: Date: Time: Date: Time:
9� /S �' �
Limits of Liability: ARI will perform all requested services in accordance with appropriate methodology following Standard Operating Procedures and our Quality Assurance Program. This program
meets standards for the industry. The total liability of ARI, its officers,agents,employees,or successors,arising out of or in connection with the requested services,shall not exceed the invoiced amount
for said services. The acceptance by the client of a proposal for services by ARI releases ARI from any liability in excess thereof,not withstanding any provision to the contrary in any contract,purchase
order or co-signed agreement between ARI and the client.
ANALYTICAL
RESOURCES
INCORPORATED
TOTAL DIESEL RANGE HYDROCARBONS
WA TPHd Range C12 to C24 by GC/FID
and Motor Oil
LIMS ID: 97-9024 QC Report No: S739-Herrera Environmental Consultant
Matrix: Soil Project: P9 Sed
Data Release Authorized: i 06/OS/97
Reported: 06/20/97
Date Dilution Diesel *HC Motor Oil Surrogate
Lab ID Sample ID Analyzed Factor Range ID Range Recovery
S739MB Method Blank 06/12/97 1:1 5.0 U --- 10 U 110%
S739A S-1 06/12/97 1:1 6.8 U NO 26 109%
S739B SD-West 06/12/97 1:1 210 NO 290 10896
S739C SD-East 06/12/97 1:1 16 NO 58 110%
Values reported in ppm (mg/kg) on a dry weight basis.
Surrogate is Methyl-Arachidate.
* ID indicates, in the opinion of the analyst, the petroleum product with the best pattern
match. 'NO' indicates that there was not a good match for any of the requested products.
Diesel quantitation on total peaks in the range from C12 to C24.
Motor Oil quantitation on total peaks in the range from C24 to C38.
Data Qualifiers
U Compound not detected at the given detection limit.
E Value detected above linear range of instrument. Dilution required.
J Indicates an estimated value below the calculated detection limit.
S No value reported due to saturation of the detector. Dilution required.
D Indicates the surrogate was not detected because of dilution of the extract.
E Indicates a value above the linear range of the detector. Dilution required.
NR Indicates no recovery due to matrix interference.
FORM-1 WA TPHD
ANALYTICAL
RESOURCES
TOTAL DIESEL RANGE HYDROCARBONS INCORPORATED
WA TPHd Range C12 to C24 by GC/FID
Lab Sample ID: S739SB QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9024 Project: P9 Sed
Matrix: Soil
Data Release Authorized:
Reported: 06/20/97
LABORATORY CONTROL SAMPLE RECOVERY REPORT
Date extracted: 06/10/97
Date analyzed: 06/12/97
SPIRE SPIRE $
CONSTITUENT FOUND ADDED RECOVERY
Diesel Range Hydrocarbons 87.6 100 87.6%-
TPHd Surrogate Recovery
Methylarachidate 99.8%
Values reported in ppm (mg/kg) on a dry weight basis.
FORM-III
ANALYTICAL
TOTAL DIESEL RANGE HYDROCARBONS RESOURCES
INCORPORATED
WA TPHd Range C12 to C24 by GC/FID
Sample No: SD-East
Lab Sample ID: S739C QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9026 Project: P9 Sed
Matrix: Soil
Dat R�ived- 06 05/97
Data Release Authorized:
Reported: 06/20/97
MATRIX SPIRE/SPIRE DUPLICATE RECOVERY
Date extracted: 06/10/97
Date analyzed: 06/12/97
SAMPLE SPIRE SPIRE _k
CONSTITUENT VALUE VALUE ADDED RECOVERY RPD
MATRIX SPIKE
Diesel Range Hydrocarbons 16.0 124 136 79.4k
MATRIX SPIKE DUPLICATE
Diesel Range Hydrocarbons 16.0 146 136 95.6% 18.5%
TPHd Surrogate Recovery
Matrix Spike Methylarachidate 11216
MS Duplicate Methylarachidate 11716
Values reported in ppm (mg/kg) on a dry weight basis.
FORM-III
ANALYTICAL
RESOURCES
INCORPORATED
TOTAL DIESEL HYDROCARBONS COMPOUND SUMMARY
Matrix: Soil QC Report No: S739
LIMS ID Lab ID Client ID McArach TOT OUT
97-9024MB 061297MB Method Blank 110$ 0
97-9024LC 061297LC Lab Control 100%- 0
97-9024 S739A S-1 109%. 0
97-9025 S739B SD-West 108% 0
97-9026 S739C SD-East 110% 0
97-9026 S739C-MS SD-East-MS 112$ 0
97-9026 S739C-MSD SD-East-MSD 117t 0
Control Sample
QC LIMITS QC LIMITS
(MeArach) = Methylarachidate (50-150) (41-158)
# Column to be used to flag recovery values
* Values outside of required QC limits
D System Monitoring Compound diluted out
Page 1 for S739
FORM-II TPH-D
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET
Semivolatiles by GC/MS Sample No: S-1
Page 1 of 2
Lab Sample ID: S739A QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9024 Project: P9 Sed
Matrix: Soil
Data Release Authorized: Date Sampled: 06/04/97
Reported: 06/23/97 Date Received: 06/05/97
Date extracted: 06/11/97 Sample Amount: 22.8 g-dry-wt
Date analyzed: 06/13/97 Final Extract Volume: 2.0 mL
Instrument: finn8 Dilution Factor: 1:1
GPC Cleanup: NO Percent Moisture: 26.3%
PH: 6.0
CAS Number Analyte ug/kg
108-95-2 Phenol 180 U
111-44-4 Bis- (2-Chloroethyl) Ether 180 U
95-57-8 2-Chlorophenol 88 U
541-73-1 1,3-Dichlorobenzene 88 U
106-46-7 1,4-Dichlorobenzene 88 U
100-51-6 Benzyl Alcohol 440 U
95-50-1 1,2-Dichlorobenzene 88 U
95-48-7 2-Methylphenol 180 U
108-60-1 2,21-Oxybis(1-Chloropropane) 88 U
106-44-5 4-Methylphenol 88 U
621-64-7 N-Nitroso-Di-N-Propylamine 180 U
67-72-1 Hexachloroethane 180 U
98-95-3 Nitrobenzene 88 U
78-59-1 Isophorone 88 U
88-75-5 2-Nitrophenol 440 U
105-67-9 2,4-Dimethylphenol 260 U
65-85-0 Benzoic Acid 880 U
111-91-1 bis(2-Chloroethoxy) Methane 88 U
120-83-2 2,4-Dichlorophenol 260 U
120-82-1 1,2,4-Trichlorobenzene 88 U
91-20-3 Naphthalene 88 U
106-47-8 4-Chloroaniline 260 U
87-68-3 Hexachlorobutadiene 180 U
59-50-7 4-Chloro-3-methylphenol 180 U
91-57-6 2-Methylnaphthalene 88 U
77-47-4 Hexachlorocyclopentadiene 440 U
88-06-2 2,4,6-Trichlorophenol 440 U
95-95-4 2,4,5-Trichlorophenol 440 U
91-58-7 2-Chloronaphthalene 88 U
88-74-4 2-Nitroaniline 440 U
131-11-3 Dimethylphthalate 88 U
208-96-8 Acenaphthylene 88 U
99-09-2 3-Nitroaniline 530 U
83-32-9 Acenaphthene 88 U
51-28-5 2,4-Dinitrophenol 880 U
100-02-7 4-Nitrophenol 440 U
132-64-9 Dibenzofuran 88 U
606-20-2 2,6-Dinitrotoluene 440 U
FORM-1
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET
Semivolatiles by GC/MS Sample No: S-1
Page 2 of 2
Lab Sample ID: S739A QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9024 Project: P9 Sed
Matrix: Soil
Data Release Authorized:ly Date Sampled: 06/04/97
Reported: 06/23/97 Date Received: 06/05/97
Date extracted: 06/11/97 Sample Amount: 22.8 g-dry-wt
Date analyzed: 06/13/97 Final Extract Volume: 2.0 mL
Instrument: finn8 Dilution Factor: 1:1
GPC Cleanup: NO Percent Moisture: 26.3k
pH: 6.0
CAS Number Analyte ug/kg
121-14-2 2,4-Dinitrotoluene 440 U
84-66-2 Diethylphthalate 88 U
7005-72-3 4-Chlorophenyl-phenylether 88 U
86-73-7 Fluorene 88 U
100-01-6 4-Nitroaniline 440 U
534-52-1 4,6-Dinitro-2-Methylphenol 880 U
86-30-6 N-Nitrosodiphenylamine 88 U
101-55-3 4-Bromophenyl-phenylether 88 U
118-74-1 Hexachlorobenzene 88 U
87-86-5 Pentachlorophenol 440 U
85-01-8 Phenanthrene 88 U
86-74-8 Carbazole 88 U
120-12-7 Anthracene 88 U
84-74-2 Di-n-Butylphthalate 88 U
206-44-0 Fluoranthene 88 U
129-00-0 Pyrene 88 U
85-68-7 Butylbenzylphthalate 88 U
91-94-1 3,31-Dichlorobenzidine 440 U
56-55-3 Benzo(a)anthracene 88 U
117-81-7 bis(2-Ethylhexyl)phthalate 100 B
218-01-9 Chrysene 88 U
117-84-0 Di-n-Octyl phthalate 88 U
205-99-2 Benzo(b)fluoranthene 88 U
207-08-9 Benzo(k)fluoranthene 88 U
50-32-8 Benzo(a)pyrene 88 U
193-39-5 Indeno(1,2,3-cd)pyrene 88 U
53-70-3 Dibenz(a,h)anthracene 88 U
191-24-2 Benzo(g,h,i)perylene 88 U
Semivolatiles Surrogate Recovery
d5-Nitrobenzene 85.4!k d5-Phenol 85.3%
2-Fluorobiphenyl 92.4%- 2-Fluorophenol 89.0%-
d14-p-Terphenyl 85.6!k 2,4,6-Tribromophenol 107%-
d4-1,2-Dichlorobenzene 76.1% d4-2-Chlorophenol 85.9%
FORM-1
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET
Semivolatiles by GC/MS Sample No: SD-West
Page 1 of 2
Lab Sample ID: S739B QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9025 Project: P9 Sed
Matrix: Soil
Data Release Authorized: Date Sampled: 06/04/97
Reported: 06/23/97 Date Received: 06/05/97
Date extracted: 06/11/97 Sample Amount: 21.2 g-dry-wt
Date analyzed: 06/13/97 Final Extract Volume: 2.0 mL
Instrument: finn8 Dilution Factor: 1:1
GPC Cleanup: NO Percent Moisture: 30.5%-
pH: 5.7
CAS Number Analyte ug/kg
108-95-2 Phenol 190 U
111-44-4 Bis- (2-Chloroethyl) Ether 190 U
95-57-8 2-Chlorophenol 94 U
541-73-1 1.3-Dichlorobenzene 94 U
106-46-7 1,4-Dichlorobenzene 94 U
100-51-6 Benzyl Alcohol 470 U
95-50-1 1,2-Dichlorobenzene 94 U
95-48-7 2-Methylphenol 190 U
108-60-1 2,21-Oxybis(1-Chloropropane) 94 U
106-44-5 4-Methylphenol 94 U
621-64-7 N-Nitroso-Di-N-Propylamine 190 U
67-72-1 Hexachloroethane 190 U
98-95-3 Nitrobenzene 94 U
78-59-1 Isophorone 94 U
88-75-5 2-Nitrophenol 470 U
105-67-9 2,4-Dimethylphenol 280 U
65-85-0 Benzoic Acid 940 U
111-91-1 bis(2-Chloroethoxy) Methane 94 U
120-83-2 2,4-Dichlorophenol 280 U
120-82-1 1,2,4-Trichlorobenzene 94 U
91-20-3 Naphthalene 94 U
106-47-8 4-Chloroaniline 280 U
87-68-3 Hexachlorobutadiene 190 U
59-50-7 4-Chloro-3-methylphenol 190 U
91-57-6 2-Methylnaphthalene 94 U
77-47-4 Hexachlorocyclopentadiene 470 U
88-06-2 2,4,6-Trichlorophenol 470 U
95-95-4 2,4,5-Trichlorophenol 470 U
91-58-7 2-Chloronaphthalene 94 U
88-74-4 2-Nitroaniline 470 U
131-11-3 Dimethylphthalate 94 U
208-96-8 Acenaphthylene 94 U
99-09-2 3-Nitroaniline 560 U
83-32-9 Acenaphthene 94 U
51-28-5 2,4-Dinitrophenol 940 U
100-02-7 4-Nitrophenol 470 U
132-64-9 Dibenzofuran 94 U
606-20-2 2,6-Dinitrotoluene 470 U
FORM-1
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET
Semivolatiles by GC/MS Sample No: SD-West
Page 2 of 2
Lab Sample ID: S739B QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9025 Project: P9 Sed
Matrix: Soil
Data Release Authorized:of Date Sampled: 06/04/97
Reported: 06/23/97 Date Received: 06/05/97
Date extracted: 06/11/97 Sample Amount: 21.2 g-dry-wt
Date analyzed: 06/13/97 Final Extract Volume: 2.0 mL
Instrument: finn8 Dilution Factor: 1:1
GPC Cleanup: NO Percent Moisture: 30.5%
pH: 5.7
CAS Number Analyte ug/kg
121-14-2 2,4-Dinitrotoluene 470 U
84-66-2 Diethylphthalate 94 U
7005-72-3 4-Chlorophenyl-phenylether 94 U
86-73-7 Fluorene 94 U
100-01-6 4-Nitroaniline 470 U
534-52-1 4,6-Dinitro-2-Methylphenol 940 U
86-30-6 N-Nitrosodiphenylamine 94 U
101-55-3 4-Bromophenyl-phenylether 94 U
118-74-1 Hexachlorobenzene 94 U
87-86-5 Pentachlorophenol 470 U
85-01-8 Phenanthrene 94 U
86-74-8 Carbazole 94 U
120-12-7 Anthracene 94 U
84-74-2 Di-n-Butylphthalate 94 U
206-44-0 Fluoranthene 190
129-00-0 Pyrene 190
85-68-7 Butylbenzylphthalate 94 U
91-94-1 3,31-Dichlorobenzidine 470 U
56-55-3 Benzo(a)anthracene 94 U
117-81-7 bis(2-Ethylhexyl)phthalate 750 B
218-01-9 Chrysene 130
117-84-0 Di-n-Octyl phthalate 94 U
205-99-2 Benzo(b)fluoranthene 110
207-08-9 Benzo(k)fluoranthene 97
50-32-8 Benzo(a)pyrene 94 U
193-39-5 Indeno(1,2,3-cd)pyrene 94 U
53-70-3 Dibenz(a,h)anthracene 94 U
191-24-2 Benzo(g,h,i)perylene 94 U
Semivolatiles Surrogate Recovery
d5-Nitrobenzene 71.2t d5-Phenol 86.916
2-Fluorobiphenyl 92.4% 2-Fluorophenol 79.4%-
d14-p-Terphenyl 86.4%- 2,4,6-Tribromop4enol 108%-
d4-1,2-Dichlorobenzene 65.0%- d4-2-Chlorophenol 81.4%
FORM-1
. ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET
Semivolatiles by GC/MS Sample No: SD-East
Page 1 of 2
Lab Sample ID: S739C QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9026 Project: P9 Sed
Matrix: Soil
Data Release Authorized:/ Date Sampled: 06/04/97
Reported: 06/23/97 Date Received: 06/05/97
Date extracted: 06/11/97 Sample Amount: 22.2 g-dry-wt
Date analyzed: 06/13/97 Final Extract Volume: 2.0 mL
Instrument:. finn8 Dilution Factor: 1:1
GPC Cleanup: NO Percent Moisture: 26.3t
PH: 5.5
CAS Number Analyte ug/kg
108-95-2 Phenol 180 U
111-44-4 Bis- (2-Chloroethyl) Ether 180 U
95-57-8 2-Chlorophenol 90 U
541-73-1 1,3-Dichlorobenzene 90 U
106-46-7 1,4-Dichlorobenzene 90 U
100-51-6 Benzyl Alcohol 450 U
95-50-1 1,2-Dichlorobenzene 90 U
95-48-7 2-Methylphenol 180 U
108-60-1 2,21-Oxybis(1-Chloropropane) 90 U
106-44-5 4-Methylphenol 90 U
621-64-7 N-Nitroso-Di-N-Propylamine 180 U
67-72-1 Hexachloroethane 180 U
98-95-3 Nitrobenzene 90 U
78-59-1 Isophorone 90 U
88-75-5 2-Nitrophenol 450 U
105-67-9 2,4-Dimethylphenol 270 U
65-85-0 Benzoic Acid 900 U
111-91-1 bis(2-Chloroethoxy) Methane 90 U
120-83-2 2,4-Dichlorophenol 270 U
120-82-1 1,2,4-Trichlorobenzene 90 U
91-20-3 Naphthalene 90 U
106-47-8 4-Chloroaniline 270 U
87-68-3 Hexachlorobutadiene 180 U
59-50-7 4-Chloro-3-methylphenol 180 U
91-57-6 2-Methylnaphthalene 90 U
77-47-4 Hexachlorocyclopentadiene 450 U
88-06-2 2,4,6-Trichlorophenol 450 U
95-95-4 2,4,5-Trichlorophenol 450 U
91-58-7 2-Chloronaphthalene 90 U
88-74-4 2-Nitroaniline 450 U
131-11-3 Dimethylphthalate 90 U
208-96-8 Acenaphthylene 90 U
99-09-2 3-Nitroaniline 540 U
83-32-9 Acenaphthene 90 U
51-28-5 2,4-Dinitrophenol 900 U
100-02-7 4-Nitrophenol 450 U
132-64-9 Dibenzofuran 90 U
606-20-2 2,6-Dinitrotoluene 450 U
FORM-1
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET
Semivolatiles by GC/MS Sample No: SD-East
Page 2 of 2
Lab Sample ID: S739C QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9026 Project: P9 Sed
Matrix: Soil
Data Release Authorized: Date Sampled: 06/04/97
Reported: 06/23/97 Date Received: 06/05/97
Date extracted: 06/11/97 Sample Amount: 22.2 g-dry-wt
Date analyzed: 06/13/97 Final Extract Volume: 2.0 mL
Instrument: finn8 Dilution Factor: 1:1
GPC Cleanup: NO Percent Moisture: 26.3%
pH: 5.5
CAS Number Analyte ug/kg
121-14-2 2,4-Dinitrotoluene 450 U
84-66-2 Diethylphthalate 90 U
7005-72-3 4-Chlorophenyl-phenylether 90 U
86-73-7 Fluorene 90 U
100-01-6 4-Nitroaniline 450 U
534-52-1 4,6-Dinitro-2-Methylphenol 900 U
86-30-6 N-Nitrosodiphenylamine 90 U
101-55-3 4-Bromophenyl-phenylether 90 U
118-74-1 Hexachlorobenzene 90 U
87-86-5 Pentachlorophenol 450 U
85-01-8 Phenanthrene 90 U
86-74-8 Carbazole 90 U
120-12-7 Anthracene 90 U
84-74-2 Di-n-Butylphthalate 90 U
206-44-0 Fluoranthene S10 U
129-00-0 Pyrene 90 U
85-68-7 Butylbenzylphthalate 90 U
91-94-1 3,31-Dichlorobenzidine 450 U
56-55-3 Benzo(a)anthracene 90 U
117-81-7 bis(2-Ethylhexyl)phthalate 290 B
218-01-9 Chrysene 90 U
117-84-0 Di-n-Octyl phthalate 90 U
205-99-2 Benzo(b)fluoranthene 90 U
207-08-9 Benzo(k)fluoranthene 90 U
50-32-8 Benzo(a)pyrene 90 U
193-39-5 Indeno(1,2,3-cd)pyrene 90 U
53-70-3 Dibenz(a,h)anthracene 90 U
191-24-2 Benzo(g,h,i)perylene 90 U
Semivolatiles Surrogate Recovery
d5-Nitrobenzene 84.7% d5-Phenol 92.2%
2-Fluorobiphenyl 93.4% 2-Fluorophenol 94.1%
d14-p-Terphenyl 84.91; 2,4,6-Tribromophenol 103%
d4-1,2-Dichlorobenzene 77.3% d4-2-Chlorophenol 90.7%
FORM-1
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET
Semivolatiles by GC/MS Sample No: Method Blank
Page 1 of 2
Lab Sample ID: S739MB QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9024 Project: P9 Sed
Matrix: Soil
Data Release Authorized: Date Sampled: NA
Reported: 06/23/97 Date Received: NA
Date extracted: 06/11/97 Sample Amount: 30.0 g-dry-wt Equiv
Date analyzed: 06/13/97 Final Extract Volume: 2.0 mL
Instrument: finn8 Dilution Factor: 1:1
GPC Cleanup: NO Percent Moisture: NA
pH: NA
CAS Number Analyte ug/kg
108-95-2 Phenol 130 U
111-44-4 Bis- (2-Chloroethyl) Ether 130 U
95-57-8 2-Chlorophenol 67 U
541-73-1 1,3-Dichlorobenzene 67 U
106-46-7 1,4-Dichlorobenzene 67 U
100-51-6 Benzyl Alcohol 330 U
95-50-1 1,2-Dichlorobenzene 67 U
95-48-7 2-Methylphenol 130 U
108-60-1 2,21-Oxybis(1-Chloropropane) 67 U
106-44-5 4-Methylphenol 67 U
621-64-7 N-Nitroso-Di-N-Propylamine 130 U
67-72-1 Hexachloroethane 130 U
98-95-3 Nitrobenzene 67 U
78-59-1 Isophorone 67 U
88-75-5 2-Nitrophenol 330 U
105-67-9 2,4-Dimethylphenol 200 U
65-85-0 Benzoic Acid 670 U
111-91-1 bis(2-Chloroethoxy) Methane 67 U
120-83-2 2,4-Dichlorophenol 200 U
120-82-1 1,2,4-Trichlorobenzene 67 U
91-20-3 Naphthalene 67 U
106-47-8 4-Chloroaniline 200 U
87-68-3 Hexachlorobutadiene 130 U
59-50-7 4-Chloro-3-methylphenol 130 U
91-57-6 2-Methylnaphthalene 67 U
77-47-4 Hexachlorocyclopentadiene 330 U
88-06-2 2,4,6-Trichlorophenol 330 U
95-95-4 2,4,5-Trichlorophenol 330 U
91-58-7 2-Chloronaphthalene 67 U
88-74-4 2-Nitroaniline 330 U
131-11-3 Dimethylphthalate 67 U
208-96-8 Acenaphthylene 67 U
99-09-2 3-Nitroaniline 400 U
83-32-9 Acenaphthene 67 U
51-28-5 2,4-Dinitrophenol 670 U
100-02-7 4-Nitrophenol 330 U
132-64-9 Dibenzofuran 67 U
606-20-2 2,6-Dinitrotoluene 330 U
FORM-1
• ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET
Semivolatiles by GC/MS Sample No: Method Blank
Page 2 of 2
Lab Sample ID: S739MB QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9024 Project: P9 Sed
Matrix: Soil Data Release Authorized:o/ Date Sampled: NA
Reported: 06/23/97 Date Received: NA
Date extracted: 06/11/97 Sample Amount: 30.0 g-dry-wt Equiv
Date analyzed: 06/13/97 Final Extract Volume: 2.0 mL
Instrument: finn8 Dilution Factor: 1:1
GPC Cleanup: NO Percent Moisture: NA
pH: NA
CAS Number Analyte ug/kg
121-14-2 2,4-Dinitrotoluene 330 U
84-66-2 Diethylphthalate 67 U
7005-72-3 4-Chlorophenyl-phenylether 67 U
86-73-7 Fluorene 67 U
100-01-6 4-Nitroaniline 330 U
534-52-1 4,6-Dinitro-2-Methylphenol 670 U
86-30-6 N-Nitrosodiphenylamine 67 U
101-55-3 4-Bromophenyl-phenylether 67 U
118-74-1 Hexachlorobenzene 67 U
87-86-5 Pentachlorophenol 330 U
85-01-8 Phenanthrene 67 U
86-74-8 Carbazole 67 U
120-12-7 Anthracene 67 U
84-74-2 Di-n-Butylphthalate 67 U
206-44-0 Fiuoranthene 67 U
129-00-0 Pyrene 67 U
85-68-7 Butylbenzylphthalate 67 U
91-94-1 3,31-Dichlorobenzidine 330 U
56-55-3 Benzo(a)anthracene 67 U
117-81-7 bis(2-Ethylhexyl)phthalate 110
218-01-9 Chrysene 67 U
117-84-0 Di-n-Octyl phthalate 67 U
205-99-2 Benzo(b)fluoranthene 67 U
207-08-9 Benzo(k)fluoranthene 67 U
50-32-8 Benzo(a)pyrene 67 U
193-39-5 Indeno(1,2,3-cd)pyrene 67 U
53-70-3 Dibenz(a,h)anthracene 67 U
191-24-2 Benzo(g,h,i)perylene 67 U
Semivolatiles Surrogate Recovery
d5-Nitrobenzene 91.1%- d5-Phenol 94.1!k
2-Fluorobiphenyl 88.1%- 2-Fluorophenol 91.91;
d14-p-Terphenyl 104%- 2,4,6-Tribromophenol 84.2%;
d4-1,2-Dichlorobenzene 84.796 d4-2-Chlorophenol 92.4%
FORM-1
ANALYTICAL
ORGANICS ANALYSIS DATA SHEET RESOURCES
Semivolatiles by GC/MS INCORPORATED
Page 1 of 1
Lab Sample ID: S739SB QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9024 Project: P9 Sed
Matrix: Soil
Data Release Authorized Ay
Reported: 06/23/97
LABORATORY CONTROL SAMPLE
Date extracted: 06/11/97
Date analyzed: 06/13/97
SPIRE SPIRE %
CONSTITUENT VALUE ADDED RECOVERY
Phenol 2340 2500 93.6%
2-Chlorophenol 2400 2500 96.0%
1,4-Dichlorobenzene 1480 1670 88.6%
N-Nitroso-Di-N-Propylamine 1520 1670 91.0%
1,2,4-Trichlorobenzene 1370 1670 82.0%
4-Chloro-3-methylphenol 2510 2500 100%
Acenaphthene 1540 1670 92.2%
4-Nitrophenol 2040 2500 81.6%
2,4-Dinitrotoluene 1810 1670 108%
Pentachlorophenol 1630 2500 65.2%
Pyrene 1760 1670 105%
Lab Control Surrogate Recovery
d5-Nitrobenzene 87.8% d5-Phenol 96.696
2-Fluorobiphenyl 89.1% 2-Fluorophenol 98.4%
d14-p-Terphenyl 95.2% 2,4,6-Tribromophenol 92.15k
d4-1,2-Dichlorobenzene 80.746 d4-2-Chlorophenol 93.9%
Values reported in ug/kg-dry-weight
FORM-III
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET Sample No: SD-East
Semivolatiles by GC/MS MATRIX SPIKE
Page 1 of 2
Lab Sample ID: S739C-MS QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9026 Project: P9 Sed
Matrix: Soil o
Data Release Authorized:/,'/ Date Sampled: 06/04/97
Reported: 06/23/97 Date Received: 06/05/97
Date extracted: 06/11/97 Sample Amount: 22.5 g-dry-wt
Date analyzed: 06/13/97 Final Extract Volume: 2.0 mL
Instrument: finn8 Dilution Factor: 1:1
GPC Cleanup: NO Percent Moisture: 26.3%-
pH: 5.5
CAS Number Analyte ug/kg
108-95-2 Phenol ---
111-44-4 Bis- (2-Chloroethyl) Ether 180 U
95-57-8 2-Chlorophenol ---
541-73-1 1,3-Dichlorobenzene 89 U
106-46-7 1,4-Dichlorobenzene -- -
100-51-6 Benzyl Alcohol 450 U
95-50-1 1,2-Dichlorobenzene 89 U
95-48-7 2-Methylphenol 180 U
108-60-1 2,21-Oxybis(1-Chloropropane) 89 U
106-44-5 4-Methylphenol 89 U
621-64-7 N-Nitroso-Di-N-Propylamine ---
67-72-1 Hexachloroethane 180 U
98-95-3 Nitrobenzene 89 U
78-59-1 Isophorone 89 U
88-75-5 2-Nitrophenol 450 U
105-67-9 2,4-Dimethylphenol 270 U
65-85-0 Benzoic Acid 890 U
111-91-1 bis(2-Chloroethoxy) Methane 89 U
120-83-2 2,4-Dichlorophenol 270 U
120-82-1 1,2,4-Trichlorobenzene ---
91-20-3 Naphthalene 89 U
106-47-8 4-Chloroaniline 270 U
87-68-3 Hexachlorobutadiene 180 U
59-50-7 4-Chloro-3-methylphenol ---
91-57-6 2-Methylnaphthalene 89 U
77-47-4 Hexachlorocyclopentadiene 450 U
88-06-2 2,4,6-Trichlorophenol 450 U
95-95-4 2,4,5-Trichlorophenol 450 U
91-58-7 2-Chloronaphthalene 89 U
88-74-4 2-Nitroaniline 450 U
131-11-3 Dimethylphthalate 89 U
208-96-8 Acenaphthylene 89 U
99-09-2 3-Nitroaniline 530 U
83-32-9 Acenaphthene ---
51-28-5 2,4-Dinitrophenol 890 U
100-02-7 4-Nitrophenol ---
132-64-9 Dibenzofuran 89 U
606-20-2 2,6-Dinitrotoluene 450 U
FORM-1
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET Sample No: SD-East
Semivolatiles by GC/MS MATRIX SPIRE
Page 2 of 2
Lab Sample ID: S739C-MS QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9026 Project: P9 Sed
Matrix: Soil
Data Release Authorized: Date Sampled: 06/04/97
Reported: 06/23/97 Date Received: 06/05/97
Date extracted: 06/11/97 Sample Amount: 22.5 g-dry-wt
Date analyzed: 06/13/97 Final Extract Volume: 2.0 mL
Instrument: finn8 Dilution Factor: 1:1
GPC Cleanup: NO Percent Moisture: 26.3%
pH: 5.5
CAS Number Analyte ug/kg
121-14-2 2,4-Dinitrotoluene ---
84-66-2 Diethylphthalate 89 U
7005-72-3 4-Chlorophenyl-phenylether 89 U
86-73-7 Fluorene 89 U
100-01-6 4-Nitroaniline 450 U
534-52-1 4,6-Dinitro-2-Methylphenol 890 U
86-30-6 N-Nitrosodiphenylamine 89 U
101-55-3 4-Bromophenyl-phenylether 89 U
118-74-1 Hexachlorobenzene 89 U
87-86-5 Pentachlorophenol ---
85-01-8 Phenanthrene 89 U
86-74-8 Carbazole 89 U
120-12-7 Anthracene 89 U
84-74-2 Di-n-Butylphthalate 89 U
206-44-0 Fluoranthene 89 U
129-00-0 Pyrene ---
85-68-7 Butylbenzylphthalate 89 U
91-94-1 3,31-Dichlorobenzidine 450 U
56-55-3 Benzo(a)anthracene 89 U
117-81-7 bis(2-Ethylhexyl)phthalate 360 B
218-01-9 Chrysene 89 U
117-84-0 Di-n-Octyl phthalate 89 U
205-99-2 Benzo(b)fluoranthene 89 U
207-08-9 Benzo(k)fluoranthene 89 U
50-32-8 Benzo(a)pyrene 89 U
193-39-5 Indeno(1,2,3-cd)pyrene 89 U
53-70-3 Dibenz(a,h)anthracene 89 U
191-24-2 Benzo(g,h,i)perylene 89 U
Semivolatiles Surrogate Recovery
d5-Nitrobenzene 79.5% d5-Phenol 86.0%
2-Fluorobiphenyl 89.2% 2-Fluorophenol 82.7%
d14-p-Terphenyl 91.0% 2,4,6-Tribromophenol 108%
d4-1,2-Dichlorobenzene 68.7% d4-2-Chlorophenol 88.6%
FORM-1
• ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET Sample No: SD-East
Semivolatiles by GC/MS SPIKE DUPLICATE
Page 1 of 2
Lab Sample ID: S739C-MSD QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9026 Project: P9 Sed
Matrix: Soil
Data Release Authorized:o/ Date Sampled: 06/04/97
Reported: 06/23/97 Date Received: 06/05/97
Date extracted: 06/11/97 Sample Amount: 22.3 g-dry-wt
Date analyzed: 06/13/97 Final Extract Volume: 2.0 mL
Instrument: finn8 Dilution Factor: 1:1
GPC Cleanup: NO Percent Moisture: 26.3%
pH: 5.5
CAS Number Analyte ug/kg
108-95-2 Phenol ---
111-44-4 Bis- (2-Chloroethyl) Ether 180 U
95-57-8 2-Chlorophenol ---
541-73-1 1,3-Dichlorobenzene 90 U
106-46-7 1,4-Dichlorobenzene -
100-51-6 Benzyl Alcohol 45C U
95-50-1 1,2-Dichlorobenzene 90 U
95-48-7 2-Methylphenol 180 U
108-60-1 2,21-Oxybis(1-Chloropropane) 90 U
106-44-5 4-Methylphenol 90 U
621-64-7 N-Nitroso-Di-N-Propylamine ---
67-72-1 Hexachloroethane 180 U
98-95-3 Nitrobenzene 90 U
78-59-1 Isophorone 90 U
88-75-5 2-Nitrophenol 450 U
105-67-9 2,4-Dimethylphenol 270 U
65-85-0 Benzoic Acid 900 U
111-91-1 bis(2-Chloroethoxy) Methane 90 U
120-83-2 2,4-Dichlorophenol 270 U
120-82-1 1,2,4-Trichlorobenzene ---
91-20-3 Naphthalene 90 U
106-47-8 4-Chloroaniline 270 U
87-68-3 Hexachlorobutadiene 180 U
59-50-7 4-Chloro-3-methylphenol ---
91-57-6 2-Methylnaphthalene 90 U
77-47-4 Hexachlorocyclopentadiene 450 U
88-06-2 2,4,6-Trichlorophenol 450 U
95-95-4 2,4,5-Trichlorophenol 450 U
91-58-7 2-Chloronaphthalene 90 U
88-74-4 2-Nitroaniline 450 U
131-11-3 Dimethylphthalate 90 U
208-96-8 Acenaphthylene 90 U
99-09-2 3-Nitroaniline 540 U
83-32-9 Acenaphthene ---
51-28-5 2,4-Dinitrophenol 900 U
100-02-7 4-Nitrophenol ---
132-64-9 Dibenzofuran 90 U
606-20-2 2,6-Dinitrotoluene 450 U
FORM-1
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET Sample No: SD-East
Semivolatiles by GC/MS SPIRE DUPLICATE
Page 2 of 2
Lab Sample ID: S739C-MSD QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9026 Project: P9 Sed
Matrix: Soil
Data Release Authorized: Date Sampled: 06/04/97
Reported: 06/23/97 Date Received: 06/05/97
Date extracted: 06/11/97 Sample-Amc,unt: 22.3 g-dry-wt
Date analyzed: 06/13/97 Final Extract Volume: 2.0 mL
Instrument: finn8 Dilution Factor: 1:1
GPC Cleanup: NO Percent Moisture: 26.3%
pH: 5.5
CAS Number Analyte ug/kg
121-14-2 2,4-Dinitrotoluene ---
84-66-2 Diethylphthalate 90 U
7005-72-3 4-Chlorophenyl-phenylether 90 U
86-73-7 Fluorene 90 U
100-01-6 4-Nitroaniline 450 U
534-52-1 4,6-Dinitro-2-Methylphenol 900 U
86-30-6 N-Nitrosodiphenylamine 90 U
101-55-3 4-Bromophenyl-phenylether 90 U
118-74-1 Hexachlorobenzene 90 U
87-86-5 Pentachlorophenol ---
85-01-8 Phenanthrene 90 U
86-74-8 Carbazole 90 U
120-12-7 Anthracene 90 U
84-74-2 Di-n-Butylphthalate 90 U
206-44-0 Fluoranthene 90 U
129-00-0 Pyrene ---
85-68-7 Butylbenzylphthalate 90 U
91-94-1 3,3'-Dichlorobenzidine 450 U
56-55-3 Benzo(a)anthracene 90 U
117-81-7 bis(2-Ethylhexyl)phthalate 360 B
218-01-9 Chrysene 90 U
117-84-0 Di-n-Octyl phthalate 90 U
205-99-2 Benzo(b)fluoranthene 90 U
207-08-9 Benzo(k)fluoranthene 90 U
50-32-8 Benzo(a)pyrene 90 U
193-39-5 Indeno(1,2,3-cd)pyrene 90 U
53-70-3 Dibenz(a,h)anthracene 90 U
191-24-2 Benzo(g,h,i)perylene 90 U
Semivolatiles Surrogate Recovery
d5-Nitrobenzene 78.696 d5-Phenol 90.816
2-Fluorobiphenyl 81.7% 2-Fluorophenol 92.81;
d14-p-Terphenyl 94.8%- 2,4,6-Tribromophenol 112%;
d4-1,2-Dichlorobenzene 58.8% d4-2-Chlorophenol 92.6%
FORM-1
ORGANICS ANALYSIS DATA SHEET ANALYTICAL
Semivolatiles by GC/MS RESOURCES
Page 1 of 1 0 INCORPORATED
Sample No: SD-East
Lab Sample ID: S739C QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9026 Project: P9 Sed
Matrix: Soil
Date Received: 06/05/97
Data Release Authorized: e
Reported: 06/23/97
MATRIX SPIRE/SPIKE DUPLICATE RECOVERY
Date extracted: 06/11/97
Date analyzed: 06/13/97
SAMPLE SPIKE SPIKE $
CONSTITUENT VALUE VALUE ADDED RECOVERY RPD
MATRIX SPIKE
Phenol < 180. 2950 3340 88.316
2-Chlorophenol < 89.9 2850 3340 85.3%
1,4-Dichlorobenzene < 89.9 1460 2230 65.516
N-Nitroso-Di-N-Propylamine< 180. 1850 2230 83.0%
1,2,4-Trichlorobenzene < 89.9 1700 2230 76.2%
4-Chloro-3-methylphenol < 180. 3500 3340 105%
Acenaphthene < 89.9 1920 2230 86.1%
4-Nitrophenol < 450. 2980 3340 89.216
2,4-Dinitrotoluene < 450. 2540 2230 114%
Pentachlorophenol < 450. 3390 3340 101%
Pyrene < 89.9 2120 2230 95.1%
MATRIX SPIKE DUPLICATE
Phenol < 180. 3160 3360 94.0% 6.2;
2-Chlorophenol < 89.9 3110 3360 92.6% 8.2%
1,4-Dichlorobenzene < 89.9 1790 2240 79.9% 20%
N-Nitroso-Di-N-Propylamine< 180. 2080 2240 92.9% 11%
1,2,4-Trichlorobenzene < 89.9 1770 2240 79.09. 3.616
4-Chloro-3-methylphenol < 180. 3320 3360 98.8% 5.9%
Acenaphthene < 89.9 1930 2240 86.2% 0.1%
4-Nitrophenol < 450. 2910 3360 86.6% 3.016
214-Dinitrotoluene < 450. 2540 2240 113% 0.8%
Pentachlorophenol < 450. 3030 3360 90.2% 12%
Pyrene < 89.9 2380 2240 106% 11%
Values reported in ug/kg-dry-weight
FORM-III
• ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET Sample No: S-1
Pesticides/PCB by GC/ECD
Lab Sample ID: S739A QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9024 roject: P9 Sed
Matrix: Soil
Data Release Authorized: ?tDa
d 06/04/97
Reported: 06/27/97 ive 06/05/97
Date extracted: 06/11/97 Sample Amount: 8.88 g-dry-wt
Date analyzed: 06/17/97 Final Extract Volume: 4.0 mL
GPC Cleanup: NO Dilution Factor: 1:1
Florisil: YES Percent Moisture: 26.3%
Sulfur Cleanup: YES pH: 6.0
CAS Number Analyte ug/kg
319-84-6 alpha-BHC 2.3 U
319-85-7 beta-BHC 2.3 U
319-86-8 delta-BHC 2.3 U
58-89-9 gamma-BHC (Lindane) 2.3 U
76-44-8 Heptachlor 2.3 U
309-00-2 Aldrin 2.3 U
1024-57-3 Heptachlor Epoxide 2.3 U
959-98-8 Endosulfan I 2.3 U
60-57-1 Dieldrin 4.5 U
72-55-9 4,4'-DDE 4.5 U
72-20-8 Endrin 4.5 U
33213-65-9 Endosulfan II 4.5 U
72-54-8 4,4'-DDD 4.5 U
1031-07-8 Endosulfan Sulfate 4.5 U
50-29-3 4,4'-DDT 4.5 U
72-43-5 Methoxychlor 23 U
53494-70-5 Endrin Ketone 4.5 U
7421-93-4 Endrin Aldehyde 4.5 U
57-74-9 gamma Chlordane 2.3 U
5103-71-9 alpha Chlordane 2.3 U
8001-35-2 Toxaphene 230 U
12674-11-2 Aroclor 1016 45 U
53469-21-9 Aroclor 1242 45 U
12672-29-6 Aroclor 1248 45 U
11097-69-1 Aroclor 1254 45 U
11096-82-5 Aroclor 1260 45 U
Pesticide Surrogate Recovery
Decachlorobiphenyl 97.8%
Tetrachlorometaxylene 110%
FORM-1
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET Sample No: SD-West
Pesticides/PCB by GC/ECD
Lab Sample ID: S739B QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9025 Project: P9 Sed
Matrix: Soil
Data Release Authorized: rS e 6/04/97
Reported: 06/27/97 Date c ive 06/05/97
Date extracted: 06/11/97 Sample Amount: 8.37 g-dry-wt
Date analyzed: 06/17/97 Final Extract Volume: 4.0 mL
GPC Cleanup: NO Dilution Factor: 1:1
Florisil: YES Percent MOi.3Lure: 30.5%
Sulfur Cleanup: YES pH: 5.7
CAS Number Analyte ug/kg
319-84-6 alpha-BHC 2.4 U
319-85-7 beta-BHC 2.4 U
319-86-8 delta-BHC 2.4 U
58-89-9 gamma-BHC (Lindane) 2.4 U
76-44-8 Heptachlor 2.4 U
309-00-2 Aldrin 2.4 U
1024-57-3 Heptachlor Epoxide 2.4 U
959-98-8 Endosulfan I 2.4 U
60-57-1 Dieldrin 4.8 U
72-55-9 4,4'-DDE 4.8 U
72-20-8 Endrin 4.8 U
33213-65-9 Endosulfan II 4.8 U
72-54-8 4,4--DDD 4.8 U
1031-07-8 Endosulfan Sulfate 4.8 U
50-29-3 4,4--DDT 4.8 U
72-43-5 Methoxychlor 24 U
53494-70-5 Endrin Ketone 4.8 U
7421-93-4 Endrin Aldehyde 4.8 U
57-74-9 gamma Chlordane 2.4 U
5103-71-9 alpha Chlordane 2.4 U
8001-35-2 Toxaphene 240 U
12674-11-2 Aroclor 1016 48 U
53469-21-9 Aroclor 1242 48 U
12672-29-6 Aroclor 1248 48 U
11097-69-1 Aroclor 1254 48 U
11096-82-5 Aroclor 1260 48 U
Pesticide Surrogate Recovery
Decachlorobiphenyl 56.51;
Tetrachlorometaxylene 49.5%
FORM-1
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET Sample No: SD-East
Pesticides/PCB by GC/ECD
Lab Sample ID: S739C QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9026 Project: P9 Sed
Matrix: Soil
Data Release Authorized: �ate
m 0 04 97
Reported: 06/27/97 ei ed: 06/05/97
Date extracted: 06/11/97 Sample Amount: 8.86 g-dry-wt
Date analyzed: 06/17/97 Final Extract Volume: 4.0 mL
GPC Cleanup: NO Dilution Factor: 1:1
Florisil: YES Percent Moisture: 26.3%
Sulfur Cleanup: YES pH: 5.5
CAS Number Analyte ug/kg
319-84-6 alpha-BHC 2.3 U
319-85-7 beta-BHC 2.3 U
319-86-8 delta-BHC 5.3 Y
58-89-9 gamma-BHC (Lindane) 2.3 U
76-44-8 Heptachlor 2.3 U
309-00-2 Aldrin 2.3 U
1024-57-3 Heptachlor Epoxide 2.3 U
959-98-8 Endosulfan I 2.3 U
60-57-1 Dieldrin 4.5 U
72-55-9 4,4'-DDE 4.5 U
72-20-8 Endrin 4.5 U
33213-65-9 Endosulfan II 4.5 U
72-54-8 4,4--DDD 4.5 U
1031-07-8 Endosulfan Sulfate 4.5 U
50-29-3 4,4--DDT 4.5 U
72-43-5 Methoxychlor 23 U
53494-70-5 Endrin Ketone 4.5 U
7421-93-4 Endrin Aldehyde 4.5 U
57-74-9 gamma Chlordane 2.3 U
5103-71-9 alpha Chlordane 2.3 U
8001-35-2 Toxaphene 230 U
12674-11-2 Aroclor 1016 45 U
53469-21-9 Aroclor 1242 45 U
12672-29-6 Aroclor 1248 45 U
11097-69-1 Aroclor 1254 45 U
11096-82-5 Aroclor 1260 45 U
Pesticide Surrogate Recovery
Decachlorobiphenyl 84.816
Tetrachlorometaxylene 84.8t
FORM-1
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET Sample No: Method Blank
Pesticides/PCB by GC/ECD
Lab Sample ID: S739MB QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9024 Project: P9 Sed
Matrix: Soil
Data Release Authorized: Xa d N
Reported: 06/27/97 e ed: NA
Date extracted: 06/11/97 Sample Amount: 12.0 g-dry-wt
Date analyzed: 06/17/97 Final EXtract_Volume: 4.0 mL
GPC Cleanup: NO Dilution Factor: 1:1
Florisil: YES Percent Moisture: NA
Sulfur Cleanup: YES pH: NA
CAS Number Analyte ug/kg
319-84-6 alpha-BHC 1.7 U
319-85-7 beta-BHC 1.7 U
319-86-8 delta-BHC 1.7 U
58-89-9 gamma-BHC (Lindane) 1.7 U
76-44-8 Heptachlor 1.7 U
309-00-2 Aldrin 1.7 U
1024-57-3 Heptachlor Epoxide 1.7 U
959-98-8 Endosulfan I 1.7 U
60-57-1 Dieldrin 3.3 U
72-55-9 4,4'-DDE 3.3 U
72-20-8 Endrin 3.3 U
33213-65-9 Endosulfan II 3.3 U
72-54-8 4,4'-DDD 3.3 U
1031-07-8 Endosulfan Sulfate 3.3 U
50-29-3 4,4--DDT 3.3 U
72-43-5 Methoxychlor 17 U
53494-70-5 Endrin Ketone 3.3 U
7421-93-4 Endrin Aldehyde 3.3 U
57-74-9 gamma Chlordane 1.7 U
5103-71-9 alpha Chlordane 1.7 U
8001-35-2 Toxaphene 170 U
12674-11-2 Aroclor 1016 33 U
53469-21-9 Aroclor 1242 33 U
12672-29-6 Aroclor 1248 33 U
11097-69-1 Aroclor 1254 33 U
11096-82-5 Aroclor 1260 33 U
Pesticide Surrogate Recovery
Decachlorobiphenyl 97.2%-
Tetrachlorometaxylene 11216
FORM-1
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET
Pesticide/PCB by GC/ECD
Lab Sample ID: S739SB QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9024 Project: P9 Sed
Matrix: Soil
Data Release Authorized:
Reported: 06/27/97
LABORATORY CONTROL SAMPLE
Date extracted: 06/11/97
SPIRE SPIKE $
CONSTITUENT FOUND ADDED RECOVERY
gamma-BHC (Lindane) 17.8 16.7 107$
Heptachlor 17.7 16.7 106$
Aldrin 17.9 16.7 107%-
Dieldrin 34.7 33.3 104%-
Endrin 38.7 33.3 116%;
4,4'-DDT 36.3 33.3 109"s
Spike Blank Surrogate Recovery
Decachlorobiphenyl 97.0%-
Tetrachlorometaxylene 11216
Values reported in ug/kg
FORM-III
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET Sample No: SD-East
Pesticides/PCB by GC/ECD MATRIX SPIRE
Lab Sample ID: S739C-MS QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9026 PrXe : P9 Sed
Matrix: Soil
Data Release Authorized: a a : 06/ 4 97
Reported: 06/27/97 Date R c 6/05/97
Date extracted: 06/11/97 Sample Amount: 8.84 g-dry-wt
Date analyzed: 06/17/97 Final Extract Volume: 4.0 mL
GPC Cleanup: NO Dilution Factor: 1:1
Florisil: YES Percent Moisture: 26.3%
Sulfur Cleanup: YES pH: 5.5
CAS Number Analyte ug/kg
319-84-6 alpha-BHC 2.3 U
319-85-7 beta-BHC 2.3 U
319-86-8 delta-BHC 4.0 Y
58-89-9 gamma-BHC (Lindane) ---
76-44-8 Heptachlor ---
309-00-2 Aldrin ---
1024-57-3 Heptachlor Epoxide 2.3 U
959-98-8 Endosulfan I 2.3 U
60-57-1 Dieldrin ---
72-55-9 4,4'-DDE 4.5 U
72-20-8 Endrin ---
33213-65-9 Endosulfan II 4.5 U
72-54-8 4,4'-DDD 4.5 U
1031-07-8 Endosulfan Sulfate 4.5 U
50-29-3 4,4'-DDT ---
72-43-5 Methoxychlor 23 U
53494-70-5 Endrin Ketone 4.5 U
7421-93-4 Endrin Aldehyde 4.5 U
57-74-9 gamma Chlordane 2.3 U
5103-71-9 alpha Chlordane 2.3 U
8001-35-2 Toxaphene 230 U
12674-11-2 Aroclor 1016 45 U
53469-21-9 Aroclor 1242 45 U
12672-29-6 Aroclor 1248 45 U
11097-69-1 Aroclor 1254 45 U
11096-82-5 Aroclor 1260 45 U
Pesticide Surrogate Recovery
Decachlorobiphenyl 75.8%
Tetrachlorometaxylene 78.0%
FORM-1
ANALYTICAL
RESOURCES
INCORPORATED
ORGANICS ANALYSIS DATA SHEET Sample No: SD-East
Pesticides/PCB by GC/ECD MS DUPLICATE
Lab Sample ID: S739C-MSD QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9026 Project: P9 Sed
Matrix: Soil
Data Release Authorized: d 06/04/97
Reported: 06/27/97 Date Re a ve 06/05/97
Date extracted: 06/11/97 Sample Amount: 8.85 g-dry-wt
Date analyzed: 06/17/97 Final Extract Volume: 4.0 mL
GPC Cleanup: NO Dilution Factor: 1:1
Florisil: YES Percent Moisture: 26.3%
Sulfur Cleanup: YES pH: 5.5
CAS Number Analyte ug/kg
319-84-6 alpha-BHC 2.3 U
319-85-7 beta-BHC 2.3 U
319-86-8 delta-BHC 2.8 Y
58-89-9 gamma-BHC (Lindane) ---
76-44-8 Heptachlor ---
309-00-2 Aldrin ---
1024-57-3 Heptachlor Epoxide 2.3 U
959-98-8 Endosulfan I 2.3 U
60-57-1 Dieldrin ---
72-55-9 4,4'-DDE 4.5 U
72-20-8 Endrin ---
33213-65-9 Endosulfan II 4.5 U
72-54-8 4,4--DDD 4.5 U
1031-07-8 Endosulfan Sulfate 4.5 U
50-29-3 4,4'-DDT ---
72-43-5 Methoxychlor 23 U
53494-70-5 Endrin Ketone 4.5 U
7421-93-4 Endrin Aldehyde 4.5 U
57-74-9 gamma Chlordane 2.3 U
5103-71-9 alpha Chlordane 2.3 U
8001-35-2 Toxaphene 230 U
12674-11-2 Aroclor 1016 45 U
53469-21-9 Aroclor 1242 45 U
12672-29-6 Aroclor 1248 45 U
11097-69-1 Aroclor 1254 45 U
11096-82-5 Aroclor 1260 45 U
Pesticide Surrogate Recovery
Decachlorobiphenyl 95.096
Tetrachlorometaxylene 79.0%
FORM-1
ANALYTICAL
RESOURCES
ORGANICS ANALYSIS DATA SHEET INCORPORATED
Pesticide/PCB by GC/ECD
Sample No: SD-East
Lab Sample ID: S739C QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9026 Project: P9 Sed
Matrix: Soil
D ce' a 06/05/97
Data Release Authorized:
Reported: 06/27/97
MATRIX SPIRE/SPIRE DUPLICATE RECOVERY
Date extracted: 06/11/97
Date analyzed: 06/17/97
SAMPLE SPIRE SPIRE $
CONSTITUENT VALUE FOUND ADDED RECOVERY RPD
MATRIX SPIKE
gamma-BHC (Lindane) < 2.26 17.1 22.6 75.6%
Heptachlor < 2.26 15.8 22.6 69.8%
Aldrin < 2.26 16.4 22.6 72.5%
Dieldrin < 4.51 34.1 45.2 75.4%
Endrin < 4.51 38.9 45.2 86.0%;
4,4'-DDT < 4.51 32.5 45.2 71.8%
MATRIX SPIKE DUPLICATE
gamma-BHC (Lindane) < 2.26 17.0 22.6 75.2% 0.5%
Heptachlor < 2.26 14.9 22.6 65.9% 5.8%
Aldrin < 2.26 16.0 22.6 70.8% 2.4%
Dieldrin < 4.51 32.9 45.2 72.8% 3.5%
Endrin < 4.51 40.1 45.2 88.7% 3.1%
4,4- -DDT < 4.51 26.4 45.2 58.4% 21.0%
values reported in ug/kg-dry-weight
FORM-III
ANALYTICAL
RESOURCES
INCORPORATED
SOIL PEST SURROGATE SUMMARY
Matrix: Soil QC Report No: 5739
Project: P9 Sed
DB5 DB5 TOT
LIMS ID Lab ID Client ID TCMX # DCBP # OUT
97-9024MB 061197MB Method Blank 112!� 97.21t 0
97-9024 S739A S-1 110% 97.8% 0
97-9025 S739B SD-West 49.5%- 56.51: 0
97-9026 S739C SD-East 84.8!k 84.896 0
97-9026MS S739C SD-East 78.0%- 75.8% 0
97-9026MD S739C SD-East 79.0% 95.0% 0
Control Sample
QC LIMITS QC LIMITS
(TCMX) = Tetrachloro-m-xylene (36-115) (46-131)
(DCBP) = Decachlorobiphenyl (39-127) (54-138)
# Column to be used to flag recovery values
* Values outside of required QC limits
D Surrogate Compound diluted out
Page 1 for S739 FORM-II PEST
ANALYTICAL
RESOURCES
INCORPORATED
INORGANICS ANALYSIS DATA SHEET Sample No: S-1
TOTAL METALS
Lab Sample ID: S739A QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9024 Project: P9 Sed
Matrix: Soil
Date Sampled: 06/04/97
Date Received: 06/05/97
Data Release Authorized
Reported: 06/26/97
Percent Total Solids: 76.9%
Prep Prep Analysis Analysis
Meth Date Method Date CAS Number Analyte RL mg/kg-dry
3050 06/16/97 6010 06/17/97 7440-38-2 Arsenic 6 6 U
3050 06/16/97 6010 06/17/97 7440-39-3 Barium 0.1 75.3
3050 06/16/97 6010 06/17/97 7440-43-9 Cadmium 0.2 0.2 U
3050 06/16/97 6010 06/17/97 7440-47-3 Chromium 0.6 33.1
3050 06/16/97 6010 06/17/97 7439-92-1 Lead 2 10
CLP 06/16/97 7471 06/17/97 7439-97-6 Mercury 0.05 0.05 U
3050 06/16/97 6010 06/17/97 7782-49-2 Selenium 6 6 U
3050 06/16/97 6010 06/17/97 7440-22-4 Silver 0.3 0.3 U
U Analyte undetected at given RL
RL Reporting Limit
FORM-I
ANALYTICAL
RESOURCES
INCORPORATED
INORGANICS ANALYSIS DATA SHEET Sample No: SD-West
TOTAL METALS
Lab Sample ID: S739B QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9025 Project: P9 Sed
Matrix: Soil
Date Sampled: 06/04/97
Date Received: 06/05/97
Data Release Authorize
Reported: 06/26/97
Percent Total Solids: 71.1%
Prep Prep Analysis Analysis
Meth Date Method Date CAS Number Analyte RL mg/kg-dry
3050 06/16/97 6010 06/17/97 7440-38-2 Arsenic 6 6 U
3050 06/16/97 6010 06/17/97 7440-39-3 Barium 0.1 63.0
3050 06/16/97 6010 06/17/97 7440-43-9 Cadmium 0.2 0.3
3050 06/16/97 6010 06/17/97 7440-47-3 Chromium 0.6 32.2
3050 06/16/97 6010 06/17/97 7439-92-1 Lead 2 10
CLP 06/16/97 7471 06/17/97 7439-97-6 Mercury 0.06 0.06 U
3050 06/16/97 6010 06/17/97 7782-49-2 Selenium 6 7
3050 06/16/97 6010 06/17/97 7440-22-4 Silver 0.4 0.4 U
U Analyte undetected at given RL
RL Reporting Limit
FORM-I
ANALYTICAL
RESOURCES
INCORPORATED
INORGANICS ANALYSIS DATA SHEET Sample No: SD-East
TOTAL METALS
Lab Sample ID: S739C QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9026 Project: P9 Sed
Matrix: Soil
Date Sampled: 06/04/97
Date Received: 06/05/97
Data Release Authorize
Reported: 06/26/97
Percent Total Solids: 59.5%
Prep Prep Analysis Analysis
Meth Date Method Date CAS Number Analyte RL mg/kg-dry
3050 06/16/97 6010 06/17/97 7440-38-2 Arsenic 7 7 U
3050 06/16/97 6010 06/17/97 7440-39-3 Barium 0.1 64.6
3050 06/16/97 6010 06/17/97 7440-43-9 Cadmium 0.3 0.6
3050 06/16/97 6010 06/17/97 7440-47-3 Chromium 0.7 29.9
3050 06/16/97 6010 06/17/97 7439-92-1 Lead 3 11
CLP 06/16/97 7471 06/17/97 7439-97-6 Mercury 0.07 0.07 U
3050 06/16/97 6010 06/17/97 7782-49-2 Selenium 7 7 U
3050 06/16/97 6010 06/17/97 7440-22-4 Silver 0.4 0.4 U
U Analyte undetected at given RL
RL Reporting Limit
FORM-I
ANALYTICAL
RESOURCES
INCORPORATED
INORGANICS ANALYSIS DATA SHEET Sample No: S-1
TCLP METALS
Lab Sample ID: S739A QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9024 Project: P9 Sed
Matrix: Soil
Date Sampled: 06/04/97
Date Received: 06/05/97
Data Release Authorized
Reported: 06/26/97
Prep Prep Analysis Analysis
Meth Date Method Date CAS Number Analyte RL mg/L
1311 06/12/97 6010 06/17/97 7440-38-2 Arsenic 0.05 0.05 U
1311 06/12/97 6010 06/17/97 7440-39-3 Barium 0.001 0.580
1311 06/12/97 6010 06/17/97 7440-43-9 Cadmium 0.002 0.002 U
1311 06/12/97 6010 06/17/97 7440-47-3 Chromium 0.005 0.005 U
1311 06/12/97 6010 06/17/97 7439-92-1 Lead 0.02 0.02 U
1311 06/13/97 7470 06/16/97 7439-97-6 Mercury 0.0001 0.0001 U
1311 06/12/97 6010 06/17/97 7782-49-2 Selenium 0.05 0.05 U
1311 06/12/97 6010 06/17/97 7440-22-4 Silver 0.003 0.003 U
U Analyte undetected at given RL
RL Reporting Limits
FORM-I
ANALYTICAL
RESOURCES
INCORPORATED
INORGANICS ANALYSIS DATA SHEET Sample No: SD-West
TCLP METALS
Lab Sample ID: S739B QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9025 Project: P9 Sed
Matrix: Soil
Date Sampled: 06/04/97
Date Received: 06/05/97
Data Release Authorize
Reported: 06/26/97
Prep Prep Analysis Analysis
Meth Date Method Date CAS Number Analyte RL mg/L
1311 06/12/97 6010 06/17/97 7440-38-2 Arsenic 0.05 0.05 U
1311 06/12/97 6010 06/17/97 7440-39-3 Barium 0.001 0.272
1311 06/12/97 6010 06/17/97 7440-43-9 Cadmium 0.002 0.002
1311 06/12/97 6010 06/17/97 7440-47-3 Chromium 0.005 0.005 U
1311 06/12/97 6010 06/17/97 7439-92-1 Lead 0.02 0.02 U
1311 06/13/97 7470 06/16/97 7439-97-6 Mercury 0.0001 0.0001 U
1311 06/12/97 6010 06/17/97 7782-49-2 Selenium 0.05 0.05 U
1311 06/12/97 6010 06/17/97 7440-22-4 Silver 0.003 0.003 U
U Analyte undetected at given RL
RL Reporting Limits
FORM-I
ANALYTICAL
RESOURCES
INCORPORATED
INORGANICS ANALYSIS DATA SHEET Sample No: SD-East
TCLP METALS
Lab Sample ID: S739C QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9026 Project: P9 Sed
Matrix: Soil
Date Sampled: 06/04/97
Date Received: 06/05/97
Data Release Authorize
Reported: 06/26/97
Prep Prep Analysis Analysis
Meth Date Method Date CAS Number Analyte RL mg/L
1311 06/12/97 6010 06/17/97 7440-38-2 Arsenic 0.05 0.05 U
1311 06/12/97 6010 06/17/97 7440-39-3 Barium 0.001 0.250
1311 06/12/97 6010 06/17/97 7440-43-9 Cadmium 0.002 0.002 U
1311 06/12/97 6010 06/17/97 7440-47-3 Chromium 0.005 0.005 U
1311 06/12/97 6010 06/17/97 7439-92-1 Lead 0.02 0.02 U
1311 06/13/97 7470 06/16/97 7439-97-6 Mercury 0.0001 0.0001 U
1311 06/12/97 6010 06/17/97 7782-49-2 Selenium 0.05 0.05 U
1311 06/12/97 6010 06/17/97 7440-22-4 Silver 0.003 0.003 U
U Analyte undetected at given RL
RL Reporting Limits
FORM-I
ANALYTICAL
RESOURCES
INCORPORATED
INORGANICS ANALYSIS DATA SHEET Sample No: Method Blank
TOTAL METALS
Lab Sample ID: S739MB QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9025 Project: P9 Sed
Matrix: Soil
Date Sampled: NA
ate Received: NA
Data Release Authorize
Reported: 06/26/97
Percent Total Solids: NA
Prep Prep Analysis Analysis
Meth Date Method Date CAS Number Analyte RL mg/kg-dry
3050 06/16/97 6010 06/17/97 7440-38-2 Arsenic 5 5 U
3050 06/16/97 6010 06/17/97 7440-39-3 Barium 0.1 0.1 U
3050 06/16/97 6010 06/17/97 7440-43-9 Cadmium 0.2 0.2 U
3050 06/16/97 6010 06/17/97 7440-47-3 Chromium 0.5 0.5 U
3050 06/16/97 6010 06/17/97 7439-92-1 Lead 2 2 U
CLP 06/16/97 7471 06/17/97 7439-97-6 Mercury 0.05 0.05 U
3050 06/16/97 6010 06/17/97 7782-49-2 Selenium 5 5 U
3050 06/16/97 6010 06/17/97 7440-22-4 Silver 0.3 0.3 U
U Analyte undetected at given RL
RL Reporting Limit
FORM-I
ANALYTICAL
RESOURCES
INORGANICS ANALYSIS DATA SHEET INCORPORATED
TOTAL METALS
Lab Sample ID: S739LCS QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9025 Project: P9 Sed
Matrix: Soil
Data Release Authorized
Reported: 06/26/97
BLANK SPIKE QUALITY CONTROL REPORT
Analysis Spike Spike $
Analyte Method mg/kg-dry Added Recovery Q
Arsenic 6010 256 250 102%
Barium 6010 214 200 107%
Cadmium 6010 10.7 10.0 107%
Chromium 6010 26.0 25.0 104%
Lead 6010 103 100 103%
Mercury 7471 0.92 1.00 92.0%
Selenium 6010 267 250 107%
Silver 6010 25.3 25.0 101%
IQ, codes: N = control limit not met
Control Limits: 80-120%
FORM-VII
ANALYTICAL
RESOURCES
INCORPORATED
INORGANIC ANALYSIS DATA SHEET
TOTAL METALS
Sample No: S-1
Lab Sample ID: S739A QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9024 Project: P9 Sed
Matrix: Soil
Date Received: 06/05/97
Data Release Authorized
Reported: 06/26/97
MATRIX DUPLICATE QUALITY CONTROL REPORT
Analysis Sample Duplicate Control
Analyte Method mg/kg-dry mg/kg-dry RPD Limit Q
Arsenic 6010 6 U 6 U 0.0% +/- 6 L
Barium 6010 75.3 72.4 3.9% +/- 20 W
Cadmium 6010 0.2 U 0.2 U 0.0% +/- 0.2 L
Chromium 6010 33.1 30.9 6.9% +/- 20 %
Lead 6010 10 7 35.3% +/- 2 L*
Mercury 7471 0.05 U 0.06 U 0.0% +/- 0.05 L
Selenium 6010 6 U 6 U 0.0% +/- 6 L
Silver 6010 0.3 U 0.3 U 0.0% +/- 0.3 L
'Q' codes: * = control limit not met
L = RPD not valid, alternate limit = detection limit
FORM-VI
ANALYTICAL
RESOURCES
INORGANICS ANALYSIS DATA SHEET INCORPORATED
TOTAL METALS
Sample No: S-1
Lab Sample ID: S739A QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9024 Project: P9 Sed
Matrix: Soil
ate Received: 06/05/97
Data Release Authorize
Reported: 06/26/97
MATRIX SPIKE QUALITY CONTROL REPORT
Analysis Sample Spike Spike $
Analyte Method mg/kg-dry mg/kg-dry Added Recovery Q
Arsenic 6010 6 U 281 289 97.2%
Barium 6010 75.3 312 231 102%
Cadmium 6010 0.2 U 11.9 11.6 103%
Chromium 6010 33.1 61.7 28.9 99.0%
Lead 6010 10 121 116 95.7%
Mercury 7471 0.05 U 0.54 0.56 96.4%
Selenium 6010 6 U 303 289 105%
Silver 6010 0.3 U 27.1 28.9 93.8%
'Q' codes: N = control limit not met
H = %R not applicable, sample concentration too high
* = RPD control limit not met
NA = Not applicable - analyte not spiked
Control Limits: Percent Recovery: 75-125%
RPD: +/-20%
FORM-V
r
ANALYTICAL
RESOURCES
INCORPORATED
INORGANICS ANALYSIS DATA SHEET Sample No: Method Blank
TCLP METALS
Lab Sample ID: S739MB QC Report No: 5739-Herrera Environmental Consultant
LIMS ID: 97-9025 Project: P9 Sed
Matrix: Soil
Date Sampled: NA
Date Rece'ved: NA
Data Release Authorized:
Reported: 06/26/97
Prep Prep Analysis Analysis
Meth Date Method Date CAS Number Analyte RL mg/L
1311 06/12/97 6010 06/17/97 7440-38-2 Arsenic 0.05 0.05 U
1311 06/12/97 6010 06/17/97 7440-39-3 Barium 0.001 0.126
1311 06/12/97 6010 06/17/97 7440-43-9 Cadmium 0.002 0.002 U
1311 06/12/97 6010 06/17/97 7440-47-3 Chromium 0.005 0.005 U
1311 06/12/97 6010 06/17/97 7439-92-1 Lead 0.02 0.02 U
1311 06/13/97 7470 06/16/97 7439-97-6 Mercury 0.0001 0.0001 U
1311 06/12/97 6010 06/17/97 7782-49-2 Selenium 0.05 0.05 U
1311 06/12/97 6010 06/17/97 7440-22-4 Silver 0.003 0.003 U
U Analyte undetected at given RL
RL Reporting Limits
FORM-I
• ANALYTICAL
RESOURCES
INCORPORATED
INORGANICS ANALYSIS DATA SHEET
TCLP METALS
Sample No: S-1
Lab Sample ID: S739A QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9024 Project: P9 Sed
Matrix: Soil
D Received: 06/05/97
Data Release Authorize
Reported: 06/26/97
MATRIX DUPLICATE QUALITY CONTROL REPORT
Sample Duplicate Control
Analyte mg/L mg/L RPD Limit Q
Arsenic 0.05 U 0.05 U 0.0% +/- 0.05 L
Barium 0.580 0.602 3.7% +/- 20 %
Cadmium 0.002 U 0.003 40.0% +/- 0.002 L
Chromium 0.005 U 0.009 57.1% +/- 0.005 L
Lead 0.02 U 0.02 U 0.0% +/- 0.02 L
Mercury 0.0001 U 0.0001 U 0.0% +/- 0.0001 L
Selenium 0.05 U 0.05 U 0.0% +/- 0.05 L
Silver 0.003 U 0.003 0.0% +/- 0.003 L
'Q' codes: * = control limit not met
L = RPD not valid, alternate limit = detection limit
FORM-VI
• ANALYTICAL
RESOURCES
INORGANICS ANALYSIS DATA SHEET INCORPORATED
TCLP METALS
Sample No: S-1
Lab Sample ID: S739A QC Report No: S739-Herrera Environmental Consultant
LIMS ID: 97-9024 Project: P9 Sed
Matrix: Soil
Da eceived: 06/05/97
Data Release Authorized
Reported: 06/26/97
MATRIX SPIKE QUALITY CONTROL REPORT
Sample Spike Spike %
Analyte mg/L mg/L Added Recovery Q
Arsenic 0.05 U 5.08 5.00 102%
Barium 0.580 5.23 5.00 93.0%
Cadmium 0.002 U 0.967 1.00 96.7%
Chromium 0.005 U 4.71 5.00 94.2%
Lead 0.02 U 4.77 5.00 95.4%
Mercury 0.0001 U 0.0009 0.0010 90.0%
Selenium 0.05 U 1.11 1.00 111%
Silver 0.003 U 0.769 1.00 76.9%
'Q' codes: N = control limit not met
H = %R not applicable, sample concentration too high
* = RPD control limit not met
NA = Not applicable - analyte not spiked
Control Limits: Percent Recovery: 75-125%
RPD: +/-20%
FORM-V