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HomeMy WebLinkAboutWTR2703214_5Denis May r City Of i or Public Works Department - Gregg Zimmerman P. E., Administrator August 3, 2009 Edward McGettigan Evonik Degussa Corporation Inorganic Materials 379 Interpace Parkway, P. O. Box 677 Parsippany, NJ 07054-0677 SUBJECT: TEN YEAR SERVICE AGREEMENT - WEATHERPROOFING Dear Mr. McGettigan: Enclosed please find two signed originals of a Ten Year Service Agreement for Protectosil Chem-trete PB VOC weatherproofing for the City of Renton Hazen Reservoir project. Please execute the originals and return one signed original to me for inclusion in the City of Renton Hazen Reservoir project records. If you need additional information regarding the Hazen Reservoir project, you may contact me at 425-430-7313 or email me at tmalphrus@rentonwa.gov. Sincerely, Tom Malphrus, P.E. Water Utility Engineer H:\File Sys\WTR - Drinking Water Utility\WTR-27 - Water Project Files\WTR-27-3214 Hazen 565 Zone Reservoir Construction\Construction\Submittals\EvonikDegussa08-03-09.doc\TMaw Renton City Hall • 1055 South Grady Way • Renton, Washington 98057 • rentonwa.gov 31 EVonm INDUSTRIES TEN YEAR SERVICE AGREEMENT FOR PROTECTOSILO CHEM-TRETEO PB VOC WEATHERPROOFING with HAZEN RESERVOIR 4901 NE SUNSET BLVD. RENTON, WA 98059 Evonik Degussa Corporation Inorganic Materials 379 Interpace Parkway, P.O. Box 677 Parsippany, NJ 07054-0677 Telephone (800) 828-0919 Marketing Fax: (973) 541-8503 Evonik Degussa Corporation ("Evonik") agrees with the building owner to maintain the water repellent effect of the surface of sound concrete or masonry treated with PROTECTOSILO CHEM-TRETE® PB VOC ("PRODUCT") on the project known as: HAZEN RESERVOIR, 4901 NE SUNSET BLVD., RENTON, WA 98059 TREATED AREA(S): 365 sq. ft. / all exterior CMU block at its own expense for a period of ten (10) years from the date of application, provided that the surface has not been abraded away and that the owner gives Evonik written notice by certified mail at 379 Interpace Parkway, Parsippany, NJ 07054-0677 of any claims within thirty days of the discovery of any leaks. This Service Agreement does not include or cover any condition or damage due to water penetration caused by structural defects or movement, faulty construction or materials, cracks or joint areas requiring caulking, sealants or repointing, failure of the building, any damage to the building or contents thereof, any leakage due to mechanical damage or abuse, or any leaks or damages arising out of any improper architectural or engineering specifications relied upon or submitted to Evonik. This agreement is solely intended to cover any condition caused by defective material supplied by Evonik. It shall not include any condition caused by unusual natural occurrences or acts of God, or any condition caused by damage to the surface to which PRODUCT has been applied, or by any deliberate act or negligence. Any measurement of the water repellent effect shall be made according to Evonik standard procedures. This agreement shall be governed by and construed in accordance with the laws of the State of New Jersey. This agreement will not cover damage due to repair or subsequent work on or through the surface to which PRODUCT was applied. During the term of this agreement, Evonik, its agents or employees shall have reasonable access to the project site during normal business hours upon prior notice to Owner. This agreement is solely for the benefit of the owner of this project at the time the treatment is applied, and it does not extend to any successors or assignees of said owner. Evonik will re -issue the agreement for a new owner for the remaining term of the original agreement upon written request to Evonik from the new owner, provided such request is made within one hundred twenty days following the transfer of ownership, and providing the new owner pays the then current registration fee. This agreement becomes effective, and remains valid, only when Evonik has confirmed receipt of the Service Agreement from the owner, and when all outstanding invoices for application, supplies and services have been paid in full to Evonik, and to the contractor and material suppliers. THIS SERVICE AGREEMENT AND THE REMEDIES PROVIDED HEREUNDER ARE EXCLUSIVE AND GIVEN IN LIEU OF ALL OTHER WARRANTIES (WHETHER WRITTEN, ORAL, IMPLIED OR STATUTORY). THE PARTIES AGREE THAT ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE IS HEREBY EXCLUDED AND SHALL NOT APPLY TO GOODS SOLD. This agreement will immediately terminate and become null and void if there is any material change in the use or type of occupancy of the building. THE; I'ARTIES AGREE THAT EVONIK'S LIABILITY HEREUNDER SHALL BE IAMITEI) TO TILE COST OF LABOR AND MATERIALS INCURRED BY EVONIK OR BY AN A[1THORIZED APPLICATOR TO RESTORE THE WATER RF,I'EI.I.ENT EFFECT OF PRODUCT TO THE AREA ON WHICH IT HAS BEEN LOST. HOWEVER, EVONIK'S LIABILITY SHALL NOT EXCEED TWICE THE MATERIAI, VALUE OF THE ORIGINAL PRODUCT INVOICED BY EVONIK FOR THE PROJECT. EVONIK SHALL NOT BE LIABLE FOR ANY SURFACE PREPARATION THAT MAY BE REQUIRED PRIOR TO THE RE -APPLICATION. Evonik shall have no liability for any damage to other components of the building, nor for any consequential or incidental damages including, but not limited to, lost profits, sales or revenues, loss of use of the building, cost of capital, cost of a substitute building, facilities or services, downtime cost or claims of tenants of the building for such damages or personal injury. In the event the owner requests Evonik to investigate leakage or other related problems on this project, owner will pay to Evonik the then current fee plus expenses for the investigation. This fee will not be applicable if the investigation determines that required service is covered by this agreement. This agreement shall become void if the owner fails to pay Evonik for said investigation within thirty days of Evonik's invoice date. Any controversy or claim arising out of, or relating to, this agreement, or the breach thereof, shall be settled by arbitration in accordance with the Construction Industry Arbitration Rules of the American Arbitration Association, then obtaining, at the New Jersey Regional Offices. The award rendered by the arbitrators shall be final and judgment upon the award may be entered in any Court having jurisdiction thereof. Notwithstanding the foregoing, owner agrees that it will participate in, and be bound by any judicial, administrative or arbitration proceeding wherein the owner's participation and presence are requested by Evonik, provided that said proceeding involve a common question of law or fact, or indemnification, and further provided that said proceedings involve a third party and Evonik, even though said third party might not be specifically bound by this Service Agreement. The terms and conditions of this Service Agreement are hereby accepted. City of Renton Evonik Degussa Corporation By: By: Owner's Authorized >! epresentative Edward McGettigan, Business Manager Date of Signature Date of Signature Hazen Reservoir NoA 12441 Bartholomew Rd., Anacortes, WA 98221 RECEIVE[ (360) 293-0682 FAX (360) 293-3893 TD ` '�. ... ... .. J..AN 7.................................................... 3 �UOb.............. ILIL�o CITY OF RENTON (907) 277-1665 • FAX (907) 277-1676 UTILITY SYSTEMS TO: City of Renton 1055 South Grady W Renton, WA 98057 425-430-7313 LETTER OF TRANSMITTAL DATE 01/30/08 1 JOB NO. 878 ATTENTION: Tom Malphrus CONTRACT NO. WTR-27-3214 RE: City of Renton - Hazen Reservoir WE ARE SENDING: [X] Attached/Enclosed [ ] Under separate cover via [ ] Contracts [ ] Subcontracts [ ] Submittals [ ] Plans [ ] Copy of Letter [ ] Change Order [ ] Invoice the following items- [ ] Specifications COPIES DATE NUMBER DESCRIPTION 1 each 7.2 Coating Resubmittal - includes Manufacturers Original Warrant THESE ARE TRANSMITTED as checked below: [ ] For signature & return [X] For your use [ ] As requested [ ] Approved as submitted [ ] Approved as noted [ ] Returned for corrections [ ] For your action [ ] For your information [ ] For your completion [ ] For review, approval and comment [ ] Progress pay estimate [ ] Final release of retainage REMARKS: Thank You, SIGNED: Bonnie drodie 7 IM =�(ce Submittal #07.2 Hazen Reservoir Renton, WA - Job #878 RH2 Engineering, Inc. City of Renton Project #: WTR-27-3214 Division 9 Coating System ■ 5 year warranty from manufacturer • 2 year inspection confirmation General Contractor: T BAILEY, INC. 12441 Bartholomew. Rd. Anacortes, WA 98221 Voice 360) 293-0682 Fax 360) 293-3893 Subcontractor: Coatings Unlimited, Inc. 18420 68th Ave S #110 Kent, WA 98032 Voice 425-251-3268 Fax 425-251-3269 It is hereby certified that this equipment/material is in compliance with the contract drawings and specifications, coordination with other work on the job, and dimensional suitability. T BAILEY, INC. By Date 01 /30/08 TNEIIEC TNW, INC. 1UNPINDNI I:IIESMATIVE 3P i61AEC C:dl EA47 INMPGIAi Eta 7929 M AVENK SOUTH SCOW, 0 93109 UL! 206-762-S755 RX. 206-767-1533 W'kk-1NFA'1(.i0A1 Date: January 29, 2008 To: Bonnie Brodie T BAILEY, INC. From: Scott McConnell Subject: Manufacturers Reviews Hazen Tank Comments: Please use this letter to provide a schedule of site visits on the above referenced project. Warranty review on the 23 month Fist day and several follow up days of Surface preparation Fist day and several follow up days of coating application Final review of interior / exterior coating systems If I can help any further please give me a call. Cordially Scott McConnell Tnemec Representative CITY OF RENTON TRACKING NO. 7.2 Transmittal of Shop Drawing or Submittal For. - Hazen Reservoir CONTRACTOR: T BAILEY INC. RH2 Job No.. REN 105.049 Item covered by this submittal: Coating Systems and Applicators Refer to the following attachment(s) for a detailed description of the item. Applicable specification section(s): 9.2 and 9.4 ❑ First Submittal OR ® Resubmittal No. 2 ® This item is as specified OR ❑ This item is a substitution/or equal ❑ Supplier/Subcontractor certifies: ❑ Conforms to contract ❑ Minor deviations as specifically noted ❑ Major deviations as specifically noted Review Priority: ❑ 1 ❑ 2 ❑ 3 Due Date: Notes to Engineer:: I Date Received by Contractor: Contractor Comments: Date Returned to Subcontractor/Supplier: Deviations Specifically Noted: 2/5/2008 8:57 AM J:\Data\REN\105-049\SDC\Submittals\Submitta1007.2 - Coadngs.doc Date Received by RH2 Engineering: 1/30/08 Date Returned to Contractor: 2/5/08 Engineer's Comments: ,, i." �SS ,AM ® Reviewed ❑ Revise and Resubmit ❑ Rejected ❑ Furnish as Corrected Corrections or comments made on the shop drawings during this review do not relieve contractor from compliance with requirements of the drawings and specifications. This check is only for review of general conformance with the design concept of the project and general compliance with the information given in the contract documents. The contractor is responsible for: confirming and correlating all quantities and dimensions; selecting fabrication processes and techniques of construction; coordinating his work with that of all other trades; and performing his work in a safe and satisfactory manner. RIi2 ENGINEERING, INC. Date:2/5/08 By: Karla Secrist. Kyle Pettibone P.E. \Data\REN\105-049\SDC\Submittals\Submittal 007.2 - Coatings.doc Submittal #07.2 Hazen Reservoir Renton, WA - Job #878 RH2 Engineering, Inc. City of Renton Project #: WTR-27-3214 Division 9 Coating System • 5 year warranty from manufacturer ■ 2 year inspection confirmation General Contractor: T BAILEY, INC. 12441 Bartholomew, Rd. Anacortes, WA 98221 Voice 360) 293-0682 Fax 360) 293-3893 Subcontractor: Coatings Unlimited, Inc. 18420 68th Ave S #110 Kent, WA 98032 Voice 425-251-3268 Fax 425-251-3269 It is hereby certified that this equipment/material is in compliance with the contract drawings and specifications, coordination with other work on the job, and dimensional suitability. '._ -- f T BAILEY, INC. Dy J Date 01/30/08 :. 12441 Bartholomew Rd., Anacortes, WA 98221 .s ® .< (360) 293-0682 •FAX (360) 293-3893 s ``5 .................................................................................................... (907) 277-1665 • FAX (907) 277-1676 TO: City of Renton 1055 South Grady W Renton, WA 98057 425-430-7313 LETTER OF TRANSMITTAL DATE 01/30/08 1 JOB NO. 878 ATTENTION: Tom Malphrus CONTRACT NO. WTR-27-3214 RE: City of Renton - Hazen Reservoir WE ARE SENDING: [X] Attached/Enclosed [ ] Under separate cover via [ ] Contracts [ ] Subcontracts [ ] Submittals [ ] Plans [ ] Copy of Letter [ ] Change Order [ ] Invoice the following items: [ ] Specifications COPIES DATE NUMBER DESCRIPTION 1 each 7.2 Coating Resubmittal - includes Manufacturers Original Warranty THESE ARE TRANSMITTED as checked below [ ] For signature & return [X] For your use [ ] As requested [ ] Approved as submitted [ ] Approved as noted (] Returned for corrections [ ] For your action [ ] For your information [ ] For your completion [ ] For review, approval and comment [ ] Progress pay estimate [ ] Final release of retainage [] REMARKS: Thank You, SIGNED: Bo6nie Brodie WARRANTY NO.2008015 MANUFACTURER'S LIMITED WARRANTY WARRANTY & LIMITATION OF SELLER'S LIABILITY: Tnemec Company, Inc. hereby warrants that its coatings supplied for the project referenced herein meet the formulation standards of Tnemec Company, Inc. THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU OF ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The Buyer's sole and exclusive remedy against Tnemec Company shall be for replacement of the product in the event a defective condition of the product should be found to exist within a period of five (5) years beginning on the date of substantial completion identified herein and the exclusive remedy shall not have failed its essential purpose as long as Tnemec is willing to provide comparable replacement product to the Buyer. NO OTHER REMEDY (INCLUDING,. BUT NOT LIMITED TO INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR LOST PROFITS, LOST SALES,' INJURY TO PERSON OR PROPERTY, ENVIRONMENTAL INJURIES, OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE TO THE BUYER. TNEMEC COMPANY, INC. 6800 Corporate Drive Kansas City, MO 64120-1372 Jason Stoner Warranty Administrator Date: January 21, 2008 ■i TNEJIN.C; TNW, IN{. INDEPENDENT REPRESENTATIVE OF TNEAEEC COMPANY INCORPORATED 7929 2NO AVENJE SOUTH SEATEEE, WA 78108 TEL 206-762 5755 FAX: 206 767-7588 WWW.TNEMEC.COM Date: January 29, 2008 To: Bonnie Brodie T BAILEY, INC. From: Scott McConnell Subject: Manufacturers Reviews Hazen Tank Comments: Please use this letter to provide a schedule of site visits on the above referenced project. Warranty review on the 23 month Fist day and several follow up days of Surface preparation Fist day and several follow up days of coating application Final review of interior / exterior coating systems If I can help any further please give me a call. Cordially Scott McConnell Tnemec Representative 0 01998 GOES 34625 LITHO. IN U.S.A. All Rights Reserved Thomas Malphrus - Re: Hazen Reservoir - Coating Submittal Page 1 From: Thomas Malphrus S v� 0 0-7 To: Sled, Raymond �T Date: 11/30/2007 8:20:22 AM Subject: Re: Hazen Reservoir - Coating Submittal COGL-F'/`�t5 Ray: J Yes we did, we chose he West Hill Reservoir color. NOTIT >>> Raymond Sled 11/30/07 7:39 AM >>> Look fine did we select a color yet? I would prefer the color like west hill tank. Thanks Ray Ray Sled Water Maintenance Manager P/B/PW Maintenance Division 425-430-7400 >>> Thomas Malphrus 11/29/2007 2A9 PM >>> Ray: Attached is the coating submittal for the Hazen Reservoir Project. Please review and provide me with your comments by Dec. 13. Thanks, Tom Thomas Malphrus - Hazen Reservoir - Coating Submittal Page 1 From: Thomas Malphrus To: Pettibone, Kyle Date: 11 /30/2007 2:26:46 PM Subject: Hazen Reservoir - Coating Submittal Kyle: Ray Sled has approved the Coating Submittal, Submittal No. 7. My concerns were expressed in my earlier e-mail to you dated November 27. Thanks, Tom Thomas Malphrus - Coating Submittal Page 1 I From: Thomas Malphrus To: Pettibone, Kyle Date: 11/27/2007 3:20:43 PM Subject: Coating Submittal Kyle Please note that the coating submittals for Items 9.101, Stainless Steel In Contact With Drinking Water and 9.10.J, New Welded Steel Reservoir (Interior Coating Systems For Shop and Field) do not match the specifications. Please look at these carefully. Thanks, Tom G') CITY OF RENTON TRACKING NO. 7_1 Transmittal of Shop Drawing or Submittal Item covered by this submittal: Fora Hazen Reservoir CONTRACTOR: T BAILEY INC. RH2 Job No.: REN 105.049 Coating Systems and Applicators Refer to the following attachment(s) for a detailed description of the item. Applicable specification section(s): 9.2 and 9.4 ❑ First Submittal OR ® Resubmittal No. 1 ® This item is as specified OR ❑ This item is a substitution/or equal ❑ Supplier/Subcontractor certifies: ❑ Conforms to contract ❑ Minor deviations as specifically noted ❑ Major deviations as specifically noted Review Priority: ❑ 1 ❑ 2 ❑ 3 Due Date: Notes to Engineer:: Date Received by Contractor: Contractor Comments: Date Returned to Subcontractor/Supplier: Deviations Specifically Noted: 1/9/20081:42 PM J:\Data\REN\105-049\SDC\Submittals\Submitta1007.1 - Coatings.doc IDate Received by RH2 Engineering: 1/3/08 Date Returned to Contractor: 1/9/08 I Engineer's Comments: Provide a letter(s) confirming that the warranty period and 2-year inspection will be provided in accordance with Section 9.15 as requested per Submittal Comments 7.0 dated 12/6/2007 to complete this submittal. ❑ Reviewed ❑ Revise and Resubmit ❑ Rejected ® Furnish as Corrected Corrections or comments made on the shop drawings during this review do not relieve contractor from compliance with requirements, of the drawings and specifications. This check is only for review of general conformance with the design concept of the project and general compliance with the information given in the contract documents. The contractor is responsible for: confirming and correlating all quantities and dimensions; selecting fabrication processes and techniques of construction; coordinating his work with that of all other trades; and performing his work in a safe and satisfactory manner. RH2 ENGINEERING, INC. Date: 1/9/08 By: Karla Secrist 1/9/2008 1:42 PM J:\Data\REN\105-049\SDC\Submittals\Submittal 007.1 - Coatmgs.doc Submittal #07.1 Hazen Reservoir Renton, WA — Job #878 RH2 Engineering, Inc. City of Renton Project #: WTR-27-3214 Division 9 Coating System response to previous review comments, includes sample warranty from applicator General Contractor: T BAILEY, INC. 12441 Bartholomew; Rd. Anacortes, WA 98221 Voice 360) 293-0682 Fax 360) 293-3893 Subcontractor: Coatings Unlimited, Inc. 18420 68th Ave S #110 Kent, \NA 98032 Voice 425-251-3268 Fax 425-251-3269 It is hereby certified that this equipment/material is in compliance with the contract drawings and specifications, coordination with other work on the job, and dimensional suitability. T BAILEY, INC. By J' Date 01/03/08 r � ' APPLICATOR'S LIMITED WARRANTY WARRANTY & LIMITATION OF APPLICATOR'S LIABILITY: Coatings Unlimited Inc. hereby warrants that its surface preparation and application of the Tnemec Coatings as manufactured by Tnemec Company were in accordance with the manufacturer's recommendations for the project referenced herein. (Hazen Reservoir) THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU OF ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The owner's sole and exclusive remedy against Coatings Unlimited shall be for surface preparation and re- application in the event a defective condition should be found to exist within a period of one (5) years beginning on the date of substantial completion identified herein. NO OTHER REMEDY (INCLUDING, BUT NOT LIMITED TO INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR LOST PROFITS, LOST SALES, INJURY TO PERSON OR PROPERTY, ENVIRONMENTAL INJURIES, OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE TO THE OWNER. COATINGS UNLIMITED INC. By: 18420 68th Avenue S, Suite 110 Kent, WA 98032 (425) 251-3268 Date: Greg Snider, President TNEME(: TNW, INC. INDEPENDENT REPRESENTATIVE OF TNFAAEC COMPANY INCORPORATED 7929 2NO AVENUE SOUTH SEATTLE, WA 98108 TEL: 206 762-5755 FAR: 206-767 7588 WWW.TNEMEC.COM Date: January 3, 2008 To: Michael Jackson From: Scott McConnell Subject: Hazen Reservoir Comments: Please review the following response and corrections to the submittal review dated 12/6/07 from Kyle Pettibone of RH2 Engineers. 1. Finish coat for system 9.10.E has been changed to Series 141 PotaPox 80 per the specifications. 2. Finish coat for system 9.10.1 utilizes the film build characteristics of the submitted Series N69 Epoxoline II to attain the specified dry film thickness of 6-8 mils. 3. Surface preparations for 9.10.J New Welded Steel Reservoir are included for both shop and field requirements, interior and exterior surfaces. 4. Hold backs during shop priming are included in the submittal per the contract documents. 5. Interior coating system per 9.10.J New Welded Steel Reservoir is submitted to reflect the contract documents. 6. Performance criteria required in section 9.10.J New Welded Steel Reservoir for interior and exterior coating systems are included in this submittal package. TNW, INC. INOEPENOENT RfPRESENTAIM OF TNENFC COMPANYINCORFORATEO 7929 1N0 AVENUE SOUTH SEATTLE, WA 90108 TEL 206-762-5755 EAX: 206-767-7588 19WW.INEMICUM January 3, 2008 Michael Jackson T Bailey / San Juan Blast Cleaning and Coatings, Inc. 12441 Bartholomew Rd Anacortes, WA 98221 Project: Subject: Scott McConnel Hazen 4.22 MG Reservoir Tnemec Material Submittal Tnemec Sales Representative T1t1"1, 111(. INOTFEN0011 REFREST4 AIM OF TrFuft fOA FAN4 1401PORAT0 7929 ?ND AVENUE SOUTN SEATTLE, WA 98108 TEE: 206.761.5755 FAX: 106.767.7SOO WMINEMECUM January 3, 2008 Michael Jackson T Bailey / San Juan Blast Cleaning and Coatings, Inc. 12441 Bartholomew Rd Anacortes, WA 98221 Project: Hazen 4.22 MG Reservoir Subject: Material Submittals Mr. Jackson Please review the following submittal information for use on the above project. Division 9 Finishes 9.10 Materials - Field Applied B. Metal (Wet Interior Conditions/Non-Submerged) Surface preparation: SP10 Near White Blast Primer: Tnemec Series 394 Perimeter Prime 2.5 to 3.5 Mil DFT Intermediate: Tnemec Series N69 Epoxoline II 6 to 8 Mil DFT Finish: Tnemec Series N69 Epoxoline II 6 to 8 Mil DFT C. Metals Exterior (Wet Conditions) Surface preparation: SP6 Commercial Blast Primer: Tnemec Series 394 Perimeter Prime 2.5 to 3.5 Mil DFT Finish: Tnemec Series 73 EnduraShield 3 to 5 Mil DFT D. Metals (Dry Conditions) Surface preparation: SP-6 Commercial blast Primer: Tnemec Series 394 Perimeter Primer 2.5 to 3.5 Mil DFT Finish: Tnemec Series N69 Epoxoline H 4 to 6 Mil DFT E. Mild Steel and Iron In Contact With Drinking Water Surface preparation: Ferrous Metal SP10 Near White Blast Ductile Iron SP10 Gray White Blast Primer: Tnemec Series N140 Pota-Pox Plus 6 to 8 Mil DFT Finish: Tnemec Series N140 Pota-Pox Plus 6 to 8 Mil DFT F. Stainless Steel In Contact With Drinking Water Surface preparation: Sweep blast to provide surface profile of 1 — 2 mils Primer: Tnemec Series 20/FC20 Pota-Pox 4 to 6 mil DFT Finish: Tnemec Series 141 Pota Pox 80 6 to 8 mil DFT G. Galvanized Iron and Non Ferrous Metal (non -immersion) Surface Preparation: SP1 Solvent clean Drain pipe prior to painting Two coats Tnemec Series 30 Spra-Saf 2 to 4 Mil DFT each coat H. Concrete Vault Interior Concrete Coat interior concrete floors, walls, ceiling, equipment, and housekeeping pads. Surface Preparation: Allow 28 days cure time for concrete, or until passing the ASTM D 4263 Plastic Mat Test. Surface shall be clean, dry, and free of contaminants Primer: Tnemec Series 66 Hi -Build Epoxoline 4.0 to 6.0 Mil DFT Finish: Tnemec Series 73 Endura-Shield 3.0 to 5.0 Mil DFT Exterior Concrete (Below Grade) Surface preparation: SP7 Sweep Blast (Blue Gray) One coat Tnemec Series 46H-413 Hi -Build Tnemec-Tar applied at 16-20 Mil DFT I. Ductile Iron Pipe (Exposed) Pipe shall be emptied of water for a minimum of 12 hours prior to surface preparation and painting. Pipe shall not be filled with water until coating is dry. Non -submerged pipe surface preparation SSPC-SP-6 (commercial blast) Submerged pipe surface preparation SSPC-SP-10 (white blast) One coat Tnemec Series 69 Epoxoline H 6 to 8 Mil DFT One coat Tnemec Series 69 Hi -Build Epoxoline I16 to 8 Mil DFT J. New Welded Steel Reservoir Coating System Interior (Shop) Surface Preparation All surfaces to be coated shall be prepared per SSPC-SP-10 Near White Blast cleaning. Prime all prepared surfaces with one coat of Tnemec Series 91H20 at 2.5 to 3.5 mils DFT. Hold back coatings within 2 to 4 inches of edges or ends to be welded. Feather primer and paint out as required for a smooth finished product. Coating System (Field) Surface Preparation All welded and abraded areas shall be prepared per SSPC-SP-10 Near White Blast cleaning Primer: Coat all prepared areas with Tnemec Series 91H20 2.5 to 3.5 mil DFT Finish: Tnemec Series 141 Pota Pox 80 10 to 12 mil DFT NOTE: During application of either prime or finish coats, brush all welds seams with freshly sprayed paint. Minimum total dry film thickness shall be 12.5 mils. Coating System Exterior (Shop) Surface Preparation All surfaces to be coated shall be prepared per SSPC-SP-10 Near White Blast cleaning. Prime all prepared surfaces with one coat of Tnemec Series 91 H2O at 2.5 to 3.5 mils DFT. Hold back coatings within 2 to 4 inches of edges or ends to be welded. Feather primer and paint out as required for a smooth finished product. Coating System Exterior (Field) Surface Preparation All welded and abraded areas shall be prepared per SSPC-SP-10 Near White Blast cleaning. Primer: Coat all prepared areas with Tnemec Series 91H20 2.5 to 3.5 mil DFT Intermediate: One coat Tnemec Series 66/161 Hi -Build Epoxoline 4 to 6 mil DFT Finish: One coat Tnemec Series 73 Endura-Shield 3 to 5 Mil DFT NOTE: Minimum total dry film thickness shall be 9.5 mils. Colors will be as stated on specifications sheet 9-4, reservoir interior color Tank White 15BL, exterior reservoir color Cumulus 78GN. For any additional colors for value piping please visit Tnemec.com color palette littp://www.tnemee.com/product/colors/ Buried Welded Steel Pipe Potable Service Exterior Coating Shop Surface Preparation: SP10 Near White Blast Cleaning One Coat: Tnemec Series 141 PotaPox 80, applied at 12 to 15 mils DFT Interior Coating Shop Surface Preparation: SP10 Near White Blast Cleaning Prime Coat: Tnemec Series 141 PotaPox 80, applied at 6 to 8 mils DFT Finish Coat: Tnemec Series 141 PotaPox 80, applied at 6 to 8 mils DFT If you have any question, or I can be of further assistance please feel free to give me a call. Cor y, ' ;7(L4 Scott McConnell Tnemec Regional Representative PERFORMANCE CRITERIA (Confidential — DO NOT DUPLICATE) ABRASION Method: ASTM D 4060, (CS-17 Wheel, 1,000 gram load). System: Series 66 Hi -Build Epoxoline/Series 73 Endura-Shield applied to SSPC-SP10 Near -White Metal Blast Cleaned steel and cured 28 days at 75°F (24°C). Requirement: No more than 96 mg loss after 1,000 cycles. (TR5138) ADHESION Method: ASTM D 3359, (Method B, 5 mm Crosshatch). Systems: Applied to SSPC-SP10 Near -White Metal Blast Cleaned steel and cured 28 days at 75°F (24°C): 1) Series 66 Hi -Build Epoxoline/Series 73 Endura-Shield. 2) Series 530 Omnithane/Series 73 Endura-Shield. 3) Series 104 H.S. Epoxy/Series 73 Endura-Shield. 4) Series 90-97 Tneme-Zinc/Series 73 Endura-Shield. Requirement: No less than a rating of 5. (TR1586) Method: ASTM D 4541 (Method B, Type ll). Systems: Applied to SSPC-SP10 Near -White Metal Blast Cleaned steel and cured 14 days at 75°F (24oQ: 1) Series 66 Hi -Build Epoxoline/Series 73 Endura-Shield. Requirement: No less than 1,466 psi (10.11 MPa) pull, average of three tests. (TR5123) 2) Series 90-97 Tneme-Zinc/Series 73 Endura-Shield. Requirement: No less than 1,167 psi (8.04 MPa) pull, average of three tests. (TR5127) Method: ASTM D 4541 (Method E, Type V). Systems: Applied to SSPC-SP10 Near -White Metal Blast Cleaned steel and cured 14 days at 75°F (24oQ: 1) Series 66 Hi -Build Epoxoline/Series 73 Endura-Shield. Requirement: No less than 2,040 psi (14.06 MPa) pull, average of three tests. (TR5124) 2) Series 90-97 Tneme-Zinc/Series 73 Endura-Shield. Requirement: No less than 1,830 psi (12.62 MPa) pull, average of three tests. (TR5128) DR EXPG Method: ASTM D 4141, Method C (EMMAQUA) System: Series 66 Hi -Build Epoxoline/Series 73 Endura-Shield applied to SSPC-SP1 Solvent Cleaned aluminum panels. Requirement: No blistering, cracking or chalking. No less than 86% gloss retention (8 units gloss change) and 0.23 DED Hunter Lab Scale color change after 500 MJ/mz exposure. (TR5272) Method: Exposed at 45 degrees facing south. Location: South Florida and Kansas City. System: Series 66 Hi -Build Epoxoline/Series 73 Endura-Shield (white) applied to SSPC-SP1 Solvent Cleaning and cured 7 days. Requirement: No blistering, cracking, chalking or delamination of film. No more than 4.08 MacAdam units color change after five years exposure in Kansas City. No more than 4.33 MacAdam units color change after four years exposure in Florida. (TR5116, TR5117) Method: ASTM D 522 (Method A, Conical Mandrel). System: Series 135 Chembuild/Series 73 Endura-Shield applied to SSPC-SP7 Brush -Off Blast Cleaning and cured 7 days at 75°F (24°C). Requirement: No less than 19.05% elongation, average of three tests. (TR5120) Method: ASTM D 522 (Method B, Cylindrical Mandrel). System: Series 135 Chembuild/Series 73 Endura-Shield applied to SSPC-SP7 Brush -Off Blast Cleaning and cured 14 days at 75°F (24°C). Requirement: No cracking or delamination of film. No less than 39.0% elongation, average of three tests. (TR5121) This product will meet or exceed the above lest requirements established for the coating systems listed. Test performance results were obtained in a controlled environment and Tnemec Company makes no claim that these tests or any other tests accurately represent all environments. As application, environmental and design factors can vary significantly, due care should be exercised in the selection and use of the coating. Published technical data is subject to change without notice. For additional performance criteria and specific test results, contact Tnemec Company or its representative. TNEMEC COMPANY INCORPORATED © August 5, 2005 6800 CORPORATE DRIVE, KANSAS CITY, MISSOURI 64120.1372 TEL: 816 4833400 Page 1 of 2 (YPFC073) PRINTED IN USA •AFITTI RESISTANCE Method: The following graffiti materials applied to coating and allowed to dry for seven days. System: Series 66 Hi -Build Epoxoline/Series 73 Endura-Shield applied to SSPC-SP7/NACE 4 Brush - Off Blast Cleaned steel and cured 30 days at 75°F (24°C). Reagent Series 680 Xylene MEK Acrylic Spray Paint Removal Removal Removal Alkyd Spray Paint Removal Removal Faint Shadow Epoxy Spray Paint Removal Removal Removal Crayon Removal Removal Removal Lipstick Removal Removal Removal Note: Some slight gloss loss and/or softening may occur depending on the amount of effort required for removal of the graffiti and length of exposure of the underlying coating to the cleaning solvents. (rR5342) HUMIDITY IMPACT Method: ASTM D 4585. Systems: Applied to SSPC-SP10 Near -White Metal Blast Cleaned steel and cured 14 days at 75°F (24°C): 1) Series 66 Hi -Build Epoxoline/Series 73 Endura-Shield. (TR5131) 2) Series 91-H2O Hydro-Zinc/Series 73 Endura-Shield. JR5129) 3) Series 91-H2O Hydro-Zinc/Series 66 Hi -Build Epoxoline/Series 73 Endura-Shield. (TR5130) Requirement: No blistering, cracking, rusting or delamination of film after 2,000 hours exposure. Method: ASTM D 2794. System: Series 135 Chem buiId/Series 73 Endura-Shield applied to SSPC-SP7 Brush -Off Blast Cleaned steel and cured 14 days at 75°F (24°C). Requirement: No cracking or delamination of film after 29 inch -pounds (3.3 J) direct impact, average of three tests. (TR5132) FL'ROHESION Method: ASTM G 85 (Annex A5). System: Series N69 Hi -Build Epoxoline II/Series 73 Endura-Shield applied to SSPC-SP10 Near -White Metal Blast Cleaned steel and cured 14 days at 75°F (24°C). Requirement: No blistering, cracking, checking, rusting or delamination of film. No more than 3/16 inch (5.0 mm) rust creepage at scribe after 15,000 hours exposure. (TR5119) 1tUV EXPOSURE Method: ASTM D 4587 (UVA-340 bulbs, Cycle 4: 8 hours UV/4 hours condensation). System: Series 66 Hi -Build Epoxoline/Series 73 Endura-Shield. Requirement: No blistering, cracking, chalking or delamination. No more than 2.6 DED FMCII (MacAdam units) color change after 2,000 hours exposure. (TR5116) Method: ASTM B 117. System: Series 530 Omnithane/Series 73 Endura-Shield applied to SSPC-SP10 Near -White Metal Blast Cleaned steel and cured 10 days at 75°F (24°C). Requirement: No blistering, cracking, rusting or delamination of film. No rust creepage at scribe after 2,000 hours exposure. (TR1563) System: Series 66 Hi -Build Epoxoline/Series 73 Endura-Shield applied to SSPC-SP10 Near -White Metal Blast Cleaned steel and cured 10 days at 75°F (24°C). Requirement: No blistering, cracking, rusting or delamination of film. No more than 1/16" (1.6 mm) rust creepage at scribe after 1,000 hours exposure. (TR1585) System: Series 90-97 Tneme-Zinc/Series 73 Endura-Shield applied to SSPC-SP10 Near -White Metal Blast Cleaned steel and cured 10 days at 75°F (24°C). Requirement: No blistering, cracking, rusting or delamination of film. No more than 1/16" (1.6 mm) rust creepage at scribe after 3,000 hours exposure. (TR3026) SURFACE BURNING CHARACTERISTICS Independent laboratory tests conducted in accordance with ASTM E 84 have been conducted on various coating systems that included one or more coats of Series 73 Endura-Shield. All systems meet the NFPA (National Fire Protection Association) No. 101, Class A requirements pertaining to Flame Spread and Smoke Density. Test results are available upon request. Test performance results were obtained in a controlled environment and Tnemec Company makes no claim that these test results will reflect hazards presented under actual fire conditions. Page 2 of 2 PERFORMANCE CRITERIA (Confidential — DO NOT DUPLICATE) ADHESION Method: ASTM D 4541 (TTM-34) Type II Fixed Alignment Adhesion Tester. System: Series 91-H2O Hydro -Zinc applied to SSPC-SP10 Near -White Blast Cleaned steel. Requirement: No less than 1,516 psi (10.46 MPa) adhesion, average of three tests. Meth • ASTM D 4541 (TTM-34) Type V Self -Aligning Adhesion Tester. ® System: Series 91-H2O Hydro -Zinc applied to SSPC-SP10 Near -White Blast Cleaned steel. Requirement: No less than 2,083 psi (14.36 MPa) adhesion, average of three tests. CATHODIC Method: ASTM G8, Method A. System: One coat 91-H2O Hydro-Zinc/one coat Series 20 Pota-Pox applied to SSPC-SP10 Near -White Blast Cleaned hot rolled carbon steel. Requirement: No blistering, cracking, rusting or delamination and no undercutting at holiday after 30 days exposure. PROTECTIONGALVANIC HUMIDITY IMMERSION Metho • A 91-H2O coated steel panel containing several holidays is placed in a container of tap water. The panel's potential is measured by a voltmeter with the positive (+) pole attached to a bare spot on the panel above the water line and the negative (-) pole attached to an Ag/AgC1 reference electrode immersed in the tap water. System: Series 91-H2O Hydro -Zinc applied to SSPC-SP10 Near White Blast Cleaned hot rolled carbon steel. Significance: True theoretical galvanic action of the zinc having actual zinc -to -zinc contact would show a potential of -1100 millivolts. A range of -1100 millivolts to -750 millivolts would indicate galvanic action is occurring. The optimum potential is -850 millivolts. A potential of -500 millivolts or less would indicate that the coating is only acting as a barrier coating. Results: The average measured potential of 91-1-12O is -878 millivolts. Method: TTM-103 Test for Galvanic Measurement of Zinc -Rich Coatings. System: Series 91-H2O Hydro -Zinc applied at 3.0 mils DFT to a SSPC-SP10/NACE 2 Near -White Blast Cleaned steel panel. Significance: Galvanic protection is considered adequate if the polarized potential of at least -850 mV is achieved relative to a CSE. Polarized potential of less than -750 mV would indicate that the coating is only acting as a barrier coating. Results: The average measured galvanic potential of Series 91-H2O Hydro -Zinc is -1108 mV relative to a saturated copper/copper sulfate (CSE) reference electrode. Method: ASTM D 4585. System: Series 91-H2O Hydro-Zinc/Series 20 Pota-Pox/Series 1075 Endura-Shield II applied to SSPC- SP10 Near -White Blast Cleaned steel cured 7 days at 75aF (24aC). Requirement: No blistering, cracking, rusting or delamination of film after 4,000 hours exposure. etho • ASTM D 870. System: Series 91-H2O Hydro-Zinc/Series 20 Pota-Pox applied to SSPC-SP10 Near -White Blast Cleaned steel. Requirement: No blistering, cracking, rusting or delamination of film after seven years immersion. Method: Sea water immersion of coated angle iron panels at Wrightsville Beach, NC. System: Series 91-H2O Hydro-Zinc/Series 20 Pota-Pox/Series 20 Pota-Pox applied to SSPC-SP10 Near White Blast Cleaned steel. Requirement: No blistering, cracking, rusting or delamination of film after two years exposure. This product will meet or exceed the above test requirements established for the coating systems listed. Test performance results were obtained in a controlled environment and Tnemec Company makes no claim that these tests or any other tests accurately represent all environments. As application, environmental and design factors can very significantly, due core should be exercised in the selection and use of the coating. Published technical date is subject to change without notice. For additional performance criteria and specific test results, contact Tnemec fompony or its representative. TNEMEC COMPANY INCORPORATED ® July 19, 2007 6800 CORPORATE DRIVE, KANSAS CITY, MISSOURI 64120-1372 TEL: 816 483-3400 Page 1 of 2 PRINTED IN USA PROHESION Method: ASTM G 85 Prohesion Cabinet Testing. Systems: Series 91-H20 Hydro-Zinc/Series FC20 Pota-Pox/Series 20 Pota-Pox applied to SSPC-SP10 Near -White Blast Cleaned steel cured 14 days. Requirement: No blistering, cracking, rusting or delamination of film. No more than 1/64" creepage at scribe after 15,000 hours. TIME/ADHESIONRECOAT Method: 91-H20 steel panels were exposed to direct sunlight for one week, two weeks, one month, three months and six months. One set of panels was topcoated (without scarification) with a Tnemec two -component epoxy and another set with Endura-Shield. All panels were then exposed to 10 freeze/ thaw cycles and adhesion rated in accordance with ASTM D 3359, Method B (Crosshatch). System: One coat Series 91-H20 Hydro-Zinc/one coat Series 20 Pota-Pox. System: One coat Series 91-1-120 Hydro-Zinc/one coat Endura-Shield. Requirement: No less than 5B rating for epoxy system and no less than 4B rating for Endura-Shield system. TIME/IMMERSIONRECOAT Method: 91-1420 steel panels were exposed to direct sunlight for one, three, six and twelve months prior to topcoating (without scarification) with a Tnemec two -component epoxy. The panels were then placed in potable water immersion for 12 months. Surface Preparation: Substrate (hot rolled carbon steel)—SSPC-SP10 Near -White Blast Cleaned. Be- tween Coats —Dry and clean. System: One coat Series 91-1-120 Hydro-Zinc/one coat Series 20 Pota-Pox. Requirement- No rusting, blistering, delamination or any other film defects after 12 months immersion. SALT SPRAY (FOG) Me • ASTM B 117. System: Series 91-H20 Hydro-Zinc/Series 20 Pota-Pox/Series 700 HydroFlon applied to SSPC-SP10 Near -White Blast Cleaned steel and cured 7 days at 750F (240C). Requirement: No blistering, cracking or delamination of film. No more than 1/32" rust creepage at scribe after 10,000 hours exposure. System: Series 91-H20 Hydro-Zinc/Series FC20 Pota-Pox (Fast Cure)/Series 20 Pota-Pox applied to SSPC-SP10 Near -White Blast Cleaned steel and cured 14 days. Requirement: No blistering, cracking or delamination of film. No more than 1% rusting on plane and no more than 1/4" rust creepage at scribe after 20,000 hours. System: Series 91-H20 Hydro -Zinc applied to SSPC-SP10 Near -White Blast Cleaned steel cured 14 days at 750F (241C). Requirement: No blistering, cracking or delamination of film. No more than 1/8" creepage at scribe and no more than 1% rusting on plane after 50,000 hours exposure. STATIC FATIGUE (SLIP COEFFICIENT & TENSION CREEP) Method: Tests conducted in conformance with AISC specification using equipment as described in the Research Council on Structural Connections Spccifications, Appendix A, Section 4.1. System: One coat Series 91-H20 Hydro -Zinc. Requirement: Meets the requirements of a Class B surface with a mean slip coefficient no less than 0.50 and a tension creep not in excess of .005 inch (13 mm). Page 2 of 2 S SS PRODUCT PROFILE GENERIC DESCRIPTION Aromatic Polyurethane, Mio-Zinc Filled Primer COMMON USAGE Specially formulated, one -component, moisture -cured, micaceous iron oxide and zinc filled primer that offers superior bonding to marginally prepared rusty steel and tightly adhered old coatings. This high performance primer is ideal for corrosion resistance with a triple barrier mechanism of zinc, mio and urethane resin built into the dry film. It is suitable as a corrosion resistant primer under certain fireproofing systems. Contact your Tnemec representative for specific information. COLOR Grayish -Green SPECIAL QUALIFICATIONS UL classified in accordance with UL 263 (ASTM E 119). Meets material adhesion test ASTM E 736 for use under various fire -resistive products. Contact your Tnemec representative for specific informa- tion. Meets AISC requirements for Class B surface with a mean slip coefficient no less than 0.50 and tension creep not in excess of .005 inches (.13 mm) (SSPC-SP5/NACE 1 & SSPC-SP3). Note: Using other products as primers or topcoats voids AISC requirements. PERFORMANCE CRITERIA Contact your Tnemec representative for specific test results. COATING SYSTEM PRIMERS Self -priming TOPCOATS Series 25, 27, 35, 66, N69, N69F, 73, 113, 114, 115, 161, 1028, 1029, 1074 & 1075. Note: if Series 394 is exterior exposed for 1 year or more it must be scarified or recoated with itself before topcoating. Scarification or recoating with itself is required if the Series 394 has been exterior exposed for 3 days or longer and Series 113 is the specified topcoat. Note: Series 25, 35 and 115 re- quire the use of Series 44-900 adhesion promoter when topcoating Series 394. Note: Certain topcoat colors may not provide one coat hiding depending on method of application. Contact your Tnemec representative. SURFACE PREPARATION 1 STEEL Enclosed or Fireproofed: SSPC-SP3 Power Tool Cleaning. Moderate Exterior Exposure: Abrasive blast cleaning generally produces the best coating per- formance. If conditions won't permit this, Series 394 may be applied to SSPC-SP2 or SP3 Hand or Power Tool Cleaned surfaces. Immersion & Severe Exposure: SSPC-SP10/NACE 2 Near -White Blast Cleaning. Slip Critical Connections: SSPC-SP5/NACE 1 White Metal Blast Cleaning or SSPC-SP3 Power Tool Cleaning. ALL SURFACES Must be clean and free of oil, grease and other contaminants. TECHNICAL DATA VOLUME SOLIDS 61.0 ± 2.0% (mixed) RECOMMENDED DFT 2.5 to 3.5 mils (65 to 90 microns) per coat. CURING TIME Without 44-710 Temperature* To Handle To Recoat 70°F (21°C) lr/a hours 4 hours 60°F (16°C) 23/4 hours 6 hours 50OF (10°C) 5 hours 10 hours 40OF (4°C) 73/4 hours 16 hours *50% Relative Humidity. Curing time will vary with surface temperature, humidity and film thickness. Note: When recoating Series 394 with topcoats other than itself, the minimum recoat time is 16 hours. With 44-710 The use of 44-710 can greatly reduce recoat times. Reference the 44-710 Urethane Accelerator prod- uct data sheet. VOLATILE ORGANIC Unthinned Thinned 10% Thinned 10% COMPOUNDS (No. 2 or 3'Thinner) (No. 49 Thinner) 2.76lbs/gallon 3.181bs/gallon 2.761bs/gallon (330 grams/litre) (381 grams/litre) (330 grams/litre) HAPS 0.00 lbs/gal solids 1.19 lbs/gal solids 0.04 lbs/gal solids 0.00 lbs/gal solids (No. 2 Thinner) (No. 3 Thinner) THEORETICAL COVERAGE 978 mil sq ft/gal (24.0 m'-/L at 25 microns). See APPLICATION for coverage rates. NUMBER OF COMPONENTS One PACKAGING Five -gallon (18.9L) pails (yielding 3 gallons) and one -gallon (3.79L) cans NET WEIGHT PER GALLON 21.2 ± 0.60 lbs (9.61 ± .27 kg) STORAGE TEMPERATURE Minimum 20°F (-7°C) Maximum 1107 (43*C) Published technical data and instructions ore subject to change without notice. The online catalog at www.tnemec.com should be referenced for the most current technical data and instructions or you may contact your Tnemec representative for current technical data and instructions. 0 October 17, 2006, by Tnemec Company, Inc. 394 TECHNICAL DATA continued TEMPERATURE RESISTANCE (Dry) Continuous 250*F (121°C) Intermittent 300°F (149°C) SHELF LIFE 6 months at recommended storage temperature. FLASH POINT - SETA 85°F(290C) HEALTH 8 SAFETY Paint products contain chemical ingredients which are considered hazardous. Read container label warning and Material Safety Data Sheet for important health and safety information prior to the use of this product. Keep out of the reach of children. APPLICATION COVERAGE RATES Dry Mils (Microns) Wet Mils (Microns) Sq Ft/Gal (mz/Gal) Suggested 3.0(75) 5.0(125) 326 (30.3) Minimum 2.5 (65) 4.0(100) 391 (36.4) Maximum 3.5(90) 5.5 040) 284 (26.4) Allow for overspray and surface irregularities. Wet film thickness is rounded to the nearest 0.5 mil or 5 microns. Application of coating below minimum or above maximum recommended dry film thicknesses may adversely affect coating performance. MIXING Stir thoroughly making sure no pigment remains on the bottom of the can. Use a power mixer and keep material under constant agitation while mixing. POT LIFE 24 hours at 77*F (25°C) and 50% R.H. Caution: This product cures with moisture acting as a catalyst. Incorporation of moisture or moisture laden air (humidity) during use will shorten pot life. The use of a solvent blanket (small addition of solvent that sits atop the paint in the can) can help to retard a reaction with moisture in the container but agitation will have to be done by manual means, taking care to not disturb the solvent or incorporate it into the paint. Avoid continual agitation at high RPM. When feasible keep containers of material covered during use. THINNING For spray, thin up to 10% or 3/4 pint (380 mL) per gallon with No. 2 Thinner if temperatures are below 80°F (27°C). Thin up to 10% or 3/4 pint (380 mL) per gallon with No. 3 Thinner if temperatures are above 80°F (270C). For brush or roller, thin up to 10% or 3/4 pint (380 mL) with No. 3 Thinner. Note: No. 49 Thinner may be substituted where there are VOC restrictions. SURFACE TEMPERATURE Minimum 350F (2°C) Maximum 120OF (49°C) The surface should be dry and at least 50F (3°C) above the dew point. AMBIENT HUMIDITY Minimum 40% Maximum 90% APPLICATION EQUIPMENT Note: When intermediate and finish coats are white or light colors, best hiding of this primer can be achieved by spray application; or when roller applied, by using V4" synthetic woven nap covers. Air Spray Gun Fluid Air Cap I Air Hose MaVI Hose Atomizing I Pot Tip ID ID Pressure Pressure DeVilbiss * E 765 or 5/16" or 3/8" 3/8" or 1/2" 1 40-50 psi 10-20 psi JGA 704 1 (7.9 or 9.5 mm) (9.5 or 12.7 mm) 1 (2.8-3.4 bar) (0.7-1.4 bar) * (with heavy mastic spring) Low temperatures or longer hoses will require additional pressure. Use pressure pot equipped with an agitator and keep pressure pot at same level or higher than the spray gun. Compressed air must be dry. Airless Spray Tip Orifice Atomizing Pressure Mat'1 Hose ID Manifold Filter 0.017-0.021" 2400-3000 psi 1/4" or 3/8" 60 mesh (430-535 microns) (165-207 bar) (6.4 or 9.5 mm) (250 microns) Reversible Tip Use appropriate tip/atomizing pressure for equipment, applicator technique and weather conditions. Roller: Use a 1/4" or 3/8" (6.4 nun or 9.5 mm) synthetic woven nap roller cover. Brush: Use high quality natural or synthetic bristle brushes. CLEANUP Flush and clean all equipment immediately after use with the recommended thinner or xylene. WARRANTY & LIMITATION OF SELLER'S LIABILITY: Tnemec Company, Inc. warrants only that its coatings represented herein meet the formulation standards of Tnemec Company, Inc. THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU OF ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The buyer's sole and exclusive remedy against Tnemec Company, Inc. shall be for replacement of the product in the event a defective condition of the product should be found to exist and the exclusive remedy shall not have failed its essential purpose as long as Tnemec is willing to provide comparable replacement product to the buyer. NO OTHER REMEDY (INCLUDING, BUT NOT LIMITED TO, INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR LOST PROFITS, LOST SALES, INJURY TO PERSON OR PROPERTY, ENVIRONMENTAL INJURIES OR ANY OTHER INCIDENTAL OR (ONSEOUENTIAL LOSS) SHALL BE AVAILABLE 70 THE BUYER. Technical and application information herein is provided for the purpose of establishing a general profile of the coating and proper coating application procedures. Test performance results were obtained in o controlled environment and Tnemec Company makes no claim that these tests or any other tests, accurately represent all environments. As application, environmental and design factors can vary significantly, due cote should be exercised in the selection and use of the coating. FOR INDUSTRIAL USE ONLY. TNEMEC COMPANY INCORPORATED PRINTED IN USA 6800 CORPORATE DRIVE, KANSAS CITY, MISSOURI 64120-1372 TEL: 1 800 TNEMEC 1 www.tnemec.com (YDAT394) 394 Tnemec Company, Inc. For coatings, resins and related materials, approved by 123 West 23rd Avenue, Kansas City, MO 64116-3064 Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to Emergency Telephone: 800-535-5053 (INFOTRAC) form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. Telephone: 816-474-3400 NPCA 1-84 PREPARED DATE: 07/22/2003 Series: F394-0394 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS AROMATIC HYDROCARBON MIXTURE TALC (RESPIRABLE DUST) DIPHENYLMETHANE DIISOCYANATE (MDI) MONOMER** IRON OXIDE FUME DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER 1,2,4-TRIMETHYLBENZEN E** ZINC (TOTAL DUST)-- ** SARA Reportable Product Product Class: ISOCYANATE VAPOR PRESS. MMHG CAS# % By Wt. @ 68 ° F 64742-95-6 6-10 14807-96-6 1-5 101-68-8 2.08 1309-37-1 41-50 6-10 95-63-6 3.68 7440-66-6 27.47 SERIES 394 PERIMIPRIME OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0002.000 MG/M3 0000.005 PPM 0005.000 MG/M3 0025.000 PPM MFG REC 0010.000 MG/M3 Page 1 of 3 OSHA PEL-TWA PEL-STEL PEL-C 0002.000 MG/M3 0000.020 PPM 0010.000 MG/M3 0025.000 PPM MFG REC 0015.000 MG/M3 This substance contains a material classified as a hazardous air pollutant. This product contains no reported carcinogens or suspected carcinogens. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. Contains isocyanate monomer. If subject to spray application, engineering and administrative controls must be instituted to maintain an exposure level below .005ppm. If these controls are not adequate, the use of an air -supplied respirator is mandatory. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. SKIN: Moderate irritation, drying of skin, defatting and possible dermatitis. Allergic skin responses. Discoloration. INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION -OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. Inhalation of metallic zinc dust may result in symptoms known as metal fume fever. Symptoms include chills, fever, muscular pain, nausea and vomiting. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged contact or repeated exposure to isocyanate concentrations greater than the recommended TLV may result in permanent respiratory and skin sensitization. Once diagnosed as being sensitized to isocyanates, no further exposure can be permitted. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. TARGET ORGANS: Can cause eye damage. Can cause skin irritation. Can be corrosive to respiratory tract. Can cause lung damage. Can be corrosive to gastrointestinal tract. Can cause nervous system effects. Can cause respiratory tract sensitization. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure to isocyanate products may aggravate persons with asthmatic type conditions, chronic bronchitis, other chronic respiratory diseases, skin eczema, or skin sensitization. PREPARED DATE: 07/22/2003 Series: F394-0394 Product Class: ISOCYANATE SERIES 394 PERIMIPRIME Page 2 of 3 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 107.0 °F -N/A -N/A -N/A -N/A EXTINGUISHING MEDIA: Do not use water; use dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Dry dust forms explosive mixtures in air. Zinc dust in contact with water forms hydrogen gas which in a confined space with air or oxygen may form an explosive concentration. Small traces of HCN may be evolved under fire conditions. Do not spread material. Once ignited, zinc dust may bum readily in air. Use appropriate extinguishing media to control fire. DO NOT USE WATER. Wear self-contained breathing apparatus with a full facepiece operated in pressure -demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. Remove containers to a safe place and cover loosely until carbon dioxide has finished evolving. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. Where the isocyanate concentration exceeds the TLV or is unknown, or where there is spray application, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use protective cream where skin contact is likely. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION % VOLATILE BY VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT -N/A -N/A -N/A °F -N/A °F 21.1976 LB/GL 2.757 .000 (Ether= 1) 12.814 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Acids. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Zinc oxide fume Nitrogen monoxide, nitrogen dioxide Trace amounts of HCN. CONDITIONS TO AVOID: Heat, sparks, open flames. Amine compounds under uncontrolled conditions. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. OTHER: SECTION 16 - HMIS INFORMATION Health: 3 Flammability: 3 Reactivity: 2 PREPARED DATE: 07/22/2003 Series: F394-0394 Product Class: ISOCYANATE SERIES 394 PERIMIPRIME Page 3 of 3 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as M./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. 1 Series V69 conforms with air pollution regulations limiting Volatile Organic Compounds (VOC) to a maximum of 250 grams/litre (2.08 Ibs/gal) In areas requiring less than 100 grams/litre VOC, please refer to the Series L69 data sheet. PRODUCT PROFILE GENERIC DESCRIPTION Polyamidoamine Epoxy COMMON USAGE An advanced generation epoxy for protection and finishing of steel and concrete. It has excellent resis- tance to abrasion and is suitable for immersion as well as chemical contact exposure. Contact your local Tnemec representative for a list of chemicals. This product can also be used for lining storage tanks that contain demineralized, deionized or distilled water. COLORS Refer to Tnemec Color Guide. Note: Epoxies chalk with extended exposure to sunlight. Lack of ventila- tion, incomplete mixing, miscatalyzation or the use of heaters that emit carbon dioxide and carbon mon- oxide during application and initial stages of curing may cause yellowing to occur. FINISH Satin SPECIAL QUALIFICATIONS A two -coat system at 4.0-6.0 dry mils (100-150 dry microns) per coat passes the performance require- ments of MIL-C-4556E for fuel storage. PERFORMANCE CRITERIA Extensive test data available. Contact your Tnemec representative for specific test results. COATING SYSTEM PRIMERS Steel: Self -priming or Series 1, 27, 37H, 66, 90, 91-112O, 94-1-12O, 135, 161, 394, 530 Galvanized Steel and Non -Ferrous Metal: Self -priming or Series 66, 161 Concrete: Self -priming or 54-660, 130, 218, 219 CMU: Self -priming or 54-562, 54-660, 130, 216, 218, 219 TOPCOATS 4611-413, 66, L69, N69, 73, 84, 104, 113, 114, 161, 1070, 1071, 1072, 1o74, i074U, 1075, 1075U, 1077, 1078. Refer to COLORS on applicable topcoat data sheets for additional information. Note: The following recoat times apply for Series N69/V69: Immersion Service —Surface must be scarified after 60 days. Atmospheric Service —After 60 days, scarification or an epoxy tie -coat is required. Contact your Tnemec representative for specific recommendations. PREPARATIONSURFACE STEEL Immersion Service: SSPC-SP10/NACE 2 Near -White Blast Cleaning Non -Immersion Service: SSPC-SP6/NACE 3 Commercial Blast Cleaning PRIMED STEEL Immersion Service: Scarify the Series 66, N69/V69 or 161 prime coat surface by abrasive blasting with fine abrasive before topcoating if it has been exterior exposed for 60 days or longer and N69/V69 is the specified topcoat. GALVANIZED STEEL & Surface preparation recommendations will vary depending on substrate and exposure conditions. NON-FERROUS METAL Contact your Tnemec representative or Tnemec Technical Services. CAST/DUCTILE IRON Contact your Tnemec representative or Tnemec Technical Services. CONCRETE Allow new concrete to cure 28 days. For optimum results and/or immersion service, abrasive blast refer- encing SSPC-SP13/NACE 6, ICRI CSP 2-4 Surface Preparation of Concrete and Tnemec's Surface Prepara- tion and Application Guide. CMU Allow mortar to cure for 28 days. Level protrusions and mortar spatter. PAINTED SURFACES Non -Immersion Service: Ask your Tnemec representative for specific recommendations. All SURFACES Must be clean, dry and free of oil, grease, chalk and other contaminants. TECHNICAL DATA VOLUME SOLIDS* 67.0 ± 2.0a/o (mixed) RECOMMENDED DFT 2.0 to 10.0 mils (50 to 255 microns) per coat. Note: MIL-C-4556E applications require two coats at 4.0-6.0 mils (100-150 microns) per coat. Otherwise, the number of coats and thickness requirements will vary with substrate, application method and exposure. Contact your Tnemec representative. CURING TIME AT 5 MILS OFT Without 44.700 Accelerator VOLATILE ORGANIC COMPOUNDS* HAPS THEORETICAL COVERAGE* NUMBER OF COMPONENTS PACKAGING TP.n_p flvre Tn Handle To Recoat Immersion 90°F (32°C) 4 hours 7 hours 6 days 80°F (27*0 5 hours 8 hours 7 days 70°F (21°C) 7 hours 10 hours 7 days 60°F (16°C) 8 hours 12 hours 9 days 50*F (10*C) 12 hours 1 16 hours 1 12 days Curing time varies with surface temperature, air movement, humidity and film thickness. Note: For faster cur- ing and low -temperature applications, add No. 44-700 Epoxy Accelerator; see separate product data sheet. N69: Unthinned Thinned 10% Thinned 10% V69: Unthinned Thinned 2.5% No. 4 Thinner No. 6o Thinner 2.40lbs/gallon 2.801bs/gallon 2.801bs/gallon 1.95lbs/gallon 2.08lbs/gaUon (285 grams/litre) (334 grams/litre) (335 grams/litre) (234 grams/litre) (250 grams/litre) 2.40 lbs/gal solids 3.25 lbs/gal solids 2.401bs/gal solids 2.00 lbs/gal solids 2.30 lbs/gal solids 1,074 mil sq ft/gal (26.4 m-/L at 25 microns). See APPLICATION for coverage rates. Two: Part A and Part B 5 gallon (18.90 pails and 1 gallon (3.79L) cans — Order in multiples of 2. Published technical data and instructions are subject to change without notice. The online catalog at www.tnemec.com should be referenced for the most current technical data and instructions or you may contact your Tnemec representative for current technical data and instructions. Q April 17, 2007, by Tnemec Company, Inc. N69 TECHNICAL DATA continued NET WEIGHT PER GALLON* N69: 13.67 ± 0.25 lbs (6.10 ± .11 kg) (mixed) V69: 14.01 ± 0.25 lbs (6.36 ± .11 kg) (mixed) STORAGE TEMPERATURE Minimum 207 (-7°C) Maximum 1107 (43°C) TEMPERATURE RESISTANCE (Dry) Continuous 250*F (121*0 Intermittent 275°F (135°C) SHELF LIFE Part A: 24 months; Part B: 12 months at recommended storage temperature. FLASH POINT - SETA N69 & V69 Part A: 82°F (281C) N69 Part B: 930F (34°C) v69 Part B: 86°F (30°C) HEALTH & SAFETY Paint products contain chemical ingredients which are considered hazardous. Read container label warning and Material Safety Data Sheet for important health and safety information prior to the use of this product. Keep out of the reach of children. COVERAGE RATES* MIXING POT LIFE THINNING SURFACE TEMPERATURE APPLICATION EQUIPMENT CLEANUP Dry Mils (Microns) Wet Mils (Microns) Scl Ft/Gal (mZ/Gal) Suggested (1) 6.0(150) 9.0(230) 179 (16.6) Minimum 2.0 (50) 3.0 (75) 537 (49.9) Maximum 10.0 (250) 15.0 (375) 107 (10.0) (1) Note: Roller or brush application requires two or more coats to obtain recommended mm micxness. Alto, Series N69 can be spray applied to an optional high -build film thickness range of 8.0 to 10.0 dry mils (205 to 255 dry microns) or 11.5 to 14.5 wet mils (209 to 370 wet microns). Allow for overspray and surface irregulari- ties. Film thickness is rounded to the nearest 0.5 mil or 5 microns. Application of coating below minimum or above maximum recommended dry film thicknesses may adversely affect coating performance. 1. Start with equal amounts of both Parts A & B. 2. Using a power mixer, separately stir Parts A & B. 3• (For accelerated version. If not using 44-700, skip to No. 4.) Add four (4) fluid ounces of 44-700 per gallon of Part A while Part A is under agitation. 4. Add Part A to Part B under agitation, stir until thoroughly mixed. 5. Both components must be above 50oF (10°C) prior to mixing. For application of the unaccelerated version to surfaces between 50°F to 60'F (10°C to 16°C) or the accelerated version to surfaces between 35°F to 50°F (2°C to 10°C), allow mixed material to stand 30 minutes and restir before using. 6. For optimum application properties, the material temperature should be above 60°F (16°C). Note: The use of more than the recommended amount of 44-700 will adversely affect performance. Without 44-700 15 hours at 50OF (10°C) 5 hours at 77°F (25°C) 3 hours at 100*F (38°C) With 44-700 8 hours at 350F (2*C) 4 hours at 77*F (25°C) 1 hour at 100*F (38°C) Use No. 4 or No. 60 Thinner. For air spray, thin up to 10% or 3/ pint (380 mL) per gallon. For airless spray, roller or brush, thin up to 5% or Y4 pint (190 mL) per gallon. Note: When using Series V69, a maximum of 2.5% of No. 4 Thinner may be used to comply with VOC regulations. Minimum 50°F (10*0 Maximum 135*F (57°C) The surface should be dry and at least 50F (3°C) above the dew point. Coating will not cure below minimum surface temperature. Air Spay t Gun Fluid Air Cap AS. Hose Mat'1 Hose Atomizing Pot Tip ID ID Pressure Pressure DeVilbiss E 765 5/16" or 3/8" 3/8" or 1/2" 75-100 psi 10-20 psi JGA or 704 (7.9 or 9.5 mm) (9.5 or 12.7 mm) (5.2-6.9 bar) (0.7-1.4 bar) Low temperatures or longer hoses require higher pot pressure. Airless Snrav f Tip Orifice Atomizing Pressure Mat'1 Hose ID Manifold Filter 0.015"-0.019" (380-485 microns) 3000-4800 psi (207-330 bar) 1/4" or 3/8" (6.4 or 9.5 mm) 60 mesh (250 microns) Use appropriate tip/atomizing pressure for equipment, applicator technique and weamer concuuons. t Spray application of first coat on CMU should be followed by backrolling. Note: Application over inorganic zinc -rich primers: Apply a wet mist coat and allow tiny bubbles to form When bubbles disappear in 1 to 2 minutes, apply a full wet coat at specified mil thickness. Roller: Use 3/8" or 1/2" (9.5 mm or 12.7 mm) synthetic woven nap roller cover. Brush: Recommended for small areas only. Use high quality natural or synthetic bristle brushes. Flush and clean all equipment immediately after use with the recommended thinner or MEK. *Values may vary with color. WARRANTY R LIMITATION OF SELLER'S LIABILITY: Tnemec Company, Inc. warrants only that its coatings represented herein meet the formulation standards of Tnemec Company, Inc. THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU OF ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING BUT NOT UNITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The buyer's sole and exclusive remedy against Tnemec Company, Inc. shall be for replacement of the product in the event a defective condition of the product should be found to exist and the exclusive remedy shall not have failed its essentiol purpose as long as Tnemec is willing to provide comparable replacement product to the buyer. NO OTHER REMEDY (INCLUDING, BUT NOT LIMITED 10, INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR LOST PROFITS, LOST SALES, INJURY TO PERSON OR PROPERTY, ENVIRONMENTAL INJURIES OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE TO THE BUYER. Technical and application information herein is provided for the purpose of establishing a general profile of the coating and proper coating application procedures. Test performance results were obtained in a controlled environment and Tnemec Company makes no claim that these tests or any other tests, accurately represent all environments. As application, environmental and design factors can vary significantly, due core should be exercised in the selection and use of the coating. FOR INDUSTRIAL USE ONLY. TNEMEC COMPANY INCORPORATED PRINTED IN USA 6800 CORPORATE DRIVE, KANSAS CITY, MISSOURI 64120.1372 TEL: 1 800 TNEMEC 1 www.tnemec.com (YDAT067) N69 Tnemec Company, Inc. For coatings, resins and related materials, approved by 123 West 23rd Avenue, Kansas City, MO 64116-3064 Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to Emergency Telephone: 800-535-5053 (INFOTRAC) form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. Telephone: 816-474-3400 NPCA 1-84 PREPARED DATE: 05/03/2007 Series: N-69-11 WHA Product Class: POLYAMINE AMIDO AMINE H-B EPDXOLINE II WHITE Page 1 of 3 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS TITANIUM DIOXIDE (TOTAL DUST) TALC (RESPIRABLE DUST) AMORPHOUS SILICA BARIUM SULFATE (TOTAL DUST) ALUMINUM OXIDES MODIFIED CYCLOALIPHATIC POLYAMINE ISOPHORONE DIAMINE N-BUTANOL (SKIN)** ETHYL BENZENE** XYLENE** ** SARA Reportable Product CAS# 13463-67-7 14807-96-6 7631-86-9 7727-43-7 1344-28-1 2855-13-2 71-36-3 100-41-4 1330-20-7 VAPOR PRESS. MMHG % By Wt. @ 68 e F 11-20 11-20 1-5 23.66 1-5 6-10 1-5 4.03 4.400 2.47 6.000 10.17 5.100 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV -STEL TLV-C 0010.000 MG/M3 0002.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0000.100 MG/M3 MFG REC 0020.000 PPM 0100.000 PPM 0100.000 PPM 0125.000 PPM 0150.000 PPM 0050.000 PPM OSHA PEL-TWA PEL-STEL PEL-C 0010.000 MG/M3 0006.000 MG/M3 0010.000 MG/M3 0100.000 PPM 0100.000 PPM 0100.000 PPM This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. Corrosive responses, burns. SKIN: Severe burns. Can be a skin sensitizer. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Severe burns. Severe nasal and respiratory tract irritation. May cause allergic respiratory reaction. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. Corrosive responses and possible bums to the gastrointestinal tract. CHRONIC EFFECTS: NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer ([ARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). TARGET ORGANS: Can be corrosive to eyes. Can cause respiratory tract irritation. Can be corrosive to skin. Can cause lung damage. Can cause liver damage. Can cause respiratory tract sensitization. Can be corrosive to gastrointestinal tract. Can cause kidney damage. Can cause nervous system effects. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: This product contains a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. 0050.000 PPM PREPARED DATE: 05/03/2007 Series: N-69-11 WHA Product Class: POLYAMINE AMIDO AMINE H-B EPDXOLINE II WHITE Page 2 of 3 SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 78.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ad breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. CLEAN-UP: SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 6.00 -N/A 241.0 °F 288.0 °F 15.2560 LB/GL 2.623 19.600 (Ether= 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 %VOLATILE BY WEIGHT 36.820 PREPARED DATE: 05/03/2007 Series: N-69-11 WHA Product Class: POLYAMINE AMIDO AMINE H-B EPDXOLINE II WHITE Page 3 of 3 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as Wt./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 Material Safety Data Sheet (MSDS) For coatings, resins and related materials, approved by the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910,1200, OSHA'S hazard communication standard. NPCA 1-84 PREPARED DATE: 05/03/2007 Series: N-69-0069B Product Class: EPDXY H-B EPDXOLINE II CONVERTER Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS TALC (RESPIRABLE DUST) BARIUM SULFATE (TOTAL DUST) BISPHENOL A TYPE EPDXY RESIN BISPHENOL A TYPE EPDXY RESIN ETHYL BENZENE** XYLENE** METHYL ISOBUTYL KETONE** ** SARA Reportable Product CAS# 14807-96-6 7727-43-7 100-41-4 1330-20-7 108-10-1 VAPOR PRESS. % By Wt. MMHG @ 68 F 31-40 9.09 21-30 11-20 1.65 6.000 11.50 5.100 3.92 16.000 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV-STEL TLV -C 0002.000 MG/M3 0010.000 MG/M3 0100.000 0125.000 PPM PPM 0100.000 0150.000 PPM PPM 0050.000 0075.000 PPM PPM OSHA PEL-TWA PEL-STEL PEL -C 0010.000 MG/M3 0100.000 PPM 0100.000 PPM 0100.000 PPM This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. SKIN: Moderate irritation, drying of skin, defatting and possible dermatitis. Allergic skin responses. Can be a skin sensitizer. INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged contact or repeated overexposure to some epoxy compounds may result in permanent skin sensitization in susceptible individuals. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. TARGET ORGANS: Can cause eye irritation. Can cause respiratory tract irritation. Can cause lung damage. Can cause skin sensitization. Can cause skin irritation. Can cause gastrointestinal tract irritation. Can cause liver damage. Can cause nervous system effects. Can cause kidney damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: This product contains a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. PREPARED DATE: 05/0312007 Series: N-69-0069B Product Class: EPDXY H-B EPDXOLINE II CONVERTER Page 2 of 2 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 80.0 °F 1.0 -N/A -N/A -NIA EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous. ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 16.00 -N/A 237.0 °F 288.0 °F 12.0583 LB/GL 2.111 9.400 (Ether= 1) SECTION 10 -STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Acids. Bases. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Aldehydes. CONDITIONS TO AVOID: Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as VM./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific Information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. %VOLATILE BY WEIGHT 29.858 Tnemec Company, Inc. For coatings, resins and related materials, approved by 123 West 23rd Avenue, Kansas City, MO 64116-3064 Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to Emergency Telephone: 800-535-5053 (INFOTRAC) form OSHA-20, meets requirements of CFR 29 Part Telephone: 816-474-3400 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 PREPARED DATE: 05/03/2007 Series: V-69-0069B Product Class: EPDXY HI-BLD EPDXOLINE II CONVERTER Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS CAS# TALC (RESPIRABLE DUST) 14807-96-6 BARIUM SULFATE (TOTAL DUST) 7727-43-7 BISPHENOL A TYPE EPDXY RESIN BISPHENOL A TYPE EPDXY RESIN ETHYL BENZENE** 100-41-4 XYLENE** 1330-20-7 BENZENE, 1 -CH LORO-4-(TRI FLUOROM ETHYL)- 98-56-6 ** SARA Reportable Product VAPOR PRESS. By Wt. MMHG@ 68 F 31-40 8.60 21-30 11-20 .31 6.000 5.87 5.100 14.62 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0002.000 MG/M3 0010.000 MG/M3 0100.000 0125.000 PPM PPM 0100.000 0150.000 PPM PPM OSHA PEL-TWA PEL-STEL PEL-C 0010.000 MG/M3 0100.000 PPM 0100.000 PPM This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. SKIN: Moderate irritation, drying of skin, defatting and possible dermatitis. Allergic skin responses. Can be a skin sensitizer. INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged contact or repeated overexposure to some epoxy compounds may result in permanent skin sensitization in susceptible individuals. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 26). Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. TARGET ORGANS: Can cause eye irritation. Can cause respiratory tract irritation. Can cause lung damage. Can cause skin sensitization. Can cause skin irritation. Can cause gastrointestinal tract irritation. Can cause liver damage. Can cause nervous system effects. Can cause kidney damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: This product contains a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. PREPARED DATE: 05/03/2007 Series: V-69-0069B Product Class: EPDXY HI-BLD EPDXOLINE II CONVERTER Page 2 of 2 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT 86.0 °F EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH 1.0 -N/A FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous. ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 6.00 -N/A 275.0 °F 288.0 °F 12.7543 LB/GL 1.129 9.400 (Ether= 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Acids. Bases. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Hydrogen chloride. Hydrogen Fluoride and Organic Halides. Aldehydes. CONDITIONS TO AVOID: Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as Wt./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. %VOLATILE BY WEIGHT 13.200 H PRODUCT GENERIC DESCRIPTION Aliphatic Acrylic Polyurethane COMMON USAGE A coating highly resistant to abrasion, wet conditions, corrosive fumes, chemical contact and exte- rior weathering. High build quality combines with project specific primers for two -coat, labor saving systems. NOT FOR IMMERSION SERVICE. COLORS Refer to Tnemec Color Guide. Note: Certain colors may require multiple coats depending on method of application and finish coat color. When feasible, the preceding coat should be in the same color family (blue, gray, etc.), but noticeably different. FINISH Semi -gloss SPECIAL QUALIFICATIONS Series 73 meets the accelerated weathering requirements of SSPC Paint Standard 36. PERFORMANCE CRITERIA Extensive test data available. Contact your Tnemec representative for specific test results. COAT-ING SYSTEM PRIMERS Steel: Series 1, 20, 27, 37H, 66, L69, L69F, N69, N69F, 90-97, 91-112O, 94-H2O, 135, L140, L140F, N140, N140F, 161, 394, 530 Galvanized Steel & Non -Ferrous Metal: Series 27, 66, L69, L69F, N69, N69F, 161 Concrete: 54-660, 66, L69, L69F, N69, N69F, 161 CMU: 54-660 Note: Series 135 or 530 exterior exposed more than two months, or Series N69 or N140 exterior exposed more than three months must first be scarified or reprimed with themselves. Brush blasting with fine abrasive is the preferred method of scarification. Recoat windows for other primers may ap- ply. See those data sheets for additional information. TOPCOATS Series 76, 700, 701, 1070, 1071, 1072, 1074, 1074U, 1075U, 1077, 1078, optional when extended weath- erability is desired. PREPARATION ALL SURFACES Must be clean, dry and free of oil, grease and other contaminants. See primer product data sheet for surface preparation recommendation. TECHNICAL DATA VOLUME SOLIDS* 58.0 t 2.0% (mixed) RECOMMENDED DFT 2.0 to 5.0 mils (50 to 125 microns) per coat. Note: Number of coats and thickness require- ments will vary with substrate, application method and exposure. Contact your Tnemec representative. CURING TIME Temperature To Touch To Handle To Recoat 750F (24°C) 1 hour 5-8 hours 12 hours Curing time varies with surface temperature, air movement, humidity and film thickness. Note: For faster curing and low -temperature applications, add No. 44-710 Urethane Accelerator; see separate product data sheet. VOLATILE ORGANIC COMPOUNDS* HAPS THEORETICAL COVERAGE* NUMBER OF COMPONENTS MIXING RATIO PACKAGING NET WEIGHT PER GALLON* STORAGE TEMPERATURE TEMPERATURE RESISTANCE SHELF LIFE FLASH POINT - SETA HEALTH & SAFETY Unthinned Thinned 10% (Max) Thinned 10% (Max) (No. 39 Thinner) (No. 42 Thinner) 2.70lbs/gallon 3.06lbs/gallon 3.11lbs/gallon (325 grams/litre) (367 grams/litre) (372 grams/litre) 0.35 lbs/gal solids 0.34 lbs/gal solids 0.35 Ibs/gal solids 930 mil sq ft/gal (22.8 m2/L at 25 microns). Two: Part A and Part B By volume: Four (Part A) to one (Part B) Thinned 10% (Max) Thinned 10% (Max) (No. 56 Thinner) (No. 63 Thinner) 2.77lbs/gallon 3.08lbs/gallon (331 grams/litre) (369 grams/litre) 0.34 lbs/gal solids 0.40 Ibs/gal solids PART A (Partially filled) PART B When Mixed 5 Gallon Kit 5 gallon pail 1 gallon can 5 gallons (18.9L) 1 Gallon Kit 1 gallon pail 1 quart can 1 gallon (3.79L) 12.13 t 0.25 lbs (5.50 t .11 kg) Minimum 20°F (-7*C) Maximum 110OF (43°C) (Dry) Continuous 250°F (121°C) Intermittent 275*F (135*C) Part A: 24 months at recommended storage temperature. Part B: 12 months at recommended storage temperature. Part A: 550F (13°C) Part B: 1120F (43°C) Paint products contain chemical ingredients which are considered hazardous. Read container label warning and Material Safety Data Sheet for important health and safety infomlation prior to the use of this product. Keep out of the reach of children. Published technical data and instructions are subject to change without notice. The online catalog at www.tnemec.com should be referenced far the most current technical data and instructions or you may contact your Tnemec representative for current technical data and instructions. O February 27, 2007, by Tnemec Company, Inc. 73 "PLICATION COVERAGE RATES* Conventional Build High -Build (S ra , Brush or Roller) (Spray Only) Dry Mils (Microns) Wet Mils (Microns) Sq Ft/Gal (m2/Gal) Dry Mils (Microns) Wet Mils (Microns) Sq Ft/Gal (in Z/Gal) Suggested 2.5(65) 4.5(115) 372 (34.6) 4.0(100) 7.0(180) 233 (21.6) Minimum 2.0(50) 3.5 (90) 465 (43.2) 3.0 (75) 5.0(125) 310 (28.8) Maximum 3.0(75) 5.0(125) 310 (28.8) 5.0(125) 8.5(215) 186 07.3) (1) Can be spray applied at 3.0 to 5.0 mils (75 to 125 microns) DFT per coat when extra protection or the elimination of a coat is desired. (2) Can be sprayed, brushed or rolled at 2.0 to 3.0 mils (50 to 75 microns) DFT per coat for use in sys- tems requiring a conventional build topcoat. Allow for overspray and surface irregularities. Wet film thickness is rounded to the nearest 0.5 mil or 5 microns. Application of coating below minimum or above maximum recommended dry film thicknesses may adversely affect coating performance. MIXING Stir contents of the container marked Part A, making sure no pigment remains on the bottom. Add the contents of the can marked Part B to Part A while under agitation. Continue agitation until the two com- ponents are thoroughly mixed. When used with 44-710 Urethane Accelerator, first blend 44-710 into Part A under agitation; continue as above. Do not use mixed material beyond pot life limits. Caution: Part B is moisture -sensitive and will react with atmospheric moisture. Keep unused material tightly closed at all times. POT LIFE 8 hours at 40OF (4°C) 4 hours at 77°F (25°C) 2 hours at 100*F (38°C) THINNING For air spray, thin up to 10% or 3/ pint (380 mL) per gallon by volume with No. 42 Thinner if tempera- tures are below 80°F (270C), use No. 48 Thinner for temperatures above 80OF (27°C). Thin up to 5% or a/4 pint (190 ml.) per gallon for airless spray. For brush or roller, thin 5% to 10% or 1/4 to 3/4 pint (190 to 380 mL) per gallon with No. 39 or No. 63 Thinner. Thinning is required for proper brush or roller appli- cation. Caution: Do not add thinner if more than thirty (30) minutes have elapsed after mixing. Note: A maximum of 10% of No. 56 Thinner may be used to comply with VOC regulations. SURFACE TEMPERATURE Minimum 35*F (2°C) Maximum 120°F (49*C) The surface should be dry and at least 57 (3°C) above the dew point. Cure time necessary to resist direct contact with moisture at surface temperature: 40oF (40C): 24 to 40 hours 50OF (100C): 18 to 26 hours 60OF (16°C): 12 to 16 hours 70°F (21*C): 4 to 8 hours 90OF (320C): 2 to 4 hours 100°F (380C): 2 to 3 hours If the coating is exposed to moisture before the preceding cure parameters are met, dull, flat or spotty - appearing areas may develop. Actual times will vary with air movement, film thickness and humidity. APPLICATION EQUIPMENT Air Spray Gun Fluid Air Cap Air Hose Mat'l Hose Atomizing Pot Tip ID ID Pressure Pressure DeVilbiss J, 765 5/16" or 3/8" 3/8" or 1/2" 75-90 psi 10-20 psi JGA or 704 (7.9 or 9.5 mm) (9.5 or 12.7 mm) (5.2-6.2 bar) (0.7-1.4 bar) Low temperatures or longer hoses require higher pot pressure. Airless Spray Tip Orifice Atomizing Pressure Mat'l Hose ID Manifold Filter 0.013"-0.017" (330-430 microns) 2700-3300 psi (186-228 bar) 1/4" or 3/8" (6.4 or 9.5 mm) 60 mesh (250 microns) Use appropriate tip/atomizing pressure for equipment, applicator technique and weather conditions. Roller: Use 1/4" to 3/8" (6.4 mm to 9.5 nun) synthetic woven nap roller cover. Do not use long nap roller covers. Note: Two coats are required to obtain dry film thickness above 3.0 mils (75 microns). Brush: Recommended for small areas only. Use high quality natural or synthetic bristle brushes. Note: Two or more coats may be required to obtain recommended film thicknesses. CLEANUP Flush and clean all equipment immediately after use with the recommended thinner or MEK. Values may vary with color. WARRANTY JL LIMITATION OF SELLER'S LIABILITY: Tnemec Company, Inc. warrants only that Its coatings represented herein meet the formulation standards of lnamec Company, Inc. THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU OF ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The buyer's sole and exclusive remedy against Tnemec Company, Inc. shall be for replacement of the product in the event a defective condition of the product should be found to exist and the exclusive remedy shall not have foiled its essential purpose as long as Tnemec is willing to provide comparable replacement product to the buyer. NO OTHER REMEDY (INCLUDING, BUT NOT LIMITED TO, INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR LOST PROFITS, LOST SALES, INJURY TO PERSON OR PROPERTY, ENVIRONMENTAL INJURIES OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE TO THE BUYER. Technical and application information herein is provided for the purpose of establishing a general profile of the coating and proper coating application procedures. Test performance results were obtained in a controlled environment and Tnemec Company makes no claim that these tests or any other tests, accurately represent all environments. As application, environmental and design factors can vary significantly, due care should be exercised in the selection and use of the coating. FOR INDUSTRIAL USE ONLY. TNEMEC COMPANY INCORPORATED PRINTED IN USA 1800 CORPORATE DRIVE, KANSAS CITY, MISSOURI 64120-1372 TEL: 1 800 TNEMEC 1 www.tnemec.com (YDAT073) 73 Tnemec Company, Inc. For coatings, resins and related materials, approved by 123 West 23rd Avenue, Kansas City, MO 64116-3064 Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to Emergency Telephone: 800-535-5053 (INFOTRAC) form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. Telephone: 816-474-3400 NPCA 1-84 PREPARED DATE: 08/02/2007 Series: F073-11WHA Product Class: ACRYLIC ENDURA-SHIELD WHITE Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS CRYSTALLINE SILICA (QUARTZ) TITANIUM DIOXIDE (TOTAL DUST) AMORPHOUS SILICA ALUMINUM OXIDES PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE ETHYL BENZENE** XYLENE** METHYL ETHYL KETONE"* CAS# 14808-60-7 13463-67-7 7631-86-9 1344-28-1 108-65-6 100-41-4 1330-20-7 78-93-3 VAPOR PRESS. MMHG % By Wt. @ 68 a F 13.60 21-30 1-5 1-5 17.47 3.800 .34 6.000 1.45 5.100 4.88 70.000 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV-STEL TLV -C 0000.025 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0100.000 0125.000 PPM PPM 0100.000 0150.000 PPM PPM 0200.000 0300.000 PPM PPM PEL -TWA 0000.050 MG/M3 0010.000 MG/M3 0006.000 MG/M3 0100.000 PPM 0100.000 PPM 0200.000 PPM ** SARA Reportable Product This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. OSHA PEL-STEL PEL-C SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. SKIN: Moderate irritation, drying of skin, defatting and possible dermatitis. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged inhalation of dusts containing crystalline silica may result in the development of a lung disease known as silicosis. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). This product contains crystalline silica, which is considered a cancer hazard by inhalation of respirable dust. The Internation Agency for Research on Cancer (IARC) concluded that respirable crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1 B). TARGET ORGANS: Can cause respiratory tract irritation. Can cause skin irritation. Can cause lung damage. Can cause eye irritation. Can cause gastrointestinal tract irritation. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause liver damage. Can cause nervous system effects. Can cause kidney damage. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: This product contains a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: PREPARED DATE: 08/02/2007 Series: F073-11 WHA Product Class: ACRYLIC ENDURA-SHIELD WHITE Page 2 of 2 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 55.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ad breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous. ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 70.00 -N/A 172.0 °F 288.0 °F 12.4128 LB/GL 3.223 9.400 (Ether= 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments CONDITIONS TO AVOID: Heat, sparks, open flames. May react with oxygen to form peroxides. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as WA./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. Al materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. %VOLATILE BY WEIGHT 42.390 Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 Material Safety Data Sheet (MSDS) For coatings, resins and related materials, approved by the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 PREPARED DATE: 09/20/2007 Series: F073-0073B Product Class: POLYISOCYANATE ENDURA-SHIELD CONVERTER Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS VAPOR PRESS. MMHG INGREDIENTS CAS# % By Wt. @ 68 -F HEXAMETHYLENE DIISOCYANATE (HDI) POLYMER 28182-81-2 51-60 BENZENE, 1-CHLORO-4-(TRIFLUOROMETHYL)- 98-56-6 49.00 ** SARA Reportable Product OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0000.500 0001.000 MG/M3 MG/M3 MFG REC MFG REC OSHA PEL-TWA PEL-STEL PEL-C This product contains no reported carcinogens or suspected carcinogens. Contains isocyanate monomer. If subject to spray application, engineering and administrative controls must be instituted to maintain an exposure level below .005ppm. If these controls are not adequate, the use of an air -supplied respirator is mandatory. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Moderate irritation. Redness, tearing, blurred vision. SKIN: Moderate irritation, drying of skin, defatting and possible dermatitis. Allergic skin responses. INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION -OVEREXPOSURE TO FREE PIGMENT DUST: INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged contact or repeated exposure to isocyanate concentrations greater than the recommended TLV may result in permanent respiratory and skin sensitization. Once diagnosed as being sensitized to isocyanates, no further exposure can be permitted. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. TARGET ORGANS: Can cause eye damage. Can cause skin irritation. Can cause respiratory tract irritation. Can cause lung damage. Can be corrosive to gastrointestinal tract. Can cause liver damage. Can cause kidney damage. Can cause skin sensitization. Can cause nervous system effects. Can cause respiratory tract sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure to isocyanate products may aggravate persons with asthmatic type conditions, chronic bronchitis, other chronic respiratory diseases, skin eczema, or skin sensitization. SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 104.0 °F -N/A -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Small traces of HCN may be evolved under fire conditions. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. PREPARED DATE: 09/20/2007 Series: F073-0073B Product Class: POLYISOCYANATE ENDURA-SHIELD CONVERTER Page 2 of 2 SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. Remove containers to a safe place and cover loosely until carbon dioxide has finished evolving. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION %VOLATILE BY VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT -N/A -N/A 282.0 °F -N/A °F 10.2631 LB/GL .000 .000 (Ether= 1) .000 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Hydrogen chloride. Nitrogen monoxide, nitrogen dioxide Hydrogen Fluoride and Organic Halides. Trace amounts of HCN. CONDITIONS TO AVOID: Amine compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 2 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as M./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. NSF Certified to ANSI/NSF 61 Series V140 conforms with air pollution regulations limiting Volatile Organic Compounds (VOC) to a maximum of 250 grams/litre (2.08 Ibs/gal) In areas requiring less than 100 grams/litre VOC, please refer to the Series L140 data sheet. PRODUCT GENERIC DESCRIPTION Polyamidoamine Epoxy COMMON USAGE Innovative potable water coating which offers high -build edge protection and allows for application at a wide range of temperatures (down to 350F or 2°C with 44-700 Accelerator). For use on the interior and exterior of steel or concrete tanks, reservoirs, pipes, valves, pumps and equipment in potable water service. COLORS 1211 Red Oxide, 1255 Beige, 11VIH White, 15BL Tank White, 35GR Black and 39BL Delft Blue. Note: Epoxies chalk with extended exposure to sunlight. Lack of ventilation, incomplete mixing, miscatalyzation or the use of heaters that emit carbon dioxide and carbon monoxide during application and initial stages of curing may cause yellowing to occur. ® SPECIAL QUALIFICATIONS Certified by NSF International in accordance with ANSI/NSF Std. 61. Ambient air cured Series N140 (with or without 44-700 Epoxy Accelerator) is qualified for use on tanks and reservoirs of 1,000 gallons (3,785L) capacity or greater, pipes 12 inches (30 cm) in diameter or greater and valves two (2) inches (5 cm) in diameter or greater. Series V140 is qualified for use on tanks of 20,000 gallons (75,708L) capacity or greater and valves 1/2 inch in diameter or greater. Note: NSF certification for Series V140 applies to colors 1255 Beige, 1211 Red and 15BLTank White only. Conforms to AWWA D 102 Inside Sys- tems No. 1 and No. 2 (with or without 44-700). Conforms to AWWA C 210 (without 44-700). Contact your Tnemec representative for systems and additional information. PERFORMANCE CRITERIA Extensive test data available. Contact your Tnemec representative for specific test results. COATING SYSTEM PRIMERS Self -priming, 20, FC20, 91-HzO, 94-112O, L140, L140F, N140F TOPCOATS Interior: Series L140, L140F, N140, N140F. Exterior. Series 27, 66, L69, L69F, N69, N69F, 73, L140, L140F, N140, N140F, 161, 180, 700, 701, 1074, 1074U, 1075, 1075U. Refer to COLORS on applicable topcoat data sheets for additional information. Note: When topcoating with Series 700, an intermediate coat of Series 73 or 1075 is required. Note: The fol- lowing recoat times apply for Series N140: Immersion Service Surface must be scarified after 60 days. Atmospheric Service —After 60 days, scarification or an epoxy tie -coat is required. Contact your Tnemec representative for specific recommendations. Immersion Service: SSPC-SP10/NACE 2 Near -White Blast Cleaning STEEL Non -Immersion Service: SSPC-SP6/NACE 3 Commercial Blast Cleaning PRIMED STEEL Immersion Service: Scarify the Series N140, 20 or FC20 prime coat surface by blasting with fine abrasive before topcoating if it has been exterior exposed for 60 days or longer and N140 is the specified topcoat. CAST/DUCTILE IRON Contact your Tnemec representative or Tnemec Technical Services. CONCRETE Allow new concrete to cure 28 days. For optimum results and/or immersion service, abrasive blast refer- encing SSPC-SP13/NACE 6, ICRI-GSP 2-4 Surface Preparation of Concrete and Tnemec's Surface Prepara- tion and Application Guide. Fill all holes, pits, voids and cracks with 63-1500 Filler and Surfacer. ALL SURFACES Must be clean, dry and free of oil, grease and other contaminants. TECHNICAL DATA VOLUME SOUDS' 67.0 t 2.0% (mixed —A, B & 44-700 Epoxy Accelerator) RECOMMENDED DFT 2.0 to 10.0 mils (50 to 225 microns) per coat. Note: Number of coats and thickness requirements will vary with substrate, application method and exposure. Contact your Tnemec representative. CURING TIME AT 5 MILS OFT Without 44.700 Accelerator With 44-700 Accelerator VOLATILE ORGANIC COMPOUNDS' HAPS Temperature To Handle To Recoat Immersion 757 (24°C) 6 hours 9 hours` 7 days 75°F (24°C) 4 hours 5 hours 7 days 65°F (18°C) 7-8 hours 9-11 hours 8 days 550F (13°C) 12-14 hours 16-20 hours 9-10 days 45°F (7°C) 18-22 hours 28-32 hours 12-13 days 35°F (2°C) 28-32 hours 46-50 hours 16-18 days Curing time varies with surface temperature, air movement, humidity and film thickness. When using V140, recoat time is 5 hours. Note: For valve applications allow 14 days cure at 750F (24°C) prior to immersion. For pipe applications allow 30 days cure at 75°F (24°C) prior to immersion. Ventilation: When used in enclosed areas, provide adequate ventilation during application and cure. N140: Unthinned Thinned 5% (No. 60) V140: Unthinned Thinned 2.5% 2.4lbs/gallon 2.6lbs/gallon 1.951bs/gallon 2.08lbs/gallon (285 gramsAitre) (311 grams/litre) (234 grams/litre) (250 grams/litre) 2.4 Ibs/gal solids 2.4 lbs/gal solids 2.1 lbs/gal solids 2.3 lbs/gal solids THEORETICAL COVERAGE` 1,070 mil sq ft/gal (27.2 m2/L at 25 microns). See APPLICATION for coverage rates. NUMBER OF COMPONENTS Two: Part A and Part B or Three: Part A, Part B and 44-700 Epoxy Accelerator PACKAGING 5 gallon (18.91.) pails and 1 gallon (3.79L) cans — Order in multiples of 2. Reference 44-700 Epoxy Accelerator product data sheet for its packaging information. NET WEIGHT PER GALLON" N140: 12.66 t 0.25 Ibs (5.82 t .11 kg) (mixed) V140: 13.00 t 0.25 Ibs (5.90 t .11 kg) (nixed) STORAGE TEMPERATURE Minimum 207 (-7°C) Maximum 1107 (43°C) Published technical data and instructions ore subject to change without notice. The online catalog of www.tnemec.com should be referenced for the most current technical data and instructions or you may contact your Tnemec representative for current technical data and instructions. m May 31, 2007, by Tnemec Company, Inc. N140 TECI-1NICA1. DATA continued TEMPERATURE RESISTANCE (Dry) Continuous 250*F (121*C) Intermittent 275°F (13500 SHELF LIFE 24 months at recommended storage temperature. FLASH POINT - SETA N140 & V140 Part A: 820F (28°C) N140 Part B: 80°F (27°C) V140 Part B: 86°F (30°C) 44-700: None HEALTH 8 SAFETY Paint products contain chemical ingredients which are considered hazardous. Read container label warning and Material Safety Data Sheet for important health and safety information prior to the use of this product. Keep out of the reach of children. COVERAGE RATES' Dry Mils (Microns) Wet Mils (Microns) Sq Ft/Gal (m2/Gal) Suggested 6,0050) 9.0(230) 179 06.6) Minimum 2.0 (50) 3.0 (75) 537 (49.9) Maximum 10.0 (225) 15.0 (375) 107 (10.0) Note: Roller or brush application requires two or more coats to obtain recommended film thickness. Allow for overspray and surface irregularities. Wet film thickness is rounded to the nearest 0.5 mil or 5 microns. Applica- tion of coating below minimum or above maximum recommended dry film thicknesses may adversely affect coating performance. Reference the "Search Listings" section of the NSF website at www.nsf.org for details on the maximum allowable DFT. MIXING 1. Start with equal amounts of both Parts A & B. 2. Using a power mixer, separately stir Parts A & B. 3. (For accelerated version. If not using 44-700, skip to No. 4.) Add four (4) Fluid ounces of 44-700 per gallon of Part A while Part A is under agitation. 4. Add Part A to Part B under agitation, stir until thoroughly mixed. 5. Both components must be above 50°F (10*C) prior to mixing. For application of the unaccelerated version to surfaces between 50°F to 60°F (10*C to 16*C) or the accelerated version to surfaces between 35*F to 50OF (2*C to 10°C), allow mixed material to stand 30 minutes and restir before using. 6. For optimum application properties, the material temperature should be above 60°F (16*C). Note: The use of more than the recommended amount of 44-700 will adversely affect performance. POT LIFE Without 44-700 15 hours at 50OF (10*C) 5 hours at 77°F (25°C) 3 hours at 100OF (38°C) With 44-700 8 hours at 357 (2°C) 4 hours at 77*F (25°C) 1 hour at 100°F (38°C) THINNING Use No. 4 or No. 60 Thinner. For air spray, thin up to 10% or 3/4 pint (380 mL) per gallon. For airless spray, roller or brush, thin up to 5% or Y4 pint (190 mL) per gallon. Caution: Series N140 & V140 NSF certification is based on thinning with No. 4 or No. 60 Thinner. Use of any other thinner voids ANSI/NSF Std. 61 certifica- tion. Note: When using Series V140, a maximum of 2.5% of No. 4 Thinner may be used to comply with VOC regulations. SURFACE TEMPERATURE Without 44-700 Minimum 50°F (10*C) Maximum 1357 (57*C) With 44-700 Minimum 350F (2°C) Maximum 1357 (57*C) The surface should be dry and at least 5*F (3*C) above the dew point. Coating won't cure below minimum sur- face temperature. APPLICATION EQUIPMENT Air Spray Gun Fluid Air Cap Air Hose Mat'1 Hose Atomizing Pot Tip I L ID 113 Pressure Pressure DeVilbiss E 765 5/16" or 3/8" 1 3/8" or 1/2" 75-100 psi 10-20 psi JGA 1 or 704 (7.9 or 9.5 mm) (95 or 12.7 mm) (5.2-6.9 bar) (0.7-1.4 bar) Low temperatures or longer hoses require higher pot pressure. Airless Spray Tip Orifice Atomizing Pressure Mat'1 Hose ID Manifold Filter 0.015"-0.019" (380-485 microns) 3000-4800 psi (207-330 bar) 1/4" or 3/8" (6.4 or 9.5 mm) 60 mesh (250 microns) Use appropriate tip/atomizing pressure for equipment, applicator technique and weather conditions. Note: Application over inorganic zinc -rich primers: Apply a wet mist coat and allow tiny bubbles to form. When bubbles disappear in 1 to 2 minutes, apply a full wet coat at specified mil thickness. Roller: Roller application optional when environmental restrictions do not allow spraying. Use 3/8" or 1/2" (9.5 mm to 12.7 mm) synthetic woven nap roller covers. Brush: Recommended for small areas only. Use high quality natural or synthetic bristle brushes. CLEANUP Flush and clean all equipment immediately after use with the recommended thinner or MEK. *Values may vary with color. WARRANTY R LIMITATION Of SELLER'S LIABILITY: Tnemec Company, Inc. warrants only that its coatings represented herein meet the formulation standards of Tnemec Company, Inc. THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU Of ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMITED 10, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The buyer's sole and exclusive remedy against Tnemec Company, Inc. shall be for replacement of the product in the event a defective condition of the product should he found to exist and the exclusive remedy shall not hove failed its essential purpose as long as Tnemec is willing to provide comparable replacement product to the buyer. NO OTHER REMEDY (INCLUDING, BUT NOT LIMITED TO, INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR LOST PROFITS, LOST SALES, INJURY TO PERSON OR PROPERTY, ENVIRONMENTAL INJURIES OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE TO THE BUYER. Technical and application information herein is provided for the purpose of establishing o general profile of the coating and proper coating application procedures. Test performance results were obtained in a controlled environment and Tnemec Company makes no claim that these tests or any other tests, accurately represent all environments. As application, environmental and design factors can vary significantly, due core should be exercised in the selection and use of the coating. FOR INDUSTRIAL USE ONLY. TNEMEC COMPANY INCORPORATED PRINTED IN USA 6800 CORPORATE DRIVE, KANSAS CITY, MISSOURI 64120-1372 TEL: 1 800 TNEMEC 1 www.tnemec.com (1 DAT141) N140 Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 PREPARED DATE: 07/17/2003 Series: N140-11WHA SECTION 2 - HAZARDOUS INGREDIENTS For coatings, resins and related materials, approved by Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 Product Class: POLYAMINE AMIDO AMINE SERIES 140 POTA-PDX PLUS Page 1 of 3 VAPOR PRESS. MMHG INGREDIENTS CAS# % By Wt. @ 68 °F ISOPHORONE DIAMINE 2855-13-2 1-5 XYLENE** 1330-20-7 11.34 5.100 N-BUTANOL (SKIN)** 71-36-3 4.49 4.400 MODIFIED CYCLOALIPHATIC POLYAMINE 6-10 AMORPHOUS SILICA 7631-86-9 1-5 TALC (RESPIRABLE DUST) 14807-96-6 21-30 TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 11-20 CRYSTALLINE SILICA (QUARTZ) 14808-60-7 17.89 ALUMINUM OXIDES 1344-28-1 1-5 ETHYL BENZENE** 100-41-4 2.75 6.000 ** SARA Reportable Product OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0000.100 MG/M3 MFG REC 0100.000 0150.000 PPM PPM 0010.000 MG/M3 0002.000 MG/M3 0010.000 MG/M3 0000.100 MG/M3 0010.000 MG/M3 0100.000 0125.000 PPM PPM 0050.000 PPM PEL -TWA 0100.000 PPM 0100.000 PPM 0006.000 MG/M3 0010.000 MG/M3 0000.050 MG/M3 0100.000 PPM This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. OSHA PEL -STEL PEL-C SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. Corrosive responses, burns. SKIN: Severe burns. Can be a skin sensitizer. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. Severe burns. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. Severe burns. CHRONIC EFFECTS: Prolonged inhalation of dusts containing crystalline silica may result in the development of a lung disease known as silicosis. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 213). This product contains crystalline silica, which is considered a cancer hazard by inhalation of respirable dust. The Internation Agency for Research on Cancer (IARC) concluded that respirable crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1 B). TARGET ORGANS: Can be corrosive to eyes. Can cause respiratory tract irritation. Can be corrosive to skin. Can cause lung damage. Can cause gastrointestinal tract irritation. Can cause liver damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause kidney damage. Can cause respiratory tract sensitization. Can cause nervous system effects. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. PREPARED DATE: 07/17/2003 Series: N140-11 WHA Product Class: POLYAMINE AMIDO AMINE SERIES 140 POTA-PDX PLUS Page 2 of 3 SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 78.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. CLEAN-UP: Nitrogen monoxide, nitrogen dioxide Will not occur. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recom°ended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 6.00 -NIA 241.0 °F 288.0 °F 13.6805 LB/GL 2.623 19.600 (Ether= 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 %VOLATILE BY WEIGHT 19.178 PREPARED DATE: 07/17/2003 Series: N140-11 WHA Product Class: POLYAMINE AMIDO AMINE SERIES 140 POTA-PDX PLUS Page 3 of 3 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as VA/Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safely and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Tnemec Company, Inc. For coatings, resins and related materials, approved by 123 West 23rd Avenue, Kansas City, MO 64116-3064 Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part Emergency Telephone: 800-535-5053 (INFOTRAC) 1910.1200, OSHA'S hazard communication standard. Telephone: 816-474-3400 NPCA 1-84 PREPARED DATE: 07/22/2003 Series: N140-1211A Product Class: POLYAMINE AMIDO AMINE SERIES 140 POTA-PDX PLUS Page 1 of 3 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS ISOPHORONE DIAMINE TALC (RESPIRABLE DUST) CRYSTALLINE SILICA (QUARTZ) CRYSTALLINE SILICA (QUARTZ) XYLENE" BENZYL ALCOHOL N-BUTANOL (SKIN) -- IRON OXIDE FUME MODIFIED CYCLOALIPHATIC POLYAMINE '" SARA Reportable Product VAPOR PRESS. MMHG CAS# % By Wt. @ 68 ° F 2855-13-2 1-5 14807-96-6 14808-60-7 14808-60-7 1330-20-7 100-51-6 71-36-3 1309-37-1 21-30 22.96 2.04 10.57 5.100 6-10 4.07 4.400 11-20 6-10 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0000.100 MG/M3 MFG REC 0002.000 MG/M3 0000.100 MG/M3 0000.100 MG/M3 0100.000 PPM 0005.000 MG/M3 OSHA PEL -TWA PEL - STEL PEL - C 0000.050 MG/M3 0000.050 MG/M3 0150.000 0100.000 PPM PPM 0050.000 0100.000 PPM PPM 0010.000 MG/M3 This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. Corrosive responses, burns. SKIN: Discoloration. Severe burns. Can be a skin sensitizer. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. Severe burns. INHALATION -OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. Severe burns. CHRONIC EFFECTS: Prolonged inhalation of dusts containing crystalline silica may result in the development of a lung disease known as silicosis. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). This product contains crystalline silica, which is considered a cancer hazard by inhalation of respirable dust. The Intemation Agency for Research on Cancer (IARC) concluded that respirable crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1 B). TARGET ORGANS: Can be corrosive to eyes. Can be corrosive to skin. Can cause respiratory tract irritation. Can cause lung damage. Can cause gastrointestinal tract irritation. Can cause liver damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause kidney damage. Can cause respiratory tract sensitization. Can cause nervous system effects. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. PREPARED DATE: 07/22/2003 Series: N140-1211A Product Class: POLYAMINE AMIDO AMINE SERIES 140 POTA-PDX PLUS Page 2 of 3 SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 78.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. CLEAN-UP: Nitrogen monoxide, nitrogen dioxide Will not occur. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 6.00 -N/A 241.0 °F 288.0 °F 13.9366 LB/GL 2.477 19.600 (Ether= 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 %VOLATILE BY WEIGHT 17.774 PREPARED DATE: 07/22/2003 Series: N140-1211A Product Class: POLYAMINE AMIDO AMINE SERIES 140 POTA-PDX PLUS Page 3 of 3 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as M./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safely and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. i&a vvest 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 PREPARED DATE: 07/22/2003 Series: N140-1255A SECTION 2 - HAZARDOUS INGREDIENTS MSDS For coatings, resins and related materials, approved by Material Safety Data Sheet the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 Product Class: POLYAMINE AMIDO AMINE SERIES 140 POTA-PDX PLUS VAPOR PRESS. OCCUPATIONAL EXPOSURE LIMITS INGREDIENTS MMHG ACGIH CAS# % By Wt. @ 68 ^F TLV - TWA TLV - STEL TLV - C PEL -TWA XYLENE** 1330-20-7 10.25 5.100 0100.000 0150.000 AMORPHOUS SILICA PPM 0100.000 PPM 7631-86-9 1-5 0010.000 PPM TALC (RESPIRABLE DUST) MG/M3 0006.000 14807-96-6 21-30 0002.000 MG/M3 BENZYLALCOHOL MG/M3 100-51-6 6-10 ISOPHORONE DIAMINE 0050.000 0100,0002855-13-2 1-5 PPM PPM 0000.100 MG/M3 MODIFIED CYCLOALIPHATIC POLYAMINE MFG REC TITANIUM DIOXIDE (TOTAL DUST) 6 -10 1317-80-2 1-5 1-5 0010.000 TITANIUM DIOXIDE (TOTAL DUST) MG/M3 0010.000 13463-67-7 11-20 0010.000 MG/M3 ETHYL BENZENE** MG/M3 0010.000 100-41-4 2.48 6.000 0100.000 MG/M3 0125.000 CRYSTALLINE SILICA (QUARTZ) PPM 0100.000 PPM 14808-60-7 17.31 0000.100 PPM ALUMINUM OXIDES MG/M3 0000.050 1344-28-1 1-5 0010.000 MG/M3 "* SARA Reportable Product MG/M3 This product contains one or more reported carcinogens or suspected classified as a hazardous air pollutant. This product contains carcinogens which are noted NTP, IARC, or OSHA-Z in dusts the other limits recommended column. This substance pigment which may be released when subjected considered confidential and proprietary and should be used only for safety contains a material to abrasive blasting, sanding, or grinding. The information contained in and health purposes. this section is rdge I oT 3 OSHA PEL-STEL PEL-C SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. Corrosive responses, burns. SKIN: Severe burns. Can be a skin sensitizer. NHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, atigue, nausea, and headache. Severe burns. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: 3astrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. Severe burns. CHRONIC EFFECTS: Prolonged inhalation of dusts containing crystalline silica may result n the development of a lung disease known as silicosis. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. ntentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based m an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of arcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). This product contains crystalline silica, which is considered a cancer hazard by ihalation of respirable dust. The Internation Agency for Research on Cancer (IARC) concluded that respirable crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is arcinogenic to humans (Group 1 B). TARGET ORGANS: Can be corrosive to eyes. Can cause respiratory tract irritation. Can be corrosive to skin. Can cause lung damage. Can cause gastrointestinal tract ritation. Can cause liver damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause kidney damage. Can cause respiratory tract sensitization. Can cause nervous system ffects. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 5: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. PREPARED DATE: 07/22/2003 Series: N140-1255A Product Class: POLYAMINE AMIDO AMINE SERIES 140 POTA-PDX PLUS Page 2 of 3 SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 78.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flashback. Water maybe used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. CLEAN-UP: Nitrogen monoxide, nitrogen dioxide Will not occur. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES VAPOR PRESSURE VAPOR DENSITY LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION %VOLATILE BY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT 6.00 -N/A 241.0 °F 288.0 °F 14.0196 LB/GL 2.473 19.600 (Ether= 1) 17.641 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 PREPARED DATE: u//22/2UU3 Series: N140-1255A Product Class: POLYAMINE AMIDO AMINE SERIES 140 POTA-PDX PLUS Page 3 of 3 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as MGM., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safely and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. Al materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 PREPARED DATE: 07/22/2003 Series: N140-15BLA SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS MODIFIED CYCLOALIPHATIC POLYAMINE XYLENE** ALUMINUM OXIDES ISOPHORONE DIAMINE N-BUTANOL (SKIN)** ETHYL BENZENE** AMORPHOUS SILICA CRYSTALLINE SILICA (QUARTZ) TITANIUM DIOXIDE (TOTAL DUST) TALC (RESPIRABLE DUST) ** SARA Reportable Product For coatings, resins and related materials, approved by Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 Product Class: POLYAMINE AMIDO AMINE SERIES 140 POTA-PDX PLUS Page 1 of 3 VAPOR PRESS. MMHG CAS# % By Wt. @ 68 ° F 6-10 1330-20-7 11.37 5.100 1344-28-1 1-5 2855-13-2 1-5 71-36-3 100-41-4 7631-86-9 14808-60-7 13463-67-7 14807-96-6 4.50 4.400 2.76 6.000 1-5 17.92 11-20 21-30 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0100.000 0150.000 PPM PPM 0010.000 MG/M3 0000.100 MG/M3 MFG REC 0050.000 PPM 0100.000 PPM 0010.000 MG/M3 0000.100 MG/M3 0010.000 MG/M3 0002.000 MG/M3 0125.000 PPM OSHA PEL-TWA PEL-STEL PEL -C 0100.000 PPM 0100.000 PPM 0100.000 PPM 0006.000 MG/M3 0000.050 MG/M3 0010.000 MG/M3 This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. Corrosive responses, burns. SKIN: Severe burns. Can be a skin sensitizer. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. Severe burns. INHALATION -OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. Severe burns. CHRONIC EFFECTS: Prolonged inhalation of dusts containing crystalline silica may result in the development of a lung disease known as silicosis. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). This product contains crystalline silica, which is considered a cancer hazard by inhalation of respirable dust. The Internation Agency for Research on Cancer (IARC) concluded that respirable crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1 B). TARGET ORGANS: Can be corrosive to eyes. Can cause respiratory tract irritation. Can be corrosive to skin. Can cause lung damage. Can cause gastrointestinal tract irritation. Can cause liver damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause kidney damage. Can cause respiratory tract sensitization. Can cause nervous system effects. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. -• •-�� -• •«•-��� OCIICSL �o�., Product class: PULYAMINE AMIDO AMINE SERIES 140 POTA-PDX PLUS Page 2 of 3 SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 78.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. CLEAN-UP: Nitrogen monoxide, nitrogen dioxide Will not occur. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES VAPOR PRESSURE VAPOR DENSITY LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION %VOLATILE BY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT 6.00 -N/A 241.0 °F 288.0 °F 13.6617 LB/GL 2.626 19.600 (Ether= 1) 19.222 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 PREPARED DATE: 07/22/2003 Series: N140-1SBLA Product Class: POLYAMINE AMIDO AMINE SERIES 140 POTA-PDX PLUS Page 3 of 3 This is a condensed MSDS, providing safety and health Information pertinent to the complete product series. Physical constants such as M./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safely and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Tnemec Company, Inc. For coatings, resins and related materials, approved by 123 West 23rd Avenue, Kansas City, MO 64116-3064 Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part Emergency Telephone: 800-535-5053 (INFOTRAC) 1910.1200, OSHA'S hazard communication standard. Telephone: 816-474-3400 NPCA 1-84 PREPARED DATE: 07/17/2003 Series: N140-0140B Product Class: EPDXY SERIES 140 POTA-PDX PLUS CONVE Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS VAPOR OCCUPATIONAL EXPOSURE LIMITS PRESS. ACGIH OSHA M INGREDIENTS CAS# % By Wt. s$G F TLV - TWA TLV - STEL TLV - C PEL -TWA PEL - STEL PEL - C XYLENE** 1330-20-7 12.27 5.100 0100.000 0150.000 0100.000 PPM PPM PPM TALC (RESPIRABLE DUST) 14807-96-6 31-40 0002.000 MG/M3 BISPHENOL A TYPE EPDXY RESIN 21-30 ETHYL BENZENE** 100-41-4 1.37 6.000 0100.000 0125.000 0100.000 PPM PPM PPM METHYL ISOBUTYL KETONE** 108-10-1 4.07 16.000 0050.000 0075.000 0100.000 PPM PPM PPM BISPHENOL A TYPE EPDXY RESIN 11-20 CRYSTALLINE SILICA (QUARTZ) 14808-60-7 5.68 0000.100 0000.050 MG/M3 MG/M3 ** SARA Reportable Product This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. SKIN: Moderate irritation, drying of skin, defatting and possible dermatitis. Allergic skin responses. Can be a skin sensitizer. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged contact or repeated overexposure to some epoxy compounds may result in permanent skin sensitization in susceptible individuals. Prolonged inhalation of dusts containing crystalline silica may result in the development of a lung disease known as silicosis. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. This product contains crystalline silica, which is considered a cancer hazard by inhalation of respirable dust. The Internation Agency for Research on Cancer (IARC) concluded that respirable crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 113). TARGET ORGANS: Can cause respiratory tract irritation. Can cause lung damage. Can cause skin sensitization. Can cause eye irritation. Can cause skin irritation. Can cause gastrointestinal tract irritation. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause liver damage. Can cause nervous system effects. Can cause kidney damage. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. PREPARED DATE: 07/17/2003 Series: N140-0140B Product Class: EPDXY SERIES 140 POTA-PDX PLUS CONVE Page 2 of 2 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 80.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous. ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION. Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION %VOLATILE BY VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT 16.00 -N/A 237.0 °F 288.0 °F 11.6218 LB/GL 2.111 9.400 (Ether= 1) 18.168 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments CONDITIONS TO AVOID: Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as VAR./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. NSF Certified to ANSI/NSF 61 PRODUCT PROFILE GENERIC DESCRIPTION Polyamide Epoxy COMMON USAGE Industry standard for potable water epoxy coatings for nearly 30 years. Known for its forgiving appli- cation characteristics in adverse and varied conditions, and for its benchmark performance. COLORS 1211 Red, 1255 Beige, 11WH White, 15BL Tank White, 39BL Delft Blue. Note: Epoxies chalk with extended exposure to sunlight. Lack of ventilation, incomplete mixing, miscatalyzation or the use of heaters that emit carbon dioxide and carbon monoxide during appli- cation and initial stages of curing may cause yellowing to occur. x SPECIAL QUALIFICATIONS Certified by NSF International in accordance with ANSI/NSF Std. 61. Ambient air cured Series 20 is qualified for use on the interior of potable water storage tanks and reservoirs of 1,000 gallons (3785 L) capacity or greater. Conforms to AWWA D 102 Inside Systems No. 1 and No. 2. Contact your Tnemec representative for approved systems and additional information on potential uses. PERFORMANCE CRITERIA Extensive test data available. Contact your Tnemec representative for specific test results. COATING SYSTEM PRIMERS Self -priming, 1, FC20, N140, N140F, 91-H2O, 94-H2O. Note: 91-112O is ANSI/NSF Std. 61 certified by U� as a primer for Series 20, Refer to the 91-H2O product data sheet for additional information. TOPCOATS Interior•. Series 20, FC20, N140, N140F, 264, 265 Exterior. Series 20, FC20, 66, N69, N69F, 73, N140, N140F, 161, 700, 701, 1074, 1075. Note: When topcoating with Series 700 or 701, an intermediate coat of Series 73 or 1075 is required. Refer to COLORS on applicable topcoat data sheets for additional information. SURFACE PREPARATION STEEL Immersion Service: SSPC-SP10/NACE 2 Near -White Blast Cleaning Non -Immersion Service: SSPC-SP6/NACE 3 Commercial Blast Cleaning PRIMED SURFACES Immersion Service: Scarify the Series 20 or FC20 prime coat by brush -blasting with fine abrasive before topcoating if it has been exterior exposed for 60 days or longer. CAST/DUCTILE IRON Contact your Tnemec representative or Tnemec Technical Services. CONCRETE Allow new concrete to cure for 28 days. Abrasive blast referencing SSPC-SP13/NACE 6, ICRI CSP 2-3 Surface Preparation of Concrete and Tnemec's Surface Preparation and Application Guide. Holes, pits, voids and cracks should be filled with 63-1500 Filler and Surfacer. All SURFACES Must be clean, dry and free of oil, grease, chalk and other contaminants. I 1 VOLUME SOLIDS* 57.0 t 2.0% (mixed) RECOMMENDED OFT 2.0 to 6.0 mils (50 to 150 microns) per coat. Note: Number of coats and thickness requirements will vary with substrate, application method and exposure. Contact your Tnemec representative. CURING TIME Temperature To Handle To Recoat Immersion 750F (241C) 10 hours 12 hours 7 da s Curing time varies with surface temperature, air movement, humidity and film thickness. Ventilation: When used in enclosed areas, provide adequate ventilation during application and cure. VOLATILE ORGANIC Unthinned Thinned 10% COMPOUNDS* 3.02lbs/gallon 3.37lbs/gallon (362 grams/litre) (404 grams/litre) HAPS 4.18 lbs/gal solids 5.16 lbs/gal solids THEORETICAL COVERAGE* 898 mil sq ft/gal (22.0 m'-/L at 25 microns). See APPLICATION for coverage rates. NUMBER OF COMPONENTS Two: Part A and Part B PACKAGING 5 gallon (18.90 pails and 1 gallon (3.79L) cans — Order in multiples of 2. NET WEIGHT PER GALLON* 12.50 t 0.25 lbs (5.7 t .11 kg) (mixed) STORAGE TEMPERATURE Minimum 20OF (-7°C) Maximum 110°F (43°C) TEMPERATURE RESISTANCE (Dry) Continuous 250°F (121*0 Intemuttent 275°F (135°C) SHELF LIFE Part A: 24 months at recommended storage temperature. Part B: 12 months at reconunended storage temperature. FLASH POINT- SETA Part A: 82*F (28*0 Part B: 647 (18°C) Published technical data and instructions are subject to change without notice. The online catalog at www.inemec.com should be referenced for the most current technical data and instructions or you may concoct your Tnemec representative for current technical data and instructions. Q August 22, 2007, by Tnemec Company, Inc. 20 TECHNICAL DATA continued HEALTH & SAFETY Paint products contain chemical ingredients which are considered hazardous. Read container label warning and Material Safety Data Sheet for important health and safety information prior to the use of this product. Keep out of the reach of children. APPLICATION COVERAGE RATES* MIXING POT LIFE THINNING SURFACE TEMPERATURE APPLICATION EQUIPMENT CLEANUP Dry Mils (Microns) Wet Mils (Microns) Sq Ft/" W/Gal) Suggested 4.0000) 7.0(180) 225 (20.9) Minimum 2.0 (50) 3.5 (90) 450 (41.8) Maximum 6.0050) 10.5 (265) 150 03.9) Note: The above reflects the total range to which Series 20 can be applied for specific applications. To insure the proper thickness and number of coats is specified for certain substrates and exposures, con- sult the Tnemec Guide Specifications and/or contact your Tnemec representative. Note: Roller or brush application requires two or more coats to obtain recommended film thickness. Allow for overspray and surface irregularities. Film thickness is rounded to the nearest 0.5 mil or 5 microns. Application of coating below minimum or above maximum recommended dry film thicknesses may adversely affect coating performance. Power mix contents of each container, making sure no pigment remains on the bottom. Pour a measured amount of Part B into a clean container large enough to hold both components. Add an equal volume of Part A to Part B while under agitation. Continue agitation until the two components are thoroughly mixed. Do not use mixed material beyond pot life limits. Note: Both components must be above 507 (10°C) prior to mixing. For application to surfaces between 50°F to 60°F (10°C to 160C), allow mixed material to stand thirty (30) minutes and restir before using. For optimum application properties, blended components should be above 60OF (16°C). Mixing ratio is one (Part A) to one (Part B) by volume. 20 hours at 50OF (10°C) 10 hours at 77*F (25°C) 4 hours at 100*F (38°C) Use No. 4 Thinner. For air spray, thin up to 10% or 3/4 pint (380 mL) per gallon. For airless spray, roller or brush, thin up to 5% or a/4 pint (190 mL) per gallon. Caution: Series 20 NSF certification is based on thinning with No. 4 Thinner. Use of any other thinner voids ANSI/NSF Std. 61 certification. Minimum 50°F (10°C) Maximum 1350F (57*0 The surface should be dry and at least 57 WC) above the dew point. Coating won't cure below mini- mum surface temperature. Air Svrav Gun Fluid Air Cap Air Hose MaVI Hose Atomizing Pot Tip ID ID Pressure Pressure DeVilbiss E 765 5/16" or 3/8" 3/8" or 1/2" 75-100 psi 10-20 psi JGA .070" or 704 (7.9 or 9.5 mm) (9.5 or 12.7 mm) (5.2-6.9 bar) (0.7-1.4 bar) Low temperatures or longer hoses require higher pot pressure. Airless Svrav Tip Orifice Atomizing Pressure Mat'1 Hose ID Manifold Filter 0.015"-0.019" (380485 microns) 1800-3000 psi (124-207 bar) 1/4" or 3/8" (6.4 or 9.5 mm) 60 mesh (250 microns) Use appropriate tip/atomizing pressure for equipment, applicator technique and weather conditions. Plural Component Spray: Contact your Tnemec representative or Tnemec Technical Services. Roller. Roller application optional when environmental restrictions do not allow spraying. Use 3/8" or 1/2" (9.5 mm to 12.7 nun) synthetic woven nap covers. Brush: Recommended for small areas only. Use high quality natural or synthetic bristle brushes. Flush and clean all equipment immediately after use with the recommended thinner or MEK. 'Values may vary with color. WARRANTY & LIMITATION OF SELLER'S LIABILITY: Tnemec Company, Inc. warrants only that its coatings represented herein meet the formulation standards of Tnemec Company, Inc. THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU OF ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The buyer's sole and exclusive remedy against Tnemec Company, Inc. shall be for replacement of the product in the event a defective condition of the product should be found to exist and the exclusive remedy shall not have failed its essential purpose as long as Tnemec is willing to provide comparable replacement product to the buyer. NO OTHER REMEDY (INCLUDING, BUT NOT LIMITED TO, INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR LOST PROFITS, LOST SALES, INJURY TO PERSON OR PROPERTY, ENVIRONMENTAL INJURIES OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE TO THE BUYER. Technical and application information herein is provided for the purpose of establishing a general profile of the coating and proper coating application procedures. Test performance results were obtained in a controlled environment and Tnemec Company makes no claim that these tests or any other tests, accurately represent all environments. As application, environmental and design factors can vary significantly, due care should be exercised in the selection and use of the coating. FOR INDUSTRIAL USE ONLY. TNEMEC COMPANY INCORPORATED PRINTED IN USA 6800 CORPORATE DRIVE, KANSAS CITY, MISSOURI 64120-1372 TEL: 1 800 TNEMEC 1 www.tnemec.com (1CDAT020) 20 Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 PREPARED DATE: 07/17/2003 Series: F020-11 WHA SECTION 2 - HAZARDOUS INGREDIENTS Material Safety Data Sheet (MSDS) Product Class: POLYAMIDE SERIES 020 POTA-PDX VAPOR PRESS. MMHG INGREDIENTS CAS# % By Wt. @ 68 °F N-BUTANOL (SKIN)** 71-36-3 8.50 4.400 POLYAMIDE RESIN 11-20 ALUMINUM OXIDES 1344-28-1 1-5 BARIUM SULFATE (TOTAL DUST) 7727-43-7 26.70 AMORPHOUS SILICA 7631-86-9 1-5 TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 11-20 XYLENE** 1330-20-7 10.83 5.100 ETHYL BENZENE** 100-41-4 2.53 6.000 TALC (RESPIRABLE DUST) 14807-96-6 11-20 ** SARA Reportable Product ACGIH For coatings, resins and related materials, approved by the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 OCCUPATIONAL EXPOSURE LIMITS TLV - TWA TLV -STEL TLV -C 0010.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0100.000 PPM 0100.000 PPM 0002.000 MG/M3 0150.000 PPM 0125.000 PPM 0050.000 PPM Page 1 of 2 OSHA PEL -TWA PEL -STEL PEL - C 0100.000 PPM 0010.000 MG/M3 0006.000 MG/M3 0010.000 MG/M3 0100.000 PPM 0100.000 PPM This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. May result in permanent visual loss. Corrosive responses, burns. SKIN: Potential sensitization Corrosive skin responses. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION -OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). TARGET ORGANS: Can be corrosive to eyes. Can cause respiratory tract irritation. Can be corrosive to skin. Can cause lung damage. Can cause liver damage. Can cause nervous system effects. Can cause gastrointestinal tract irritation. Can cause kidney damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: PREPARED DATE: 07/17/2003 Series: F020-11 WHA Product Class: POLYAMIDE SERIES 020 POTA-PDX Page 2 of 2 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 82.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. CLEAN-UP: SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous. ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use protective cream where skin contact is likely. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION %VOLATILE BY VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT 6.00 -N/A 241.0 °F 288.0 °F 14.3426 LB/GL 3.135 19.600 (Ether= 1) 21.868 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Nitrogen monoxide, nitrogen dioxide CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as M./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 Material Safety Data Sheet (MSDS) For coatings, resins and related materials, approved by the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 PREPARED DATE: 07/22/2003 Series: F020-1255A Product Class: POLYAMIDE SERIES 020 POTA-PDX Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS VAPOR PRESS. MMHG INGREDIENTS CAS# % By Wt. @ 68 ,F BARIUM SULFATE (TOTAL DUST) 772743-7 28.67 XYLENE** 1330-20-7 11.08 5.100 TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 11-20 TITANIUM DIOXIDE (TOTAL DUST) 1317-80-2 1-5 TALC (RESPIRABLE DUST) 14807-96-6 11-20 AMORPHOUS SILICA 7631-86-9 1-5 ALUMINUM OXIDES 1344-28-1 1-5 N-BUTANOL (SKIN)** 71-36-3 8.45 4.400 POLYAMIDE RESIN 11-20 ** SARA Reportable Product OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0010.000 MG/M3 0100.000 PPM 0010.000 MG/M3 0010.000 MG/M3 0002.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0150.000 PPM 0050.000 PPM PEL -TWA 0010.000 MG/M3 0100.000 PPM 0010.000 MG/M3 0010.000 MG/M3 0006.000 MG/M3 0100.000 PPM This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, [ARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. OSHA PEL-STEL PEL-C SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW. POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. May result in permanent visual loss. Corrosive responses, burns. SKIN: Potential sensitization Corrosive skin responses. INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 213). TARGET ORGANS: Can be corrosive to eyes. Can cause respiratory tract irritation. Can be corrosive to skin. Can cause lung damage. Can cause liver damage. Can cause nervous system effects. Can cause gastrointestinal tract irritation. Can cause kidney damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: PREPARED DATE: 07/22/2003 Series: F020-1255A Product Class: POLYAMIDE SERIES 020 POTA-PDX Page 2 of 2 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 82.0 'F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. CLEAN-UP: SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardousingredientsidentified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use protective cream where skin contact is likely. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 6.00 -N/A 24 1. 0 °F 288.0 °F 14.3170 LB/GL 3.168 19.600 (Ether= 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Nitrogen monoxide, nitrogen dioxide CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as Wt./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. %VOLATILE BY WEIGHT 22.137 Tnemec Company, Inc. For coatings, resins and related materials, approved by 123 West 23rd Avenue, Kansas City, MO 64116-3064 Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part Emergency Telephone: 800-535-5053 (INFOTRAC) 1910.1200, OSHA'S hazard communication standard. Telephone: 816-474-3400 NPCA 1-84 PREPARED DATE: 07/22/2003 Series: F020-15BLA Product Class: POLYAMIDE SERIES 020 POTA-PDX Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS TALC (RESPIRABLE DUST) XYLENE** AMORPHOUS SILICA BARIUM SULFATE (TOTAL DUST) ALUMINUM OXIDES POLYAMIDE RESIN N-BUTANOL (SKIN)** ETHYL BENZENE** TITANIUM DIOXIDE (TOTAL DUST) ** SARA Reportable Product CAS# 14807-96-6 1330-20-7 7631-86-9 7727-43-7 1344-28-1 71-36-3 100-41-4 13463-67-7 VAPOR PRESS. MMHG % By Wt. @ 68 o F 11-20 10.85 5.100 1-5 26.59 1-5 11-20 8.51 4.400 2.53 6.000 11-20 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C PEL -TWA 0002.000 MG/M3 0100.000 0150.000 0100.000 PPM PPM PPM 0010.000 0006.000 MG/M3 MG/M3 0010.000 0010.000 MG/M3 MG/M3 0010.000 MG/M3 0100.000 0125.000 PPM PPM 0010.000 MG/M3 0050.000 PPM 0100.000 PPM 0100.000 PPM 0010.000 MG/M3 This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. OSHA PEL-STEL PEL-C SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. May result in permanent visual loss. Corrosive responses, burns. SKIN: Potential sensitization Corrosive skin responses. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION -OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer ([ARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). TARGET ORGANS: Can be corrosive to eyes. Can cause respiratory tract irritation. Can be corrosive to skin. Can cause lung damage. Can cause liver damage. Can cause nervous system effects. Can cause gastrointestinal tract irritation. Can cause kidney damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: PREPARED DATE: 07/22/2003 Series: F020-15BLA Product Class: POLYAMIDE SERIES 020 POTA-PDX Page 2 of 2 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 82.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. CLEAN-UP: SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous. ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations, consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use protective cream where skin contact is likely. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 6.00 -N/A 241.0 °F 288.0 °F 14.3282 LB/GL 3.138 19.600 (Ether= 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Nitrogen monoxide, nitrogen dioxide CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as V\R./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result In the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. %VOLATILE BY WEIGHT 21.904 Tnemec Company, Inc. For coatings, resins and related materials, approved by 123 West 23rd Avenue, Kansas City, MO 64116-3064 Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to Emergency Telephone: 800-535-5053 (INFOTRAC) form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. Telephone: 816-474-3400 NPCA 1-84 PREPARED DATE: 07/22/2003 Series: F020-39BLA SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS TITANIUM DIOXIDE (TOTAL DUST) TALC (RESPIRABLE DUST) AMORPHOUS SILICA BARIUM SULFATE (TOTAL DUST) ALUMINUM OXIDES POLYAMIDE RESIN ETHYL BENZENE** XYLENE** N-BUTANOL (SKIN)** ** SARA Reportable Product Product Class: POLYAMIDE CAS# 13463-67-7 14807-96-6 7631-86-9 7727-43-7 1344-28-1 100-41-4 1330-20-7 71-36-3 VAPOR PRESS. MMHG % By Wt. @ 68 `F 11-20 11-20 1-5 28.53 1-5 11-20 2.61 6.000 11.18 5.100 8.50 4.400 SERIES 020 POTA-PDX OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0010.000 MG/M3 0002.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0100.000 0125.000 PPM PPM 0100.000 0150.000 PPM PPM 0050.000 PPM Page 1 of 2 OSHA PEL-TWA PEL-STEL PEL -C 0010.000 MG/M3 0006.000 MG/M3 0010.000 MG/M3 0100.000 PPM 0100.000 PPM 0100.000 PPM This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. May result in permanent visual loss. Corrosive responses, burns. SKIN: Potential sensitization Corrosive skin responses. INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 26). TARGET ORGANS: Can be corrosive to eyes. Can cause respiratory tract irritation. Can be corrosive to skin. Can cause lung damage. Can cause liver damage. Can cause nervous system effects. Can cause gastrointestinal tract irritation. Can cause kidney damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65. Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: PREPARED DATE: 07/22/2003 Series: F020-39BLA Product Class: POLYAMIDE SERIES 020 POTA-PDX Page 2 of 2 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 82.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. CLEAN-UP: SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use protective cream where skin contact is likely. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 6.00 -N/A 241.0 °F 288.0 °F 14.2479 LB/GL 3.177 19.600 (Ether= 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Nitrogen monoxide, nitrogen dioxide CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as VV[./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. %VOLATILE BY WEIGHT 22.302 Tnemec Company, Inc. For coatings, resins and related materials, approved by 123 West 23rd Avenue, Kansas City, MO 64116-3064 Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to Telephone: 800-535-5053 (INFOTRAC) form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHNS hazard communication standard. WWEmergency Telephone: 816-474-3400 NPCA 1-84 PREPARED DATE: 07117/2003 Series: B020-0020B Product Class: EPDXY SERIES 20/FC20 POTA-PDX CONVE Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS XYLENE** METHYL ISOBUTYL KETONE** TALC (RESPIRABLE DUST) BISPHENOL A TYPE EPDXY RESIN BISPHENOL A TYPE EPDXY RESIN CAS# 1330-20-7 108-10-1 14807-96-6 VAPOR PRESS. MMHG % By Wt. @ 68 ' F 11.10 5.100 15.34 16.000 31-40 11-20 21-30 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0100.000 0150.000 PPM PPM 0050.000 0075.000 PPM PPM 0002.000 MG/M3 OSHA PEL -TWA PEL - STEL PEL - C 0100.000 PPM 0100.000 PPM ** SARA Reportable Product This substance contains a material classified as a hazardous air pollutant. This product contains no reported carcinogens or suspected carcinogens. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. SKIN. Moderate irritation, drying of skin, defatting and possible dermatitis. Allergic skin responses. Can be a skin sensitizer. INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged contact or repeated overexposure to some epoxy compounds may result in permanent skin sensitization in susceptible individuals. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous.system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. TARGET ORGANS: Can cause eye irritation. Can cause respiratory tract irritation. Can cause lung damage. Can cause skin sensitization. Can cause skin irritation. Can cause gastrointestinal tract irritation. Can cause liver damage. Can cause kidney damage. Can cause nervous system effects. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 64.0 *F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. PRFPARFD DATF* 07/17/2003 Series: B020-0020B Product Class: EPDXY SERIES 20/FC20 POTA-PDX CONVE Page 2 of 2 SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 16.00 -N/A 237.0 °F 288.0 °F 10.6705 LB/GL 2.895 9.200 (Ether= 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments CONDITIONS TO AVOID: Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as =./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. %VOLATILE BY WEIGHT 27.132 PRODUCT PROFILE GENERIC DESCRIPTION Polyanilde Epoxy COMMON USAGE Fast -curing protective coating for use in steel and concrete potable water storage facilities. Contact your Tnemec representative for other systems and additional information on potential uses. COLORS 1211 Red, 1255 Beige, 11WH White, 15BL Tank White, 39BL Delft Blue. Note: Epoxies chalk with extended exposure to sunlight. Lack of ventilation, incomplete mixing, miscatalyzation or the use of heaters that emit carbon dioxide and carbon monoxide during appli- cation and initial stages of curing may cause yellowing to occur. ® SPECIAL QUALIFICATIONS Certified by NSF International in accordance with ANSI/NSF Std. 61 for use on the interior of potable water storage tanks and reservoirs of 1,000 gallons (3785 L) capacity or greater. Conforms to AWWA D 102 Inside Systems No. 1 and No. 2. Contact your Tnemec representative for approved systems and additional information on potential uses. PERFORMANCE CRITERIA Extensive test data available. Contact your Tnemec representative for specific test results. COATING PRIMERS Self 20, 91-H2O, N140, N140F. Note: 91-H2O is ANSI/NSF Std. 61 certified by k -priming, as a primer for Series FC20. Refer to the 91-H2O product data sheet for additional inforation. TOPCOATS Interior: Series 20, FC20, N140, N140F, 264, 265 Exterior: Series 20, FC20, 66, N69, 73, 104, N140, N140F, 161, 175, 700, 1074, 1075. Note: When topcoating with Series 700, an intermediate coat of Series 73 or 1075 is required. N%)'F Refer to COLORS on applicable topcoat data sheets for additional information. SURFACE PREPARATION STEEL Immersion Service: SSPC-SP10/NACE 2 Near -White Blast Cleaning Certified to Non -Immersion Service: SSPC-SP6/NACE 3 Commercial Blast Cleaning ANSUNSF 61 PRIMED SURFACES Immersion Service: Scarify the Series FC20 prime coat surface by abrasive -blasting with fine abra- sive before topcoating if it has been exposed to sunlight for 60 days or longer. CAST/DUCTILE IRON Contact your Tnemec representative or Tnemec Technical Services. CONCRETE Allow new concrete to cure for 28 days. Abrasive blast referencing SSPC-SPl3/NACE 6 Surface Preparation of Concrete and Tnemec's Surface Preparation and Application Guide. Holes, pits, voids and cracks should be filled with 63-1500 Filler and Surfacer. ALL SURFACES Must be clean, dry and free of oil, grease and other contaminants. TECHNICAL DATA VOLUME SOLIDS* 58.0 t 2.0% (mixed) RECOMMENDED OFT CURING TIME VOLATILE ORGANIC COMPOUNDS* THEORETICAL COVERAGE* 2.0 to 6.0 mils (50 to 150 microns) per coat. Note: Number of coats and thickness requirements will vary with substrate, application method and exposure. Contact your Tnemec representative. TPn,TPTA I'IefP Tn Touch To Handle To Recoat Immersion 750F (24°C) 1 hour 2 hours 3 hours 6 days 65°F (18°C) 2 hours 4 hours 5-6 hours 8 days 557 (13°C) 3-4 hours 6-8 hours 10-12 hours 12 days 450F (7°C) 6-7 hours 12-14 hours 16-18 hours 20 days 350F (2°C) 8-10 hours 16-18 hours 20-22 hours 25 days Curing time varies with surface temperature, air movement, humidity and film thickness. Unthinned Thinned 10% 2.94 lbs/gallon 3.30 lbs/gallon (352 grams/litre) (395 grams/litre) 930 mil sq ft/gal (22.8 m2/L at 25 microns). See APPLICATION for coverage rates. NUMBER OF COMPONENTS Two: Part A and Part B PACKAGING 5 gallon (18.9L) pails and 1 gallon (3.79L) cans — Order in multiples of 2. NET WEIGHT PER GALLON* 12.50 t 0.25 lbs (5.7 t .11 kg) (mixed) STORAGE TEMPERATURE Minimum 20°F (-7°C) Maximum 110°F (43°C) TEMPERATURE RESISTANCE (Dry) Continuous 250°F (121°C) Intermittent 275*F (135°C) Published technical data and instructions are subject to change without notice. The online catalog at www-tnemec.Cam should be referenced for the most current technical data and instructions or you may contact your Tnemec representative for current technical data and instructions. 0 March 2004, by Tnemec Company, Inc. FC20 TECHNICAL DATA continued SHELF LIFE Part A: 24 months; Part B: 12 months at recommended storage temperature. FLASH POINT. SETA Part A: 82*F (28°C) Part B: 64OF (18°C) HEALTH & SAFETY Paint products contain chemical ingredients which are considered hazardous. Read container label warning and Material Safety Data Sheet for important health and safety information prior to the use of this product. Keep out of the reach of children. APPLICATION COVERAGE RATES* MIXING POT LIFE THINNING SURFACE TEMPERATURE APPLICATION EQUIPMENT CLEANUP Dry Mils (Microns) Wet Mils (Microns) Sq Ft/Gal (m2/Gal) Suggested 4.0(100) 7.0080) 232 (21.6) Minimum 2.0 (50) 3.5 (90) 465 (43.3) Maximum 6.0(150) 10.5 (265) 155 (14.4) Note: The above reflects the total range to which Series FC20 can be applied for specific applications. To insure the proper thickness and number of coats is specified for certain substrates and exposures, consult the Tnemec Guide Specifications and/or contact your Tnemec representative. Note: Roller or brush application requires two or more coats to obtain recommended film thickness. Allow for over - spray and surface irregularities. Film thickness is rounded to the nearest 0.5 mil or 5 microns. Applica- tion of coating below minimum or above maximum recommended dry film thicknesses may adversely affect coating performance. Power mix contents of each container, making sure no pigment remains on the bottom. Pour a measured amount of Part B into a clean container large enough to hold both components. Add an equal volume of Part A to Part B while under agitation. Continue agitation until the two components are thoroughly mixed. Do not use mixed material beyond pot life limits. Note: Both components should be above 50OF (10*C) prior to mixing. For application to surfaces between 350F to 50°F (2°C to 10*C), allow mixed material to stand thirty (30) minutes and restir before using. For optimum application properties, blended components should be above 60°F (160C). 16 hours at 35*F (2*C) 2 hours at 77°F (25°C) 1h hour at 100°F (38*C) Use No. 4 Thinner. For air spray, thin up to 10% or 3/4 pint (380 mL) per gallon. For airless spray, roller or brush, thin up to 5% or V4 pint (190 mL) per gallon. Caution: Series FC20 NSF certification is based on thinning with No. 4 Thinner. Use of any other thinner voids ANSI/NSF Std. 61 certification. Minimum 35°F (2°C) Maximum 1350F (57°C) The surface should be dry and at least 50F WC) above the dew point. Coating won't cure below mini- mum surface temperature. Air Spray Gun Fluid Air Cap Air Hose Mat'l Hose Atomizing Pot Tip ID ID Pressure Pressure DeVilbiss E 765 5/16" or 3/8" 3/8" or 1/2" 75-100 psi 10-20 psi MBC or JGA or 78 (7.9 or 9.5 mm) (9.5 or 12.7 mm) (5.2-6.9 bar) (0.7-1.4 bar) Low temperatures or longer hoses require higher pot pressure. Airless Svrav Tip Orifice Atomizing Pressure Mat'l Hose ID Manifold Filter 0.015"-0.019" (380-485 microns) 1800-3000 psi (124-207 bar) 1/4" or 3/8" (6.4 or 9.5 mm) 60 mesh (250 microns) Use appropriate tip/atomizing pressure for equipment, applicator technique and weather conditions. Plural Component Spray: Contact your Tnemec representative or Tnemec Technical Services. Roller: Roller application optional when environmental restrictions do not allow spraying. Use 3/8" or 1/2" (9.5 mm to 12.7 mm) synthetic nap covers. Brush: Recommended for small areas only. Use high quality natural or synthetic bristle brushes. Flush and clean all equipment immediately after use with the recommended thinner or MEK. *Values may vary with color. WARRANTY & LIMITATION OF SELLER'S LIABILITY: Tnemec Company, Inc. warrants only that its coatings represented herein meet the formulation standards of Tnemec Company, Inc. THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU OF ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMITED T0, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The buyer's sale and exclusive remedy against Tnemec Company, Inc. shall be for replacement of the product in the event a defective condition of the product should be found to exist and the exclusive remedy shall not hove failed its essential purpose as long as Tnemec is willing to provide comparable replacement product to the buyer. NO OTHER REMEDY (INCLUDING, BUT NOT LIMITED TO, INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR LOST PROFITS, LOST SALES, INJURY TO PERSON OR PROPERTY, ENVIRONMENTAL INJURIES OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE TO THE BUYER. Technical and application information herein is provided for the purpose of establishing a general profile of the coating and proper coating application procedures. Test performance results were obtained in o controlled environment and Tnemec Company makes no claim that these tests or any other tests, o(curotely represent all environments. As application, environmental and design factors can vary significantly, due care should be exercised in the selection and use of the coating. FOR INDUSTRIAL USE ONLY. TNEMEC COMPANY INCORPORATED PRINTED IN USA 6800 CORPORATE DRIVE, RANSAS CITY, MISSOURI 64120-1372 TEL: 1 800 TNEMEC 1 www.tnemec.com (YDAT021) FC20 Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) ® Telephone:816-474-3400 PREPARED DATE: 07/1712003 Series: FC20-11 WHA SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS MODIFIED ALIPHATIC AMINE ALUMINUM OXIDES TITANIUM DIOXIDE (TOTAL DUST) BARIUM SULFATE (TOTAL DUST) TALC (RESPIRABLE DUST) POLYAMIDE RESIN N-BUTANOL (SKIN)`* AMORPHOUS SILICA XYLENE** ** SARA Reportable Product For coatings, resins and related materials, approved by Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 Product Class: POLYAMIDE SERIES FC20 POTA-PDX FC Page 1 of 2 CAS# 1344-28-1 13463-67-7 7727-43-7 14807-96-6 71-36-3 7631-86-9 1330-20-7 VAPOR PRESS. MMHG % By Wt. Cq 68 o F 1-5 1-5 11-20 29.09 11-20 11-20 8.46 4.400 1-5 9.30 5.100 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV-STEL TLV -C 0010.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0002.000 MG/M3 0010.000 MG/M3 0100.000 0150.000 PPM PPM 0050.000 PPM PEL -TWA 0010.000 MG/M3 0010.000 MG/M3 0100.000 PPM 0006.000 MG/M3 0100.000 PPM This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, [ARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. OSHA PEL-STEL PEL -C SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. May result in permanent visual loss. Corrosive responses, burns. SKIN: Allergic skin responses. Can be a skin sensitizer. Corrosive skin responses. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). TARGET ORGANS: Can cause respiratory tract irritation. Can be corrosive to skin. Can cause lung damage. Can cause eye damage. Can cause liver damage. Can cause gastrointestinal tract damage. Can cause kidney damage. Can cause nervous system effects. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. PREPARED DATE: 07/17/2003 Series: FC20-11 WHA Product Class: POLYAMIDE SERIES FC20 POTA-PDX FC Page 2 of 2 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 82.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION %VOLATILE BY VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT 6.00 -N/A 241.0 °F 288.0 °F 14.4091 LB/GL 2.869 19.600 (Ether= 1) 19.917 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Nitrogen monoxide, nitrogen dioxide CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 3 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as NA./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemee.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 Material Safety Data Sheet (MSDS) For coatings, resins and related materials, approved by the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 PREPARED DATE: 07/22/2003 Series: FC20-1211A Product Class: POLYAMIDE SERIES FC20 POTA-PDX FC Page 1 of 3 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS BARIUM SULFATE (TOTAL DUST) N-BUTANOL (SKIN)** IRON OXIDE FUME ETHYL BENZENE** XYLENE** CRYSTALLINE SILICA (QUARTZ) TALC (RESPIRABLE DUST) MODIFIED ALIPHATIC AMINE POLYAMIDE RESIN ** SARA Reportable Product CAS# 7727-43-7 71-36-3 1309-37-1 100-41-4 1330-20-7 14808-60-7 14807-96-6 VAPOR PRESS. MMHG % By Wt. @ 68 a F 36.51 8.24 4.400 11-20 2.15 6.000 9.42 5.100 1.96 11-20 1-5 11-20 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0010.000 MG/M3 0050.000 PPM 0005.000 MG/M3 0100.000 0125.000 PPM PPM 0100.000 0150.000 PPM PPM 0000.100 MG/M3 0002.000 MG/M3 OSHA PEL -TWA PEL -STEL PEL - C 0010.000 MG/M3 0100.000 PPM 0010.000 MG/M3 0100.000 PPM 0100.000 PPM 0000.050 MG/M3 This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP. IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. May result in permanent visual loss. Corrosive responses, burns. SKIN: Allergic skin responses. Discoloration. Can be a skin sensitizer. Corrosive skin responses. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged inhalation of dusts containing crystalline silica may result in the development of a lung disease known as silicosis. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). This product contains crystalline silica, which is.considered a cancer hazard by inhalation of respirable dust. The Internation Agency for Research on Cancer (IARC) concluded that respirable crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1 B). TARGET ORGANS: Can be corrosive to skin. Can cause respiratory tract irritation. Can cause lung damage. Can cause eye damage. Can cause liver damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause gastrointestinal tract damage. Can cause kidney damage. Can cause nervous system effects. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. PREPARED DATE: 07/22/2003 Series: FC20-1211A Product Class: POLYAMIDE SERIES FC20 POTA-PDX FC Page 2 of 3 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 82.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 6.00 -N/A 241.0 °F 288.0 °F 14.7443 LB/GL 2.922 19.600 (Ether = 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Nitrogen monoxide, nitrogen dioxide CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 3 Flammability: 3 Reactivity: 1 %VOLATILE BY WEIGHT 19.823 PRFPARFn nATF• 07/22/2003 Series: FC20-1211A Product Class: POLYAMIDE SERIES FC20 POTA-PDX FC Page 3 of 3 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as Wt./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 PREPARED DATE: 07/22/2003 Series: FC20-1255A SECTION 2 - HAZARDOUS INGREDIENTS For coatings, resins and related materials, approved by Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 Product Class: POLYAMIDE SERIES FC20 POTA-PDX FC Page 1 of 3 VAPOR PRESS. MMHG INGREDIENTS CAS# % By Wt. @ 68 ° F AMORPHOUS SILICA 7631-86-9 1-5 TITANIUM DIOXIDE (TOTAL DUST) 1317-80-2 1-5 TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 11-20 XYLENE** 1330-20-7 10.56 5.100 ETHYL BENZENE** 100-41-4 2.46 6.000 POLYAMIDE RESIN 11-20 MODIFIED ALIPHATIC AMINE 1-5 ALUMINUM OXIDES 1344-28-1 1-5 BARIUM SULFATE (TOTAL DUST) 7727-43-7 27.73 TALC (RESPIRABLE DUST) 14807-96-6 11-20 ** SARA Reportable Product OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0010.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0100.000 PPM 0100.000 PPM 0010.000 MG/M3 0010.000 MG/M3 0002.000 MG/M3 0150.000 PPM 0125.000 0050.000 PPM PPM PEL -TWA 0006.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0100.000 PPM 0100.000 PPM 0010.000 MG/M3 This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. OSHA PEL-STEL PEL-C SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. May result in permanent visual loss. Corrosive responses, burns. SKIN: Allergic skin responses. Can be a skin sensitizer. Corrosive skin responses. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION -OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). TARGET ORGANS: Can cause respiratory tract irritation. Can be corrosive to skin. Can cause lung damage. Can cause eye damage. Can cause liver damage. Can cause gastrointestinal tract damage. Can cause kidney damage. Can cause nervous system effects. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. PREPARED DATE: 07/22/2003 Series: FC20-1255A Product Class: POLYAMIDE SERIES FC20 POTA-PDX FC Page 2 of 3 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 82.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION %VOLATILE BY VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT 6.00 -N/A 241.0 °F 288.0 °F 14.1561 LB/GL 2.981 19.600 (Ether= 1) 21.064 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Nitrogen monoxide, nitrogen dioxide CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 3 Flammability: 3 Reactivity: 1 PREPARED DATE: 07/22/2003 Series: FC20-1255A Product Class: POLYAMIDE SERIES FC20 POTA-PDX FC Page 3 of 3 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as M./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. Al materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 Material Safety Data Sheet (MSDS) For coatings, resins and related materials, approved by the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 PREPARED DATE: 07/22/2003 Series: FC20-15BLA Product Class: POLYAMIDE SERIES FC20 POTA-PDX FC TANK W Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS POLYAMIDE RESIN TITANIUM DIOXIDE (TOTAL DUST) XYLENE** TALC (RESPIRABLE DUST) MODIFIED ALIPHATIC AMINE ALUMINUM OXIDES BARIUM SULFATE (TOTAL DUST) AMORPHOUS SILICA N-BUTANOL (SKIN)** — SARA Reportable Product VAPOR PRESS. MMHG CAS# % By Wt. @ 68 ° F 13463-67-7 1330-20-7 14807-96-6 1344-28-1 7727-43-7 7631-86-9 71-36-3 11-20 11-20 9.30 5.100 11-20 1-5 1-5 29.11 1-5 8.46 4.400 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0010.000 MG/M3 0100.000 0150.000 PPM PPM 0002.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0050.000 PPM PEL -TWA 0010.000 MG/M3 0100.000 PPM 0010.000 MG/M3 0006.000 MG/M3 0100.000 PPM This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. OSHA PEL-STEL PEL-C SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. May result in permanent visual loss. Corrosive responses, burns. SKIN: Allergic skin responses. Can be a skin sensitizer. Corrosive skin responses. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on are International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 26). TARGET ORGANS: Can cause respiratory tract irritation. Can be corrosive to skin. Can cause lung damage. Can cause eye damage. Can cause liver damage. Can cause gastrointestinal tract damage. Can cause kidney damage. Can cause nervous system effects. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT. Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. PREPARED DATE: 07/22/2003 Series: FC20-15BLA Product Class: POLYAMIDE SERIES FC20 POTA-PDX FC TANK W Page 2 of 2 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 82.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous. ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION %VOLATILE BY VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT 6.00 -N/A 241.0 °F 288.0 °F 14.4148 LB/GL 2.871 19.600 (Ether = 1) 19.920 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Nitrogen monoxide, nitrogen dioxide CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 3 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as VVI./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 Material Safety Data Sheet (MSDS) For coatings, resins and related materials, approved by the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 PREPARED DATE: 07/22/2003 Series: FC20-39BLA Product Class: POLYAMIDE SERIES FC20 POTA-PDX FC Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS POLYAMIDE RESIN N-BUTANOL (SKIN)" ALUMINUM OXIDES BARIUM SULFATE (TOTAL DUST) AMORPHOUS SILICA TALC (RESPIRABLE DUST) TITANIUM DIOXIDE (TOTAL DUST) XYLENE** MODIFIED ALIPHATIC AMINE ** SARA Reportable Product CAS# 71-36-3 1344-28-1 7727-43-7 7631-86-9 14807-96-6 13463-67-7 1330-20-7 VAPOR PRESS. MMHG %ByWt. @68'F 11-20 8.48 4.400 1-5 28.47 1-5 11-20 11-20 9.66 5.100 1-5 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0010.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0002.000 MG/M3 0010.000 MG/M3 0100.000 PPM 0150.000 PPM 0050.000 PPM OSHA PEL -TWA PEL - STEL PEL - C 0100.000 PPM 0010.000 MG/M3 0006.000 MG/M3 0010.000 MG/M3 0100.000 PPM This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. May result in permanent visual loss. Corrosive responses, burns. SKIN: Allergic skin responses. Can be a skin sensitizer. Corrosive skin responses. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 213). TARGET ORGANS: Can cause respiratory tract irritation. Can be corrosive to skin. Can cause lung damage. Can cause eye damage. Can cause liver damage. Can cause gastrointestinal tract damage. Can cause kidney damage. Can cause nervous system effects. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. PREPARED DATE: 07/22/2003 Series: FC20-39BLA Product Class: POLYAMIDE SERIES FC20 POTA-PDX FC Page 2 of 2 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 82.0 °F 1.0 -NIA -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous. ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 6.00 -N/A 241.0 °F 288.0 °F 14.2812 LB/GL 2.911 19.600 (Ether= 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Nitrogen monoxide, nitrogen dioxide CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 3 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as NA./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. %VOLATILE BY WEIGHT 20.383 Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 For coatings, resins and related materials, approved by Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part Emergency Telephone: 800-535-5053 (INFOTRAC) 1910.1200, OSHA'S hazard communication standard. Telephone: 816-474-3400 NPCA 1-84 PREPARED DATE: 07/17/2003 Series: B020-0020B Product Class: EPDXY SERIES 20/FC20 POTA-PDX CONVE Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS VAPOR PRESS. MMHG INGREDIENTS CAS# % By Wt. @ 68 ° F XYLENE** 1330-20-7 11.10 5.100 METHYL ISOBUTYL KETONE** 108-10-1 15.34 16.000 TALC (RESPIRABLE DUST) 14807-96-6 31-40 BISPHENOL A TYPE EPDXY RESIN 11-20 BISPHENOL A TYPE EPDXY RESIN 21-30 ** SARA Reportable Product OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0100.000 0150.000 PPM PPM 0050.000 0075.000 PPM PPM 0002.000 MG/M3 OSHA PEL-TWA PEL-STEL PEL -C 0100.000 PPM 0100.000 PPM This substance contains a material classified as a hazardous air pollutant. This product contains no reported carcinogens or suspected carcinogens. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. SKIN: Moderate irritation, drying of skin, defatting and possible dermatitis. Allergic skin responses. Can be a skin sensitizer. INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged contact or repeated overexposure to some epoxy compounds may result in permanent skin sensitization in susceptible individuals. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous.system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. TARGET ORGANS: Can cause eye irritation. Can cause respiratory tract irritation. Can cause lung damage. Can cause skin sensitization. Can cause skin irritation. Can cause gastrointestinal tract irritation. Can cause liver damage. Can cause kidney damage. Can cause nervous system effects. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 64.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. PREPARED DATE: 07/17/2003 Series: B020-0020B Product Class: EPDXY SERIES 20/FC20 POTA-PDX CONVE Page 2 of 2 SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section 11 of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 16.00 -N/A 237.0 °F 288.0 °F 10.6705 LB/GL 2.895 9.200 (Ether= 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments CONDITIONS TO AVOID: Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as Wt./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. % VOLATILE BY WEIGHT 27.132 NSF Certified to ANSI/NSF 61 PRODUCT PROFILE GENERIC DESCRIPTION Modified Polyamine Epoxy COMMON USAGE High solids potable water coating which offers high -build edge protection and excellent corrosion resistance. For use on the interior and exterior of steel or concrete tanks, reservoirs, pipes, valves, pumps and equipment in potable water service. COLORS 1211 Red, 1255 Beige, 33GR Gray and WH03 Off -White. Note: Epoxies chalk with extended expo- sure to sunlight. Lack of ventilation, incomplete mixing, miscatalyzation or the use of heaters that emit carbon dioxide and carbon monoxide during application and initial stages of curing may cause ® yellowing to occur. SPECIAL QUALIFICATIONS Certified by NSF International in accordance with ANSI/NSF Std. 61. Ambient air cured Series 141 is qualified for use on tanks and reservoirs of 1,000 gallons (3,785 L) capacity or greater, pipes eight (8) inches (20 cm) in diameter or greater and valves two (2) inches (5 cm) in diameter or greater. Conforms to AW WA D 102 Inside Systems No. 1 and No. 2. Conforms to AW WA C 210. Contact your Tnemec representative for systems and additional information. PERFORMANCE CRITERIA Extensive test data available. Contact your Tnemec representative for specific test results. COATING SYSTEM I PRIMERS Self -priming, 91-112O, N140, N140F TOPCOATS Exterior. Series 73, 180, 1074, 1075, 1080. Refer to COLORS on applicable topcoat data sheets for additional information. Note: The following maximum recoat time applies when using Series 73, 180, 1074, 1075 or 1080: thirty (30) days. If this time limit is exceeded, Series 141 must be uniformly scarified prior to topcoating. SURFACE PREPARATION STEEL Immersion Service: SSPC-SP10/NACE 2 Near -White Blast Cleaning. Non -Immersion Service: SSPC-SP6/NACE 3 Commercial Blast Cleaning PRIMED STEEL Immersion Service: Scarify the Series N140 or N140F prime coat surface by brush -blasting with fine abrasive before topcoating if it has been exposed for 30 days or longer and 141 is the specified topcoat. CONCRETE Allow to cure for 28 days. Abrasive blast referencing SSPC-SP13/NACE 6 Surface Preparation of Con- crete and Tnemec's Surface Preparation and Application Guide. ALL SURFACES Must be clean, dry and free of oil, grease, chalk and other contaminants. TECHNICAL DATA VOLUME SOLIDS* RECOMMENDED DFT CURING TIME AT 5 MILS OFT VOLATILE ORGANIC COMPOUNDS* THEORETICAL COVERAGE* NUMBER OF COMPONENTS MIXING RATIO PACKAGING 82% t 2.0% (mixed) 4.0 to 18.0 mils (100 to 455 microns) in one coat. Note: Number of coats and thickness require- ments will vary with substrate, application method and exposure. Contact your Tnemec representative. Maximum dry film thickness for NSF exposure is 18.0 mils. Temperature To Handle To Recoat Immersion 90°F (32°C) 3 hours 4 hours 7 days 75°F (24°C) 4 hours 5 hours 7 days 65°F (18°C) 7 hours 9 hours 8 days 55°F (11°C) 13 hours 18 hours 9 days 45°F (7°C) 20 hours 30 hours 13 days 40°F (4°C) 22 hours 42 hours 18 days Curing time varies with surface temperature, air movement, humidity and film thickness. Note: For pipe and valve applications, allow 14 days cure at 75°F (24°C) prior to immersion. Unthinned Thinned 5% Thinned 10% 1.30lbs/gallon 1.57lbs/gallon 1.81lbs/gallon (156 grams/litre) (188 grams/litre) (217 grams/litre) 1,315 mil sq ft/gal (32.2 m2/L at 25 microns). See APPLICATION for coverage rates. Two: Part A and Part B Rv vnhsme- Two (Part A) to one (Part B) PART A (Partially Filled) PART B (Partially Filled) When Mixed Large Kit 1-6 gallon pail 1-2 gallon pail 5 gallons Small Kit 1-1 gallon can 1-1 gallon can 1 gallon NET WEIGHT PER GALLON* 13.33 t 0.25 lbs (6.05 t .11 kg) (mixed) STORAGE TEMPERATURE Minimum 20°F (-7°C) Maximum 110°F (43°C) Prior to application, the material temperature should be above 60°F (16°C). It is suggested the ma- terial be stored at this temperature at least 48 hours prior to use. Published technical data and Instructions are subject to change without notice. The online catalog at www.tnemec.com should be referenced for the most current technical data and instructions or you may contact your Tnemec representative for current technical data and instructions. © March 28, 2007 by Tnemec Company, Inc. 141 TECHNICAL DATA continued TEMPERATURE RESISTANCE (Dry) Continuous 250OF (121°C) Intermittent 275°F (135*C) SHELF LIFE 12 months at recommended storage temperature. FLASH POINT - SETA Part A: 91°F (33"C) Part B: 111OF (44°C) HEALTH & SAFETY This product contains chemical ingredients which are considered hazardous. Read container label warn- ing and Material Safety Data Sheet for important health and safety information prior to the use of this product. Keep out of the reach of children. APPLICATION COVERAGE RATES* Dry Mils (Microns) Wet Mils (Microns) Sq Ft/Gal (mZ/Gal) Minimum 4.0000) 5.0(125) 329 (30.5) Maximum 18.0 (455) 22.0 (560) 73 (6.8) Note: Maximum of 18.0 mils DFT in one coat for water tanks, pipes and valves. Maximum total dry film thickness for NSF exposure is 18.0 mils. Roller or brush application requires multiple coats to obtain recommended film thickness. Allow for overspray and surface irregularities. Wet film thickness is rounded to the nearest 0.5 mil or 5 microns. Application of coating below minimum or above maximum recommended dry film thicknesses may adversely affect coating performance. MIXING Mix the entire contents of Part A and Part B separately. Scrape all of the Part B into the Part A pail by using a flexible spatula. Use a variable speed drill with a PS Jiffy blade and mix the blended compo- nents for a minimum of two minutes. Apply the mixed material within pot life limits after agitation. Both components must be above 50°F (10°C) prior to mixing. For optimum application properties, the material temperature should be above 60OF (160C). For applications to surfaces between 40*F to 50°F WC to 10*C) allow mixed material to stand 30 minutes and restir before use. Note: A large volume of material will set up quickly if not applied or lessened in mass. Caution: Do not reseal mixed mate- rial. An explosion hazard may he created. POT LIFE 2 hours at 77°F (21°C) 1 hour at 90°F (32°C) SPRAY LIFE 1 hour at 770F (21°C) 30 minutes at 90*F (32°C) THINNING Caution: Do not add thinner to Part A prior to mixing with Part B. Use No. 4 Thinner. For airless spray, roller or brush, thin up to 5% or I/4 pint (190 ml.) per gallon. For air spray, thin up to 10% or 3/ pint (380 mL) per gallon. Caution: Series 141 NSF certification is based on thinning with No. 4 Thinner. Use of any other thinner voids ANSI/NSF Std. 61 certification. SURFACE TEMPERATURE Minimum 40OF (4°C) Maximum 135*F (57°C) The surface should be dry and at least 57 (3*C) above the dew point. Coating will not cure below minimum surface temperature. APPLICATION EQUIPMENT Air Spray Gun Fluid Air Cap Air Hose Mat'1 Hose Atomizing Pot Tip ID ID Pressure Pressure DeVilbiss E 765 5/16" or 3/8" 3/8" or 1/2" 75-100 psi 10-20 psi Ic :� or 704 (7.9 or 9.5 mm) (95 or 12.7 mm) (5.2-6.9 bar) (0.7-1.4 bar) Low temperatures or longer hoses require higher pot pressure. Airless Spray Tip Orifice Atomizing Pressure Mat'l Hose ID Manifold Filter 0.017"-0.021" (430-535 microns) 3000-3800 psi (207-262 bar) 1/4" or 3/8" (6.4 or 9.5 mm) 60 mesh (250 microns) Use appropriate tip/atomizing pressure for equipment, applicator technique and weather conditions. Roller: Roller application optional when environmental restrictions do not allow spraying. Use 3/8" or 1/2" (9.5 mm to 12.7 mm) synthetic nap covers. Brush: Recommended for small areas only. Use high quality natural or synthetic bristle brushes. CLEANUP Flush and clean all equipment immediately after use with the recommended thinner or MEK. *Values may vary with color. WARRANTY 8 LIMITATION OF SELLER'S LIABILITY: Tnemec Company, Inc. warrants only that its coatings represented herein meet the formulation standards of Tnemec Company, Inc. THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU OF ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMITED To, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The buyer's sole and exclusive remedy against Tnemec Company, Inc. shall be for replacement of the product in the event a defective condition of the product should be found to exist and the exclusive remedy shall not have failed its essential purpose as long as Tnemec is willing to provide comparable replacement product to the buyer. NO OTHER REMEDY (INCLUDING, BUT NOT UMITED TO, INCIDENTAL OR CONSEOUENTIAt DAMAGES FOR LOST PROFITS, LOST SALES, INJURY TO PERSON OR PROPERTY, ENVIRONMENTAL INJURIES OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE TO THE BUYER. Technical and application information herein is provided for the purpose of establishing a general profile of the coating and proper coating application procedures. Test performance results were obtained in a controlled environment and Tnemec Company makes no claim that these tests or any other tests, accurately represent all environments. As application, environmental and design factors can vary significantly, due care should be exercised in the selection and use of the coating. FOR INDUSTRIAL USE ONLY. TNEMEC COMPANY INCORPORATED PRINTED IN USA 6800 CORPORATE DRIVE, KANSAS CITY, MISSOURI 64120.1372 TEL: 1 800 TNEMEC 1 www.tnemec.com 141 Tnemec Company, Inc. For coatings, resins and related materials, approved by 123 West 23rd Avenue, Kansas City, MO 64116-3064 Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part Emergency Telephone: 800-535-5053 (INFOTRAC) 1910.1200, OSHA'S hazard communication standard. Telephone: 816-474-3400 NPCA 1-84 PREPARED DATE: 04/26/2004 Series: F141-WH03A Product Class: MODIFIED POLYAMINE POTA-PDX 80 WHITE Page 1 of 3 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS CRYSTALLINE SILICA (QUARTZ) CRYSTALLINE SILICA (QUARTZ) TITANIUM DIOXIDE (TOTAL DUST) TALC (RESPIRABLE DUST) MICA (RESPIRABLE DUST) AMORPHOUS SILICA ALUMINUM OXIDES MODIFIED ALIPHATIC AMINE MODIFIED POLYAMINE N-BUTANOL (SKIN)* BENZYLALCOHOL ETHYL BENZENE"" XYLENE" CAS# 14808-60-7 14808-60-7 13463-67-7 14807-96-6 12001-26-2 7631-86-9 1344-28-1 71-36-3 100-51-6 100-41-4 1330-20-7 VAPOR PRESS. MMHG %ByWt. @68'F 7.00 25.87 11-20 21-30 1-5 1-5 1-5 1-5 6-10 1.56 4.400 3.26 1.56 6.000 6.25 5.100 OCCUPATIONAL EXPOSURE LIMITS ACGIH OSHA TLV - TWA TLV - STEL TLV - C 0000.100 MG/M3 0000.100 MG/M3 0010.000 MG/M3 0002.000 MG/M3 0003.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 0100.000 0125.000 PPM PPM 0100.000 0150.000 PPM PPM 0050.000 PPM PEL-TWA PEL-STEL PEL-C 0000.050 MG/M3 0000.050 MG/M3 0010.000 MG/M3 0002.000 MG/M3 0003.000 MG/M3 0006.000 MG/M3 0100.000 PPM 0100.000 PPM 0100.000 PPM SARA Reportable Product This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. PREPARED DATE: 04/26/2004 Series: F141-WH03A Product Class: MODIFIED POLYAMINE POTA-PDX 80 WHITE Page 2 of 3 SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW. POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. Corrosive responses, burns. SKIN: Allergic skin responses. Severe burns. Can be a skin sensitizer. INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. Corrosive responses and possible burns to the gastrointestinal tract. INHALATION -OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Severe burns. Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged inhalation of dusts containing crystalline silica may result in the development of a lung disease known as silicosis. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). This product contains crystalline silica, which is considered a cancer hazard by inhalation of respirable dust. The Internation Agency for Research on Cancer (IARC) concluded that respirable crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1 B). TARGET ORGANS: Can be -corrosive to skin. Can cause lung damage. Can be corrosive to respiratory tract. Can cause eye damage. Can cause liver damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause gastrointestinal tract damage. Can cause kidney damage. Can cause nervous system effects. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 91.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in -dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron tc protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. PREPARED DATE: 04/26/2004 Series: F141-WH03A Product Class: MODIFIED POLYAMINE POTA-PDX 80 WHITE SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Page 3 of 3 LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 6.00 -N/A 241.0 °F 288.0 °F 15.3091 LB/GL 1.595 19.600 (Ether= 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Nitrogen monoxide, nitrogen dioxide Ammonia CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as Wt./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. %VOLATILE BY WEIGHT 10.430 Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 Material Safety Data Sheet (MSDS) For coatings, resins and related materials, approved by the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910,1200. OSHA'S hazard communication standard. NPCA 1-84 PREPARED DATE: 04/26/2004 Series: F141-0141B Product Class: POTA-PDX 80 CONVERTER Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS BISPHENOL A TYPE EPDXY RESIN ETHYL BENZENE** XYLENE** METHYL ISOBUTYL KETONE** VAPOR PRESS. MMHG CAS# % By Wt. @ 68 ° F >90 100-41-4 .41 6.000 1330-20-7 1.64 5.100 108-10-1 5.36 16.000 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0100.000 0125.000 PPM PPM 0100.000 0150.000 PPM PPM 0050.000 0075.000 PPM PPM OSHA PEL -TWA PEL -STEL PEL - C 0100.000 PPM 0100.000 PPM 0100.000 PPM ** SARA Reportable Product This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. SKIN: Moderate irritation, drying of skin, defatting and possible dermatitis. Allergic skin responses. Can be a skin sensitizer. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged contact or repeated overexposure to some epoxy compounds may result in permanent skin sensitization in susceptible individuals. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. TARGET ORGANS: Can cause eye irritation. Can cause skin sensitization. Can cause skin irritation. Can cause respiratory tract irritation. Can cause gastrointestinal tract irritation. Can cause lung damage. Can cause liver damage. Can cause nervous system effects. Can cause kidney damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 111.0 *F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. PREPARED DATE: 04/26/2004 Series: F141-0141 B Product Class: POTA-PDX 80 CONVERTER Page 2 of 2 SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION %VOLATILE BY VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT 16.00 -N/A 237.0 °F 288.0 °F 9.3602 LB/GL .694 9.400 (Ether= 1) 7.416 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Acids. Bases. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Aldehydes. CONDITIONS TO AVOID: Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as Wl./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. PRODUCT PROFILE GENERIC DESCRIPTION Hydrophobic Acrylic Polymer COMMON USAGE An advanced technology, direct -to -metal coating with very good early flash -rust resistance, as well as long term corrosion protection and weathering properties. Formulated to resist mildew growth on the paint film. Provides good gloss and color retention on structural steel, tanks, towers, pipes and similar structures. May also be used on a wide range of other substrates and many aged coatings, interior or exterior (test patch is recommended per Technical Bulletin 98- 10). Application methods include "dry -fall" under certain conditions (see Application). Note: Spra-Saf EN's "dry -fall" characteristics help reduce the potential for overspray problems on buildings and surrounding property. COLORS Refer to Tnemec Color Guide. FINISH Satin PERFORMANCE CRITERIA Extensive test data available. Contact your Tnemec representative for specific test results. COATING PRIMERS Steel: Self -priming or Series 10, 18, 27, 37H, 66, N69, 90E-92, 90-96, 135, N140,151, 161. Note: Allow Series 10 and 37H to cure one week before topcoating. SURFACE PREPARATION STEEL Weather Exposed: SSPC-SP6/NACE 3 Commercial Blast Cleaning Enclosed or Protected: SSPC-SP3 Power Tool Cleaning PAINTED SURFACES Remove chalk and old paint not tightly bonded to the surface. Clean all visible rust to bare metal using SSPC-SP11 Power Tool Cleaning to Bare Metal. Feather edges of thick coatings and dull glossy surfaces. (Test patch is recommended.) GALVANIZED STEEL & Surface preparation suggestions will vary depending on substrate and exposure conditions. ALUMINUM Contact your Tnemec representative or Tnemec Technical Services. ALL SURFACES Must be clean, dry and free of oil, grease and other contaminants. VOLUME SOLIDS* 38.0 ± 2.0% RECOMMENDED DET 2.0 to 4.0 mils (50 to 100 microns) per coat. Note: Number of coats required will vary de- pending on color, substrate (surface) and other variables. Contact your Tnemec representative. CURING TIME Temperature To Touch To Handle To Recoat Curing time varies with surface temperature, air movement, humidity and film thickness. VOLATILE ORGANIC Unthinned Thinned 5% COMPOUNDS* 1.601bs/gallon 1.601bs/gallon (192 grams/litre) (192 grams/litre) THEORETICAL COVERAGE* 610 mil sq ft/gal (15.0 mz/L at 25 microns). See APPLICATION for coverage rates. NUMBER OF COMPONENTS One PACKAGING 55 gallon (208.21.) drums, 5 gallon (18.90 pails and 1 gallon (3.79L) cans. NET WEIGHT PER GALLON* 10.39 ± 0.25 lbs (4.7 ± .11 kg) STORAGE TEMPERATURE Minimum 40'F (4°C) Maximum 95°F (35°C) TEMPERATURE RESISTANCE (Dry) Continuous 170*F (77°C) Intermittent 200OF (93°C) SHELF LIFE 12 months at recommended storage temperature. FLASH POINT - SETA Non-flammable HEALTH & SAFETY Paint products contain chemical ingredients which are considered hazardous. Read container label warning and Material Safety Data Sheet for important health and safety information prior to the use of this product. Keep out of the reach of children. Published technical data and instructions are subject to change without notice. The online catalog at www.tnemic.com should be referenced for the most current technical data and instructions or you may contact your Toemec representative for current technical data and instructions. O May 2004, by Tnemec Company, Inc. 30 APPLICATION CAUTION! Dry overspray can be wiped or washed from most surfaces. Satisfactory dry -fall perfor- mance depends upon height of work, weather conditions and equipment adjustment. Low temperature and high humidity are of particular concern. Test for each application as follows: Spray from 15 to 25 feet towards paint container. The material then should readily wipe off. Note: Heat can fuse -dry overspray to surfaces. Always clean dry over - spray from hot surfaces before fusing occurs. Be aware that exterior surface tempera- tures can be higher than air temperature. COVERAGE RATES" Dry Mils (Microns) Wet Mils (Microns) Sq Ft/Gal (m=/Gat) Suggested 3.0 (75) 8.0(205) 205 (19.0) Minimum 2.0 (50) 5.5(140) 305 (28.3) Maximum 4.0(100) 10.5 (265) 155 (14.4) Allow for overspray and surface irregularities. Film thickness is rounded to the nearest 05 rmx or.) microns. Application of coating below minimum or above maximum recommended dry film thick- nesses may adversely affect coating performance. MIXING Mix by stirring to uniform consistency without creating air bubbles and foam. Stir thoroughly, mak- ing sure no pigment remains on the bottom of the can. Do not box or use a paint shaker. THINNING Use only clean tap water. For air spray, thin up to 100/o or 3/ pint (380 mL) per gallon. For airless spray, brush or roller, thin up to 5% or r/4 pint (190 mL) per gallon. SURFACE TEMPERATURE Minimum 45°F (7*C) Maximum 120°F (49'C) The surface should be dry and at least 5°F (3°C) above the dew point. Cure time necessary to resist direct contact with moisture at surface temperature: At 750F (240C): 1 hour. At 45°F (70C): 3 hours. APPLICATION EQUIPMENT Air Spray Gun Fluid Air Cap Air Hose Mat'l Hose Atomizing Pot Tip 11D ID Pressure Pressure DeVilbiss E 765 5/16" or 3/8" 3/8" or 1/2" 50-70 psi 10-20 psi MBC or JGA or 54 (7.9 or 9.5 mm) (9.5 or 12.7 mm) (3.4-4.8 bar) (0.7-1.4 bar) Low temperatures or longer hoses require higher pot pressure. Airless Snrav Tip Orifice Atomizing Pressure Mat'l Hose ID Manifold Filter 0.013"-0.017" 1800-2400 psi 1/4" or 3/8" 60 mesh (330-430 microns) (124-165 bar) (6.4 or 9.5 mm) (250 microns) Reversible Tip Use appropriate tip/atomizing pressure for equipment, applicator technique and weather concuuons. Note: On projects involving spray equipment being used over consecutive days, follow Cleanup in- structions below and then leave xylol in the system overnight, flushing thoroughly with clean water before each start-up. Roller: Application not recommended. Brush: Recommended for small areas only. Use only synthetic or nylon bristle brushes. CLEANUP Flush and clean all equipment immediately after use with clean tap water. Finish by flushing all spray equipment with isopropyl alcohol. Wash brushes in water to remove paint build-up during and after application *Values may vary with color. WARRANTY R LIMITATION OF SELLER'S LIABILITY: Tnemec Company, Inc. warrants only that its coatings represented herein meet the formulation standards of Tnemec Company, Inc. THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU OF ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The buyer's sole and exclusive remedy against Tnemec Company, Inc. shall be for replacement of the product in the event a defective condition of the product should be found to exist and the exclusive remedy shall not have failed its essential purpose as long as Tnemec is willing to provide comparable replacement product to the buyer. NO OTHER REMEDY (INCLUDING, BUT NOT LIMITED 10, INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR LOST PROFITS, LOS] SALES, INJURY TO PERSON OR PROPERTY, ENVIRONMENTAL INJURIES OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE TO THE BUYER. Technical and application information herein is provided for the purpose of establishing a general profile of the coating and proper coating application procedures. Test performance results were obtained in a controlled environment and Tnemec Company makes no claim that these tests of any other tests, accurately represent all environments. As application, environmental and design factors can vary significantly, due care should be exercised in the selection and use of the coating. FOR INDUSTRIAL USE ONLY. TNEMEC COMPANY INCORPORATED PRINTED IN USA 6800 CORPORATE DRIVE, KANSAS CITY, MISSOURI 64120.1372 TEL: 1 800 TNEMEC 1 www.tnemec.com (YDAT030) 30 Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 PREPARED DATE: 07/17/2003 Series: F030-11WH SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS TEXANOL DIETHYLENE GLYCOL MONOBUTYL ETHER** PROPRIETARY PIGMENT (NIUSANCE DUST) BARIUM COMPOUNDS** TITANIUM DIOXIDE (TOTAL DUST) Material Safety Data Sheet (MSDS) Product Class: ACRYLIC SERIES 030 SPRA-SAF EN VAPOR PRESS. MMHG CAS# % By Wt. @ 68 ° F 25265-77-4 1-5 1.000 112-34-5 3.80 .020 1-5 3.39 13463-67-7 11-20 ACGIH For coatings, resins and related materials, approved by the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 OCCUPATIONAL EXPOSURE LIMITS TLV - TWA TLV - STEL TLV - C 0010.000 MG/M3 0000.500 MG/M3 0010.000 MG/M3 Page 1 of 2 OSHA PEL-TWA PEL-STEL PEL -C 0005.000 MG/M3 0010.000 MG/M3 0010.000 MG/M3 ** SARA Reportable Product This substance contains a material classified as a hazardous air pollutant. This product contains no reported carcinogens or suspected carcinogens. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Moderate irritation. Redness, tearing, blurred vision. SKIN: Mild irritation, drying of skin. INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, weakness, fatigue, nausea, and headache. INHALATION -OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death. CHRONIC EFFECTS: NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. TARGET ORGANS: Can cause eye irritation. Can cause respiratory tract irritation. Can cause gastrointestinal tract irritation. Can cause kidney damage. Can cause nervous system effects. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER -N/A °F .6 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Spills may be collected with inert, absorbent material for proper disposal. Use protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable container for disposal. PREPARED DATE: 07117/2003 Series: F030-11 WH Product Class: ACRYLIC SERIES 030 SPRA-SAF EN Page 2 of 2 SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous. ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 1.00 -N/A 446.0 °F 500.0 °F 10.3836 LB/GL 1.590 .000 (Ether= 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments CONDITIONS TO AVOID: POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 3 Flammability: 1 Reactivity: 1 This is a condensed MSDS, providing safely and health information pertinent to the complete product series. Physical constants such as VAR./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. %VOLATILE BY WEIGHT 7.389 7 PRODUCT PROFILE GENERIC DESCRIPTION Polyamide Epoxy COMMON USAGE Industry standard for epoxy coatings for over 30 years. Known for its forgiving application characteris- tics in adverse and varied conditions, and for benchmark performance. COLORS Refer to Tnemec Color Guide. Note: Epoxies chalk with extended exposure to sunlight and may yellow on aging. Lack of ventilation, incomplete mixing, miscatalyzation or the use of heaters that emit carbon dioxide and carbon monoxide during application and initial stages of curing may ac- celerate any potential yellowing. FINISH Satin SPECIAL QUALIFICATIONS Meets the performance requirements of AWWA C 210 (not for potable water contact). Contact your Tnemec representative for system recommendations. PERFORMANCE CRITERIA Extensive test data available. Contact your Tnemec representative for specific test results. 'COATIENG SYSTEM PRIMERS Steel: Self -priming or Series 1, 20, FC20, 37H, N69, 90, 91-H2O, 94-H20, 161, 394, 530 Galvanized Steel and Non -Ferrous Metal: Self -priming Concrete: Self -priming, 54-660, 201, 216, 218 CMU: 54-562, 54-660, 130, 216, 218 Drywall: 51-792 for dry interior environments TOPCOATS 46H-413, 66, N69, 73, 84, 104, 113, 114, 161, 262, 265, 290, 291, 1070, 1071, 1072, 1074, 1074U, 1075, 1075U, 1077, 1078. Refer to COLORS on applicable topcoat data sheets for additional information. Note: A maximum recoat time may apply depending on the topcoat specified. Refer to the applicable topcoat product sheet for information on product specific maximum recoat times. SURFACE PREPARATION STEEL Immersion Service: SSPC-SP10/NACE 2 Near -White Blast Cleaning Non -Immersion Service: SSPC-SP6/NACE 3 Commercial Blast Cleaning PRIMED STEEL Immersion Service: Scarify the Series 66 prime coat surface by abrasive -blasting with a fine abrasive before topcoating if: (a) the 66 prime coat has been in exterior exposure for 60 days or longer and 66, 46H-413, N69 or 161 is the specified topcoat; (b) the 66 prime coat has been in exterior exposure for 14 days or longer and Series 104 is the specified topcoat; (c) the 66 prime coat has been in exterior exposure for 7 days or longer and Series 262 or 265 is the specified topcoat. GALVANIZED STEEL & Surface preparation recommendations will vary depending on substrate and exposure NON-FERROUS METAL conditions. Contact your Tnemec representative or Tnemec Technical Services. CAST/DUCTILE IRON Contact your Tnemec representative or Tnemec Technical Services. CONCRETE Allow new concrete to cure 28 days. For optimum results and/or immersion service, abrasive blast referencing SSPC-SP13/NACE 6 Surface Preparation of Concrete and Tnemec's Surface Preparation and Application Guide. CMU Allow mortar to cure for 28 days. Prepare in accordance with SSPC-SP13/NACE 6 to level protru- sions and mortar spatter, and remove other contaminants. PAINTED SURFACES Non -Immersion Service: Ask your Tnemec representative for specific recommendations. ALL SURFACES Must be clean, dry and free of oil, grease and other contaminants. TECHNICAL DATA VOLUME SOUDS* 56.0 t 2.0% (mixed) RECOMMENDED DFT 2.0 to 6.0 mils (50 to 150 microns) per coat. Note: Number of coats and thickness requirements will vary with substrate, application method and exposure. Contact your Tnemec representative. CURING TIME Temperature To Touch To Handle To Recoat Immersion 75°F (24°C) 2 hours 10 hours 12 hours 7 days Curing time varies with surface temperature, air movement, humidity and film thickness. Ventilation: When used as a tank lining or in enclosed areas, provide adequate ventilation during application and cure. Reference guidelines contained in the latest edition of AWWA D 102. VOLATILE ORGANIC Unthinned Thinned 5% Thinned 10% COMPOUNDS* 3.021bs/gallon 3.20lbs/gallon 337lbs/gallon (362 grams/litre) (384 grams/litre) (404 grams/litre) THEORETICAL COVERAGE* 898 mil sq ft/gal (22.0 m'-/L at 25 microns). See APPLICATION for coverage rates. NUMBER OF COMPONENTS Two: Part A and Part B PACKAGING 5 gallon (18.9L) pails and 1 gallon (3.79L) cans - Order in multiples of 2. NET WEIGHT PER GALLON* 12.50 t 0.25 1bs (5.67 t .11 kg) (mixed) Published technical data and instructions are subject to change without notice. The online catalog at www.tnemec.com should be referenced for the most current technical data and instructions or you may contact your Tnemec representative for current technical data and instructions. 66 0 May 29, 2007, by Tnemec Company, Inc. TECHNICAL DATA continued STORAGE TEMPERATURE Minimum 20°F (-7°C) Maximum 110°F (43"C) TEMPERATURE RESISTANCE (Dry) Continuous 250°F (121°C) Intermittent 2750F (135°C) SHELF LIFE Part A: 24 months; Part B: 12 months at recommended storage temperature. FLASH POINT - SETA Part A: 827 (28°C) Part B: 640F (18°C) HEALTH 8 SAFETY Paint products contain chemical ingredients which are considered hazardous. Read container label warning and Material Safety Data Sheet for important health and safety information prior to the use of this product. Keep out of the reach of children. (OVERAGE RATES` MIXING POT LIFE THINNING SURFACE TEMPERATURE APPLICATION EQUIPMENT CLEANUP Dry Mils (Microns) Wet Mils (Microns) Sq Ft/Gal (m2/Gral) Suggested 4.0000) 7.0(180) 225 (20.9) Minimum 2.0 (50) 3.5 (90) 450 (41.8) Maximum 6.0(150) 10.5 (265) 150 (13.9) Note: The above reflects the total range to which Series 66 can be applied for specific applications. To insure the proper thickness and number of coats is specified for certain substrates and exposures, con- sult the Tnemec Guide Specifications and/or contact your Tnemec representative. Note: Roller or brush application may require two or more coats to obtain recommended film thickness. Allow for overspray and surface irregularities. Wet film thickness is rounded to the nearest 0.5 mil or 5 microns. Application of coating below minimum or above maximum reconunended dry film thicknesses may adversely affect coating performance. Power mix contents of each container, making sure no pigment remains on the bottom. Pour a measured amount of Part B into a clean container large enough to hold both components. Add an equal volume of Part A to Part B while under agitation. Continue agitation until the two components are thoroughly mixed. Do not use mixed material beyond pot life limits. Note: Both components should be above 50°F (10°C) prior to mixing. For application to surfaces between 50°F to 60°F (10°C to 16°C), allow mixed material to stand thirty (30) minutes and restir before using. For optimum application properties, blended components should be above 60*F (16*C). Mixing ratio is one to one by volume. 20 hours at 50°F (10°C) 10 hours at 77OF (25°C) 4 hours at 100°F (38°C) Use No. 4 Thinner. For air spray, thin up to 10% or 3/ pint (380 ML) per gallon. For airless spray, roller or brush, thin up to 5% or 1/4 pint (190 mL) per gallon. Minimum 50°F (10°C) Maximum 135*F (57 0 The surface should be dry and at least 5°F (3°C) above the dew point. Coating will not cure below minimum surface temperature. Air Spray Gun Fluid Air Cap Air Hose MaVI Hose Atomizing Pot Tip II) ID Pressure Pressure Devilbiss E 765 5/16" or 3/8" 3/8" or 1/2" 75-100 psi 10-20 psi or 704 (7.9 or 9.5 mm) (9.5 or 12.7 mm) (5.2-6.9 bar) (0.7-1.4 bar) Low temperatures or longer hoses require higher pot pressure. Airless Spray Tip orifice Atomizing Pressure Mat'1 Hose ID Manifold Filter 0.015"-0.019" (380-485 microns) 3000-4000 psi (207-276 bar) 1/4" or 3/8" (6.4 or 9.5 mm) 60 mesh (250 microns) Use appropriate tip/atomizing pressure for equipment, applicator technique and weather conditions. Note: Application over inorganic zinc -rich primers: Apply a wet mist coat and allow tiny bubbles to form. When bubbles disappear in 1 to 2 minutes, apply a full wet coat at specified nvl thickness. Roller: Roller application optional when environmental restrictions do not allow spraying. Use 3/8" or 1/2" (9.5 mm to 12.7 mm) synthetic woven nap covers. Brush: Recommended for small areas only. Use high quality natural or synthetic bristle brushes. Flush and clean all equipment immediately after use with the recommended thinner or MEK. *Values may vary with color. WARRANTY R LIMITATION OF SELLER'S LIABILITY: Tnemec Company, Inc. warrants only that its coatings represented herein meet the formulation standards of Tnemec Company, Inc. THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU OF ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FORA PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The buyer's sole and exclusive remedy against Tnemec Company, Inc. shall be for replacement of the product in the event a defective condition of the product should be found to exist and the exclusive remedy shall not have failed its essential purpose as long as Tnemec is willing to provide comparable replacement product to the buyer. NO OTHER REMEDY (INCLUDING, BUT NOT LIMITED TO, INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR LOST PROFITS, LOST SALES, INJURY TO PERSON OR PROPERTY, ENVIRONMENTAL INJURIES OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE TO THE BUYER. Technical and application information herein is provided for the purpose of establishing a general profile of the coating and proper coating application procedures. Test performance results were obtained in a controlled environment and Tnemec Company makes no claim that these tests or any other tests, accurately represent all environments. As application, environmental and design factors can vary significantly, due care should be exercised in the selection and use of the coating. FOR INDUSTRIAL USE ONLY. TNEMEC COMPANY INCORPORATED PRINTED IN USA 6800 CORPORATE DRIVE, RANSAS CITY, MISSOURI 64120-1372 TEL: 1 800 TNEMEC 1 www.tnemeC.COM (YDAT065) 66 Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 Material Safety Data Sheet (MSDS) For coatings, resins and related materials, approved by the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 PREPARED DATE: 07/17/2003 Series: F066-WH01A Product Class: POLYAMIDE SERIES 066 HI -BUILD EPDXOLINE Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS AMORPHOUS SILICA TITANIUM DIOXIDE (TOTAL DUST) TALC (RESPIRABLE DUST) XYLENE** ETHYL BENZENE** N-BUTANOL (SKIN)`* POLYAMIDE RESIN ALUMINUM OXIDES BARIUM SULFATE (TOTAL DUST) ** SARA Reportable Product CAS# 7631-86-9 13463-67-7 14807-96-6 1330-20-7 100-41-4 71-36-3 1344-28-1 7727-43-7 VAPOR PRESS. MMHG % By Wt. @ 68 `F 1-5 11-20 11-20 10.81 5.100 2.58 6.000 8.73 4.400 11-20 1-5 27.20 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0010.000 MG/M3 0010.000 MG/M3 0002.000 MG/M3 0100.000 0150.000 PPM PPM 0100.000 0125.000 PPM PPM 0050.000 PPM 0010.000 MG/M3 0010.000 MG/M3 OSHA PEL-TWA PEL-STEL PEL-C 0006.000 MG/M3 0010.000 MG/M3 0100.000 PPM 0100.000 PPM 0100.000 PPM 0010.000 MG/M3 This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW. POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. May result in permanent visual loss. Corrosive responses, burns. SKIN: Potential sensitization Corrosive skin responses. INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). TARGET ORGANS: Can be corrosive to eyes. Can cause respiratory tract irritation. Can be corrosive to skin. Can cause lung damage. Can cause liver damage. Can cause nervous system effects. Can cause gastrointestinal tract irritation. Can cause kidney damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: PREPARED DATE: 07/17/2003 Series: F066-WH01A Product Class: POLYAMIDE SERIES 066 HI -BUILD EPDXOLINE rage [ or 1 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 82.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. CLEAN-UP: SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use protective cream where skin contact is likely. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION %VOLATILE BY VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT 6.00 -N/A 241.0 °F 288.0 °F 14.3058 LB/GL 3.166 19.600 (Ether= 1) 22.135 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Nitrogen monoxide, nitrogen dioxide CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as NA./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 PREPARED DATE: 07/17/2003 Series: B066-0066B For coatings, resins and related materials, approved by Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 Product Class: EPDXY F65/66/160/161 CONVERTER Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS VAPOR OCCUPATIONAL EXPOSURE LIMITS PRESS. ACGIH OSHA INGREDIENTS CAS# % By wt. MMHG@ 68 ° F TLV -TWA TLV -STEL TLV - C PEL -TWA PEL -STEL PEL - C BISPHENOL A TYPE EPDXY RESIN 21-30 XYLENE** 1330-20-7 11.10 5.100 0100.000 0150.000 0100.000 PPM PPM PPM BISPHENOL A TYPE EPDXY RESIN 11-20 TALC (RESPIRABLE DUST) 14807-96-6 31-40 0002.000 MG/M3 METHYL ISOBUTYL KETONE** 108-10-1 15.34 16.000 0050.000 0075.000 0100.000 PPM PPM PPM ** SARA Reportable Product This substance contains a material classified as a hazardous air pollutant. This product contains no reported carcinogens or suspected carcinogens. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. SKIN: Moderate irritation, drying of skin, defatting and possible dermatitis. Allergic skin responses. Can be a skin sensitizer. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged contact or repeated overexposure to some epoxy compounds may result in permanent skin sensitization in susceptible individuals. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervoussystem damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. TARGET ORGANS: Can cause eye irritation. Can cause respiratory tract irritation. Can cause lung damage. Can cause skin sensitization. Can cause skin irritation. Can cause gastrointestinal tract irritation. Can cause liver damage. Can cause kidney damage. Can cause nervous system effects. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 64.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. PREPARED DATE: 07/17/2003 Series: B066-0066B Product Class: EPDXY F65/66/160/161 CONVERTER Page 2 of 2 SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION %VOLATILE BY VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT 16.00 -N/A 237.0 °F 288.0 °F 10.6705 LB/GL 2.895 9.200 (Ether= 1) 27.132 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments CONDITIONS TO AVOID: Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as Wt./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. PRODUCT PROFILE GENERIC DESCRIPTION Polyamide Epoxy -Coal Tar COMMON USAGE High -build corrosion resistant coating providing one coat protection for concrete and steel in a variety of chemical, immersion and underground conditions. Also, when a two -coat application is desired, a low film build option is possible. COLOR Black FINISH Semi -gloss SPECIALOUALIFICATIONS Conforms to the performance requirements of AWWA C 210 (not for potable water contact). PERFORMANCE CRITERIA Extensive test data available. Contact your Tnemec representative for specific test results. PRIMERS Steel: Self -priming or Series 1, 66, N69, N69F, 90-97, H90-97, 161 Galvanized Steel: Series 66, N69, N69F, 161 Concrete: Self -priming, 63-1500, 218 SURFACE PREPARATION , STEEL Immersion Service: SSPC-SP10 Near -White Blast Cleaning Non -Immersion Service: SSPC-SP6 Commercial Blast Cleaning GALVANIZED STEEL Surface preparation recommendations will vary depending on substrate and exposure condi- tions. Contact your Tnemec representative or Tnemec Technical Services. PRIMED SURFACES Immersion Service: Scarify the surface with fine abrasive before topcoating if the Series 66, N69 or 161 prime coat has been exposed to sunlight for 60 days or longer. CAST/DUCTILE IRON Contact your Tnemec representative or Tnemec Technical Services. CONCRETE Allow new concrete to cure for 28 days. Abrasive blast all surfaces referencing SSPC-SP13/ NACE 6, ICRI CSP 2-4 Surface Preparation of Concrete and Tnemec's Surface Preparation and Application Guide. ALL SURFACES Must be clean, dry and free of oil, grease and other contaminants. VOLUME SOLIDS 75.0 ± 2.0% (mixed) RECOMMENDED DFT 16.0 to 20.0 mils (405 to 510 microns) 8.0 to 10.0 mils (200 to 250 microns) for the two -coat option CURING TIME To Recoat Temperature To Touch (Min./Max) Immersion 950F (35°C) 2 hours 3-14 hours 5 days 850F (29°C) 3 hours 4-18 hours 6 days 757 (24°C) 4 hours 6-28 hours 7 days 657 (18°C) 6 hours 10-50 hours 10 days 55°F (13°C) 9 hours 16 hrs - 3 days 14-16 days 450F (7°C) 18 hours 32 hrs - 4 days 22-24 days 357 (2°C) 1-26 hours 44 hrs - 6 days 28-32 days Curing time varies with surface temperature, air movement, humidity and film thickness. Use the above times as guidelines only. Scarify the surface with fine abrasive before recoating if the maximum recoat time has been exceeded. VOLATILE ORGANIC Unthinned Thinned 20% (No. 2 Thinner) Thinned 20% (No. 65 Thinner) COMPOUNDS 1.911bs/gallon 2.801bs/gallon 1.91lbs/gallon (229 grams/litre) (335 grams/litre) (229 grams/litre) THEORETICAL COVERAGE 1,203 mil sq ft/gal (29.5 m'/L at 25 microns). See APPLICATION for coverage rates. NUMBER OF COMPONENTS Two: Part A and Part B MIXING RATIO By volume: One (Part A) to one (Part B) PACKAGING 5 gallon (18.9L) pails and 1 gallon (3.79L) cans — Order in multiples of 2. NET WEIGHT PER GALLON 11.74 ± 0.25 lbs (5.32 ± .11 kg) (mixed) STORAGE TEMPERATURE Minimum 207 (-7°C) Maximum 110°F (43°C) Published technical data and Instructions are subject to change without notice. The online catalog at www.tnemac.com should be referenced for the most current technical data and instructions or you may contact your Tnemec representative for current technical data and instructions. 0 August 22, 2007, by Tnemec Company, Inc. 46H-413 TECHNICAL DATA.continued TEMPERATURE RESISTANCE (Dry) Continuous 200OF (93°C) Intermittent 250OF (121°C) SHELF LIFE 12 months at recommended storage temperature. FLASH POINT • SETA Parts A & B: 81OF (27°C) HEALTH AND SAFETY Paint products contain chemical ingredients which are considered hazardous. Read container label warning and Material Safety Data Sheet for important health and safety information prior to the use of this product. Keep out of the reach of children. APPLICATION COVERAGE RATES Conventional Build Two -Coat System (DFT each coat) Dry Mils (Microns) wet Mils (Microns) Sq Ft/Gal (m2/Gal) Dry Mils (Microns) Wet Mils (Microns) Sq Ft/Gal (mZ/Gal) Suggested 18.0 (455) 24.0 (610) 69(6.4) 9.0(225) 12.0 (300) 134 (12.5) Minimum 16.0 (405) 21.5 (545) 75 (7.0) 8.0(200) 11.0 (275) 150 (14.0) Maximum 20.0 (510) 27.0 (685) 59 (5.5) 10.0 (250) 13.0 (325) 120 (11.2) Allow for overspray and surface irregularities. Film thickness is rounded to the nearest 0.5 mil or 5 microns. Application of coating below minimum or above maximum recommended dry film thick- nesses may adversely affect coating performance. MIXING Power mix contents of each container, making sure no pigment remains on the bottom. Pour a measured amount of Part B into a clean container large enough to hold both components. Add an equal volume of Part A to Part B while under agitation. Continue agitation until the two compo- nents are thoroughly mixed. Do not use mixed material beyond pot life limits. Note: Both com- ponents should be above 50OF (10°C) prior to mixing. For application to surfaces between 350F to 50°F WC to 10°C), allow mixed material to stand thirty (30) minutes and restir before using. For optimum application properties, the material temperature should be above 607 (16°C). POT LIFE 16 hours at 350F (2°C) 6 hours at 550F (13°C) 2 hours at 75°F (24°C) 3/ hour at 950F (35°C) THINNING Use No. 2 Thinner. For air spray, thin up to 20% or 11h pints (760 mL) per gallon; for airless spray, thin up to 5% or 1/ pint (190 mL) per gallon. A maximum of 20% of No. 65 Thinner may be used to comply with VOC regulations. SURFACE TEMPERATURE Minimum 35°F (2°C) Maximum 120OF (49°C) The surface should be dry and at least 50F (3°C) above the dew point. Coating won't cure below minimum surface temperature. APPLICATION EQUIPMENT Air Spray Gun Fluid Air Cap Air Hose Mat'l Hose Atomizing Pot Tip ID ID Pressure Pressure DeVilbiss E 704 5/16" or 3/8" 1/2" 75-100 psi 20-40 psi JGA .070" or 765 (7.9 or 9.5 mm) (12.7 mm) (5.2-6.9 bar) (1.4-2.8 bar) Low temperatures or longer hoses require higher pot pressure. Airless Spray Tip Orifice Atomizing Pressure MaVl Hose ID Manifold Filter 0.017-0.021" 3400-4000 psi (430-530 microns) 3/8" or 1/2" 1 (9.5 or 12.7 mm) 60 mesh (25( microns) Use appropriate tip/atomizing pressure for equipment, applicator technique and weather conditions. Note: Application over inorganic zinc -rich primers: Apply a wet mist coat and allow tiny bubbles to form. When bubbles disappear in 1 to 2 minutes, apply a full wet coat at specified mil thickness. Brush: Brushing is recommended on small areas only. Ladle material on and then use flat side of brush to spread. Do not brush out to thin film as with conventional coatings. CLEANUP Flush and clean all equipment immediately after use with the recommended thinner or xylol. WARRANTY R LIMITATION OF SELLER'S LIABILITY: Tnemec Company, Inc. warrants only that its coatings represented herein meet the formulation standards of Tnemec Company, Inc. THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU OF ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The buyer's sole and exclusive remedy against Tnemec Company, Inc. shall be for replacement of the product in the event a defective condition of the product should be found to exist and the exclusive remedy shall not have failed its essential purpose as long as Tnemec is willing to provide comparable replacement product to the buyer. NO OTHER REMEDY (INCLUDING, BUT NOT LIMITED TO, INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR LOST PROFITS, LOST SALES, INJURY TO PERSON OR PROPERTY, ENVIRONMENTAL INJURIES OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE TO THE BUYER. Technical and application information herein is provided for the purpose of establishing a general profile of the coating and proper coating application procedures. Test performance results were obtained in a controlled environment and Tnemec Company makes no claim that these tests or any other tests, accurately represent all environments. As application, environmental and design factors can vary significantly, due core should be exercised in the selection and use of the coating. FOR INDUSTRIAL USE ONLY. TNEMEC COMPANY INCORPORATED PRINTED IN USA 6800 CORPORATE DRIVE, NANSAS CITY, MISSOURI 64120.1372 TEL: 1 800 TNEMEC 1 www.taemec.com (YDAT045) 46H-413 Tnemec Company, Inc. For coatings, resins and related materials, approved by Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to 123 West 23rd Avenue, Kansas City, MO 64116-3064 form OSHA-20, meets requirements of CFR 29 Part Emergency Telephone: 800-535-5053 (INFOTRAC) 1910.1200, OSHA'S hazard communication standard. Telephone: 816-474-3400 NPCA 1-84 PREPARED DATE: 07/17/2003 Series: F046HO413A Product Class: COAL TAR-POLYAMIDE SERIES 46H H.B. TNEME-TAR Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS REFINED COAL TAR PITCH (CONTAINS PPAH'S) POLYAMIDE RESIN MODIFIED ALIPHATIC AMINE TALC (RESPIRABLE DUST) XYLENE** ETHYL BENZENE** VAPOR PRESS. MMHG CAS# % By Wt. @ 68 o F 65996-93-2 14807-96-6 1330-20-7 100-41-4 26.52 11-20 1-5 31-40 12.00 5.100 2.72 6.000 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV-STEL TLV -C 0000.200 MG/M3 0002.000 MG/M3 0100.000 0150.000 PPM PPM 0100.000 0125.000 PPM PPM OSHA PEL-TWA PEL-STEL PEL -C 0000.200 MG/M3 0100.000 PPM 0100.000 PPM ** SARA Reportable Product This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. Where exposure may occur, engineering and administrative controls must be instituted to maintain an exposure level below 0.2 mg/m3 for benzene soluble coal tar pitch volatiles and PPAH's (particulate polycyclic aromatic hydrocarbons). If these controls are not adequate, the use of an appropriate NIOSH/MSHA approved respirator is required. Avoid all skin and eye contact. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. May result in permanent visual loss. Corrosive responses, burns. SKIN: Allergic skin responses. Discoloration. Can be a skin sensitizer. Corrosive skin responses. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Coal tar pitch contains benzene soluble coal tar pitch volatiles. Repeated or prolonged exposure to these volatiles by heating, spraying, or skin contact presents an increased risk of developing lund, skin, and other cancers. Where repeated or prolonged exposure to benzene soluble coal tar pitch volatiles or PPAH's (particulate polycyclic aromatic hydrocarbons) may occur, there is an increased risk of developing lung, skin or other cancers. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 213). TARGET ORGANS: Can cause lung damage. Can cause eye damage. Can cause skin damage. Can cause respiratory tract damage. Can cause gastrointestinal tract damage. Can cause liver damage. Can cause kidney damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause nervous system effects. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: This product contains a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. PREPARED DATE: 07/17/2003 Series: F046HO413A Product Class: COAL TAR-POLYAMIDE SERIES 46H H.B. TNEME-TAR Page 2 of 2 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 81.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP. Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous. ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use protective cream where skin contact is likely. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION %VOLATILE BY VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT 6.00 -N/A 275.0 °F 288.0 °F 11.2534 LB/GL 1.688 9.400 (Ether = 1) 15.001 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Nitrogen monoxide, nitrogen dioxide CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 3 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as M./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 PREPARED DATE: 07/17/2003 Series: F046HO413B SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS TALC (RESPIRABLE DUST) XYLENE** ETHYL BENZENE** BISPHENOL A TYPE EPDXY RESIN ** SARA Reportable Product For coatings, resins and related materials, approved by Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 Product Class: EPDXY SERIES 46H H.B. TNEME-TAR CONV Page 1 of 2 CAS# 14807-96-6 1330-20-7 100-41-4 VAPOR PRESS. MMHG By Wt. @ 68 ' F 41-50 13.20 5.100 3.30 6.000 31-40 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C 0002.000 MG/M3 0100.000 0150.000 PPM PPM 0100.000 0125.000 PPM PPM OSHA PEL -TWA PEL - STEL PEL - C 0100.000 PPM 0100.000 PPM This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. SKIN: Moderate irritation, drying of skin, defatting and possible dermatitis. Allergic skin responses. Can be a skin sensitizer. INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged contact or repeated overexposure to some epoxy compounds may result in permanent skin sensitization in susceptible individuals. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous. system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. TARGET ORGANS: Can cause eye irritation. Can cause respiratory tract irritation. Can cause lung damage. Can cause skin sensitization. Can cause skin irritation. Can cause gastrointestinal tract irritation. Can cause liver damage. Can cause nervous system effects. Can cause kidney damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 81.0 °F 1.0 -N/A -N/A -N/A PREPARED DATE: 07/17/2003 Series: F046HO413B Product Class: EPDXY SERIES 46H H.B. TNEME-TAR CONV Page 2 of 2 EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous. ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29. 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION %VOLATILE BY VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT 6.00 -N/A 275.0 °F 288.0 °F 12.1662 LB/GL 2.007 9.400 (Ether = 1) 16.505 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments CONDITIONS TO AVOID: Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as VA/Gal., VOC content and chemical constituents will vary with color. Safely and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. H PRODUCT PROFILE GENERIC DESCRIPTION Aromatic Urethane, Zinc -Rich COMMON USAGE A two -component, moisture -cured, zinc -rich primer for the interior and exterior of steel potable water tanks. Provides outstanding long-term corrosion resistance when used as a primer in conjunction with other Tnemec potable water tank coatings. It cures quickly and can be topcoated the same day at surface temperatures down to 35°F. Series 91-H2O has no maximum recoat time, making it ideally suited as a primer for both sides of plate steel surfaces in water tank fabrication shops. Application methods include "dry -fall" under certain conditions (see Application). Note: When used in conjunction with cathodic protection, anodes or impressed current systems should not provide current demand more negative than —1.05 volts relative to a copper —copper sulfate reference electrode half -cell. ZINC DUST CONTENT 83% by weight in dried film COLOR Greenish -gray SPECIAL QUALIFICATIONS Certified (with or without 44-710 Urethane Accelerator) in accordance with ANSI/NSF Std. 61 for use on interior potable water tanks of 8,000 gallons or greater. Topcoating with Std. 61 certified Tnemec coatings is recommended. Contact your Tnemec representative for specific recommenda- tions. Meets zinc -rich primer requirements of AWWA D102-03 Standard for Inside System No. 5 and Outside System No. 4 & 6. Series 91-H2O uses a zinc dust which meets the requirements of ASTM D 520 Type HI and contains less than .002% lead. PERFORMANCE CRITERIA Extensive test data available. Contact your Tnemec representative for specific test results. • TOPCOATS Please refer to Tnemec's Systems Guide for Water Storage Tanks for specific systems and additional information. Interior: Series 20, FC20, N140 Exterior. Series 27, 66, N69, 73, 161, 175, 1074, 1075. Note: Certain topcoat colors may not provide one -coat hiding depending on method of application. Contact your Tnemec representative. TECHNICAL DATA VOLUME SOLIDS RECOMMENDED OFT CURING TIME Without 44.710 With 44-710 VOLATILE ORGANIC COMPOUNDS THEORETICAL COVERAGE NUMBER OF COMPONENTS PACKAGING NET WEIGHT PER GALLON STORAGE TEMPERATURE TEMPERATURE RESISTANCE SHELF LIFE FLASH POINT - SETA HEALTH & SAFETY Wet Interior: SSPC-SP10/NACE 2 Near -White Blast Cleaning Exterior or Dry Interior. SSPC-SP6/NACE 3 Commercial Blast Cleaning. 63.0 t 2.0% (mixed) 2.5 to 3.5 mils (65 to 90 microns) Temnerature To Handle To Recoat 750F (24°C) 1 hour 4 hours 650F (18°C) 11h hours 5 hours 550F (11°C) 2 hours 6 hours 450F (7°C) 21h hours 7 hours 35°F (2°C) 1 3 hours 8 hours Curing time will vary with surface temperature, humidity and film thickness. Ventilation: When used as a tank lining or in enclosed areas, provide adequate ventilation during application and cure. Reference ventilation guidelines contained in the latest edition of AWWA D 102. Reference the 44-710 Urethane Accelerator product data sheet. Note: For cure times to immersion service, reference the specified Tnemec interior topcoat product data sheet. Unthinned Thinned 2.5% Thinned 10% 2.651bs/gallon 2.761bs/gallon 3.071bs/gallon (318 grams/litre) (331 grams/litre) (368 grams/litre) 1,011 mil sq ft/gal (24.8 m2/L at 25 microns). See APPLICATION for coverage rates. Two: Part A and Part B Four -Gallon and One -Gallon Kits: Consist of one premeasured container of liquid (Part A) and one pre - measured container of powder (Part B). When mixed, yields four gallons (15.1L) or one gallon (3.79L). 23.94 t 0.60 lbs (10.86 t .27 kg) Minimum 20°F (-7°C) Maximum 110°F (43°C) Dry (Continuous) 250°F (121°C) Intermittent 300OF (149°C) 9 months at recommended storage temperature. Part A: 78OF (26°C) Part B: NA Paint products contain chemical ingredients which are considered hazardous. Read container label warning and Material Safety Data Sheet for important health and safety information prior to the use of this product. Keep out of the reach of children. Published technical data and instructions are subject to change without notice. The online catalog at www.inemec.com should be referenced for the most current technical data and instructions or you may contact your Tnemec representative for current technical data and instructions. 0 May 26, 2005, by Tnemec Company, Inc. 91-Hy0 APPLICATION CAUTION! COVERAGE RATES MIXING POT LIFE THINNING SURFACE TEMPERATURE APPLICATION EQUIPMENT Dry overspray can be wiped or washed from most surfaces. Satisfactory dry -fall performance depends upon height of work, weather conditions and equipment adjustment. Low temperature is of particular concern. Test for each application as follows: Spray from 15 to 25 feet towards paint container. The material then should readily wipe off. Note: Heat can fuse -dry overspray to surfaces. Always clean dry overspray from hot surfaces before fusing occurs. Be aware that exterior surface temperatures can be higher than air temperature. Dry Mils (Microns) Wet Mils (Microns) Sq Ft/Gal (m2/Gal) Suggested 3.0(75) 5.0(125) 337 (31.3) Minimum 2.5(65) 4.0(100) 404 (37.5) Maximum 3.5(90) 5.5(140) 289 (26.9) Allow for overspray and surface irregularities. Film thickness is rounded to the nearest 0.5 mu or 5 microns. Application of coating below minimum or above maximum recommended dry film thicknesses may adversely affect coating performance. Note: It is important to always use the entire contents of A and B components. Use a mechanical mixer and keep material under constant agitation while mixing. Slowly sift the entire contents of Part B zinc powder into liquid (Part A). -Do Not Reverse This Procedure- Adjust mixer speed to break up lumps and mix until the two components are thoroughly blended. Strain through a 35 to 50 mesh (300 to 600 microns) screen before using. For spray application, keep under low RPM agitation to prevent settling. For brush or roller ap- plication, stir frequently to prevent settling. Do not use mixed material beyond pot life limits. 8 hours at 77*F (25°C) and 50% R.H. Caution: This product cures with moisture acting as a catalyst. Incorporation of moisture or moisture laden air (humidity) during use will shorten pot life. Avoid continual agitation at high RPM. When fea- sible keep containers of mixed material covered during use. For spray, thin up to 10% or 3/ pint (380 mL) per gallon with No. 2 Thinner if temperatures are below 80°F (27C). Thin up to 10% or 3/ pint (380 mL) per gallon with No. 3 'Thinner if temperatures are above 80°F (270C). For brush or roller, thin up to 10% or 3/ pint (380 mL) with No. 3 Thinner. Do not thin more than 2.5% when air pollution regulations limit the atmospheric discharge of volatile organic compounds (VOC) in coatings to a maximum of 340 grams/litre (2.80 lbs/gal). Caution: Series 91-H20 certification is based on thinning with No. 2 or No. 3 Thinner. Use of any other thinner voids ANSI/NSF Std. 61 certification. Minimum 35°F (2°C) Maximum 120OF (49°C) Maximum for Brush & Roller 100OF (38*0 The surface should be dry and at least 5°F (3°C) above the dew point. Note: When intermediate and finish coats are white or light colors, best hiding of this dark color primer can be achieved by spray application; or when roller applied, by using V4" nap covers. Air Svrav Gun Fluid Air Cap Air Hose Matl Hose Atomizing Pot Tip ID ID Pressure Pressure DeVilbiss * 1 78 5/16" or 3/8" 3/8" or 1/2" 40-50 psi 10-20 psi MBC or JGA (7.9 or 9.5 mm) (9.5 or 12.7 mm) (2.8-3.4 bar) (0.7-1.4 bar) * (with heavy mastic spring) Low temperatures or longer hoses will require additional pressure. Use pressure pot equipped with an agitator and keep pressure pot at same level or higher than the spray gun. Compressed air must be dry. Airless Spray Tip orifice Atomizing Pressure Mat l Hose ID Manifold Filter 0.017-0.021" 2400-3000 psi 1/4" or 3/8" 60 mesh (430-535 microns) (165-207 bar) (6.4 or 9.5 ram) (250 microns) Reversible Tip Use appropriate tip/atomizing pressure for equipment, applicator technique and weather conditions. Roller. Use a 1/4" or 3/8" (6.4 mm or 9.5 mm) synthetic nap cover. Stir material frequently or keep under agitation to prevent settling. Brush: Use high quality natural or synthetic bristle brushes. Stir material frequently or keep under agita- tion to prevent settling. CLEANUP Flush and clean all equipment immediately after use with the recommended thinner or xylene. WARRANTY & LIMITATION OF SELLER'S LIABILITY: Tnemec Company, Inc. warrants only that its coatings represented herein meet the formulation standards of Tnemec Company, Inc. THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU OF ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The buyers sale and exclusive remedy against Tnemec Company, Inc. shall be for replacement of the product in the event a defective condition of the product should be found to exist and the exclusive remedy shall not hove foiled its essential purpose as long as Tnemec is willing to provide comparable replacement product to the buyer. NO OTHER REMEDY (INCLUDING, BUT NOT LIMITED TO, INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR LOST PROFITS, LOST SALES, INJURY TO PERSON OR PROPERTY, ENVIRONMENTAL INJURIES OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE TO THE BUYER. Technical and application information herein is provided for the purpose of establishing a general profile of the coating and proper coating application procedures. Test performance results were obtained in a controlled environment and Tnemec Company makes no claim that these tests or any other tests, accurately represent all environments. As application, environmental and design factors can vary significantly, due care should be exercised in the selection and use of the coating. FOR INDUSTRIAL USE ONLY. TNEMEC COMPANY INCORPORATED PRINTED IN USA 6800 CORPORATE DRIVE, XANSAS CITY, MISSOURI 64120-1372 TEL: 1 800 TNEMEC 1 www.tnemec.com (YDAT098) 9"2O Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 Material Safety Data Sheet (MSDS) For coatings, resins and related materials, approved by the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 PREPARED DATE: 07/23/2003 Series: F091-OH2OA Product Class: POLYMERIC DIISOCYANATE HYDRO -ZINC GREENISH GRAY Page 1 of 3 SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS IRON OXIDE FUME CRYSTALLINE SILICA (QUARTZ) MICA (RESPIRABLE DUST) AMORPHOUS SILICA DIPHENYLMETHANE DIISOCYANATE (MDI) MONOMER** DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER ETHYL BENZENE** XYLENE** ** SARA Reportable Product CAS# 1309-37-1 14808-60-7 12001-26-2 7631-86-9 101-68-8 100-41-4 1330-20-7 VAPOR PRESS. MMHG % By Wt. @ 68 ' F 6-10 3.11 1-5 1-5 8.71 31-40 8.22 6.000 32.91 5.100 OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV-STEL TLV -C 0005.000 MG/M3 0000.100 MG/M3 0003.000 MG/M3 0010.000 MG/M3 0000.005 PPM 0100.000 0125.000 PPM PPM 0100.000 0150.000 PPM PPM PEL -TWA 0010.000 MG/M3 0000.050 MG/M3 0003.000 MG/M3 0006.000 MG/M3 0100.000 PPM 0100.000 PPM OSHA PEL-STEL PEL-C This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, [ARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. Contains isocyanate monomer. If subject to spray application, engineering and administrative controls must be instituted to maintain an exposure level below .005ppm. If these controls are not adequate, the use of an air -supplied respirator is mandatory. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. SKIN: Moderate irritation, drying of skin, defatting and possible dermatitis. Allergic skin responses. Discoloration. INHALATION - OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged contactor repeated exposure to isocyanate concentrations greater than the recommended TLV may result in permanent respiratory and skin sensitization. Once diagnosed as being sensitized to isocyanates, no further exposure can be permitted. Prolonged inhalation of dusts containing crystalline silica may result in the development of a lung disease known as silicosis. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). This product contains crystalline silica, which is considered a cancer hazard by inhalation of respirable dust. The Internation Agency for Research on Cancer (]ARC) concluded that respirable crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1 B). TARGET ORGANS: Can cause eye damage. Can cause skin irritation. Can be corrosive to respiratory tract. Can cause lung damage. Can be corrosive to gastrointestinal tract. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause liver damage. Can cause nervous system effects. Can cause kidney damage. Can cause respiratory tract sensitization. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. 0000.020 PPM SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure to isocyanate products may aggravate persons with asthmatic type conditions, chronic bronchitis, other chronic respiratory diseases, skin eczema, or skin sensitization. SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 78.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Small traces of HCN may be evolved under fire conditions. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. Remove containers to a safe place and cover loosely until carbon dioxide has finished evolving. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take intemally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. Where the isocyanate concentration exceeds the TLV or is unknown, or where there is spray application, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use protective cream where skin contact is likely. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION %VOLATILE BY VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE WEIGHT 6.00 -N/A 275.0 °F 288.0 °F 9.1213 LB/GL 3.754 9.400 (Ether= 1) 41.167 SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Nitrogen monoxide, nitrogen dioxide Trace amounts of HCN. CONDITIONS TO AVOID: Heat, sparks, open flames. Amine compounds under uncontrolled conditions. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. OTHER: PREPARED DATE: 07/23/2003 Series: F091-OH2OA Product Class: POLYMERIC DIISOCYANATE HYDRO -ZINC GREENISH GRAY Page 3of3 SECTION 16 - HMIS INFORMATION Health: 3 Flammability: 3 Reactivity: 2 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as VNR./Gal., VOC content and chemical constituents will vary with color. Safely and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safely and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. 123 West 23rd Avenue, Kansas City, MO 64116-3064 Emergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816474-3400 PREPARED DATE: 07/23/2003 Series: F091-OH2OB SECTION 2 - HAZARDOUS INGREDIENTS INGREDIENTS ZINC OXIDE (TOTAL DUST)" ZINC (TOTAL DUST)" Material Safety Data Sheet (MSDS) Product Class: ZINC DUST HYDRO -ZINC ZINC DUST VAPOR PRESS. MMHG CAS# % By Wt. @ 68 ' F 1314-13-2 3.00 7440-66-6 97.00 ACGIH rui cvawiyb, icauia nnu ie'aicu inn�ena�a, nNNiuvcu the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHNS hazard communication standard. NPCA 1-84 OCCUPATIONAL EXPOSURE LIMITS TLV - TWA TLV -STEL TLV -C 0010.000 MG/M3 0010.000 MG/M3 Page 1 of 2 OSHA PEL -TWA PEL - STEL PEL - C 0010.000 MG/M3 0015.000 MG/M3 ** SARA Reportable Product This product contains no reported carcinogens or suspected carcinogens. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Redness, tearing, blurred vision. SKIN: INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. Inhalation of metallic zinc dust may result in symptoms known as metal fume fever. Symptoms include chills, fever, muscular pain, nausea and vomiting. INGESTION: Gastrointestinal irritation. CHRONIC EFFECTS: TARGET ORGANS: Can cause eye irritation. Can cause skin irritation. Can cause respiratory tract irritation. Can cause gastrointestinal tract irritation. Can cause nervous system effects. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: NOTE TO PHYSICIAN: SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 998.0 °F -N/A -N/A -N/A -N/A EXTINGUISHING MEDIA: Do not use water; use dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Dry dust forms explosive mixtures in air. Zinc dust in contact with water forms hydrogen gas which in a confined space with air or oxygen may form an explosive concentration. Do not spread material. Once ignited, zinc dust may burn readily in air. Use appropriate extinguishing media to control fire. DO NOT USE WATER. Wear self-contained breathing apparatus with a full facepiece operated in pressure -demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Avoid breathing dust. Use a dust mask or respirator. Avoid contact with water. Prohibit smoking. Eliminate all ignition sources and avoid dusting. Shovel into a container for disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: PREPARED DATE: 07/23/2003 Series: F091-OH2OB Product Class: ZINC DUST HYDRO -ZINC ZINC DUST Page 2 of 2 SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Usually not necessary. Dust tight goggles in dusty environments. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous ingredients identified in Section 11 of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. A dust mask or a particulate respirator approved by NIOSH/MSHA is recommended. OTHER PROTECTION: Use chemical resistant coveralls or apron to protect against skin and clothing contamination. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE -N/A -N/A -N/A °F -N/A °F 58.7993 LB/GL .000 .000 (Ether = 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Acids. DECOMPOSITION: Zinc oxide fume CONDITIONS TO AVOID: Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 1 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as N./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. %VOLATILE BY WEIGHT .000 PRODUCT PROFILE GENERIC DESCRIPTION Polyamide Epoxy COMMON USAGE Low temperature -cure, corrosion -resistant coating for protection against abrasion, immersion and mild chemical contact. Fast recoat at 75°F (24°C). COLORS Refer to Tnemec Color Guide. Note: Epoxies chalk with extended exposure to sunlight. Lack of ventilation, incomplete mixing, miscatalyzation or the use of heaters that emit carbon diox- ide and carbon monoxide during application and initial stages of curing may cause yellowing to occur. FINISH Satin PERFORMANCE CRITERIA Extensive test data available. Contact your Tnemec representative for specific test results. COATING SYSTEM PRIMERS Steel: Self -priming or Series 20, FC20, 37H, 66, N69, N69F, 90, 160, 530 Galvanized Steel and Non -Ferrous Metal: Self -priming or Series 66, N69 Concrete: Self -priming or 54-660, 130, 201, 214 CMU: 54-562, 54-660, 130, 216, 218 Drywall: 51-792 for dry interior environments TOPCOATS 46H-413, 66, N69, 73, 84, 104, 113, 114, 161, 175, 262, 265, 290, 291, 1074, 1075. Refer to COL- ORS on applicable topcoat data sheets for additional information. PREPARATIONSURFACE STEEL Immersion Service: SSPC-SP10 Near -White Blast Cleaning Non -Immersion Service: SSPC-SP6 Commercial Blast Cleaning PRIMED SURFACES Immersion Service: Scarify the Series 161 prime coat surface by abrasive -blasting with a fine abrasive before topcoating if: (a) the Series 161 has been exterior exposed for 60 days or longer and 46H-413, 66, N69 or 161 is the specified topcoat; (b) the Series 161 prime coat has been exterior exposed for 14 days or longer and Series 104 is the specified topcoat; (c) the Series 161 prime coat has been exterior exposed for 7 days or longer and Series 262 or 265 is the specified topcoat. GALVANIZED STEEL 8 Surface preparation recommendations will vary depending on substrate and exposure NONFERROUS METAL conditions. Contact your Tnemec representative or Tnemec Technical Services. CAST/DUCTIIE IRON Contact your Tnemec representative or Tnemec Technical Services. CONCRETE Allow new concrete to cure 28 days. For optimum results and/or immersion service, abrasive blast referencing SSPC-SP13/NACE 6 Surface Preparation of Concrete and Tnemec's Surface Preparation and Application Guide. CMU Allow mortar to cure for 28 days. Level protrusions and mortar spatter. PAINTED SURFACES Non -Immersion Service: Ask your Tnemec representative for specific recommendations. ALL SURFACES Must be clean, dry and free of oil, grease and other contaminants. TECHNICAL DATA VOLUME SOLIDS" 58.0 ± 2.0% (mixed) RECOMMENDED DFT CURING TIME VOLATILE ORGANIC COMPOUNDS* THEORETICAL COVERAGE* 2.0 to 6.0 mils (50 to 150 microns) per coat. Note: Number of coats and thickness requirements will vary with substrate, application method and exposure. Contact your Tnemec representative. Te_mnerature To Touch To Handle To Recoat Immersion 750F (24°C) 1 hour 2-3 hours 3-4 hours 3 days 65°F (18°C) 2 hours 4-5 hours 5-6 hours 4-5 days 550F (13°C) 34 hours 6-8 hours 10-12 hours 6-7 days 450F (7 0 6-7 hours 12-14 hours 16-18 hours 9-10 days 350F (2°C) 8-10 hours 16-18 hours 20-22 hours 12-14 days Curing time varies with surface temperature, air movement, humidity and film thickness. Unthinned Thinned 5% Thinned 10% 2.921bs/gallon 3.11lbs/gallon 3.281bs/gallon (349 grams/litre) (372 grams/litre) (393 grams/litre) 930 mil sq ft/gai (22.8 m'/L at 25 microns). See APPLICATION for coverage rates. NUMBER OF COMPONENTS Two: Part A and Part B PACKAGING 5 gallon (18.9L) pails and 1 gallon (3.79L) cans -Order in multiples of 2. Published technical data and instructions are subject to change without notice. The online catalog at www.tneme(.com should be referenced for the most current technical data and instructions or you may contact your Tnemec representative for current technical data and instructions. 0 June 2004, by Tnemec Company, Inc. 161 TECHNICAL DATA continued NET WEIGHT PER GALLON* 12.50 ± 0.25 lbs (5.67 ± .11 kg) STORAGE TEMPERATURE Minimum 20°F (-7*C) Maximum 1107 (43°C) TEMPERATURE RESISTANCE (Dry) Continuous 250°F (121°C) Intermittent 275°F (135°C) SHELF LIFE Part A: 24 months; Part B: 12 months at recommended storage temperature. FLASH POINT - SETA Part A: 82°F (28°C) Part B: 640F (18°C) HEALTH & SAFETY Paint products contain chemical ingredients which are considered hazardous. Read container label warning and. Material Safety Data Sheet for important health and safety information prior to the use of this product. Keep out of the reach of children. COVERAGE RATES* MIXING POT LIFE THINNING SURFACE TEMPERATURE APPLICATION EQUIPMENT CLEANUP Dry Mils (Microns) Wet Mils (Microns) Sq Ft/Gal (mZ/Gal) Suggested (1) 4.0000) 7.0(180) 232 (21.6) Minimum 2.0 (50) 3.5 (90) 465 (43.2) Maximum 6.0050) 10.5 (265) 155 (14.4) (1) Note: Roller or brush application may require two or more coats to obtain suggested film thickness. Allow for overspray and surface irregularities. Film thickness is rounded to the nearest 0.5 mil or 5 microns. Application of coating below minimum or above maximum recommended dry film thicknesses may adversely affect coating performance. Power mix contents of each container, making sure no pigment remains on the bottom. Pour a measured amount of Part B into a clean container large enough to hold both components. Add an equal volume of Part A to Part B while under agitation. Continue agitation until the two compo- nents are thoroughly mixed. Do not use mixed material beyond pot life limits. Note: Both com- ponents should be above 50*F (10°C) prior to mixing. For application to surfaces between 350F to 50°F (2°C to 100C), allow mixed material to stand thirty (30) minutes and restir before using. For optimum application properties, blended components should be above 60OF (16°C). Note: Mixing ratio is one to one by volume. 16 hours at 35°F (2°C) 2 hours at 750F (24°C) ak hour at 100°F (38°C) Use No. 4 Thinner. For air spray, thin up to 10% or 3/ pint (380 ml.) per gallon. For airless spray, roller or brush, thin up to 5% or 1/4 pint (190 mL) per gallon. Minimum 35°F (2*C) Maximum 135°F (57°C) The surface should be dry and at least 50F (3°C) above the dew point. Coating will not cure be- low minimum surface temperature. Air Storav Gun Fluid Air Cap Air Hose Mat'l Hose Atomizing Pot Tip ID ID Pressure Pressure DeVilbiss E 765 5/16" or 3/8" 3/8" or 1/2" 75-100 psi 10-20 psi MBC or JGA or 78 (7.9 or 9.5 mm) (9.5 or 12.7 rum) (5.2-6.9 bar) (0.7-1.4 bar) Low temperatures or longer hoses require higher pot pressure. Airless Sorav Tip Orifice Atomizing Pressure Mat'] Hose 1 D Manifold Filter 0.015"-0.019" 1800-3000 psi (380-485 microns) 1 (124-207 bar) 1/4" or 3/8" (6.4 or 9.5 mm) 60 mesh (250 microns) Use appropriate tip/atomizing pressure for equipment, applicator technique and weather conditions. Note: Application over inorganic zinc -rich primers: Apply a wet mist coat and allow tiny bubbles to form. When bubbles disappear in 1 to 2 minutes, apply a full wet coat at specified mil thickness. Roller: Roller application optional when environmental restrictions do not allow spraying. Use 3/8" or 1/2" (9.5 mm to 12.7 mm) synthetic nap covers. Brush: Recommended for small areas only. Use high quality natural or synthetic bristle brushes. Flush and clean all equipment immediately after use with the recommended thinner or MEK. *Values may vary with color. WARRANTY R LIMITATION OF SELLER'S LIABILITY: Tnemec Company, Inc. warrants only that Its coatings represented herein meet the formulation standards of Tnemec Company, Inc. THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU OF ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The buyer's sole and exclusive remedy against Tnemec Company, Inc. shall be for replacement of the product in the event a defective condition of the product should be found to exist and the exclusive remedy shall not have failed its essential purpose as long as Tnemec is willing to provide comparable replacement product to the buyer. NO OTHER REMEDY (INCLUDING, BUT NOT LIMITED TO, INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR LOST PROFITS, LOST SALES, INJURY 10 PERSON OR PROPERTY, ENVIRONMENTAL INJURIES OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE TO THE BUYER. Technical and application information herein is provided for the purpose of establishing a general profile of the coating and proper coating application procedures. Test performance results were obtained in a controlled environment and Tnemec Company makes no claim that these tests or any other tests, accurately represent all environments. As application, environmental and design factors can vary significantly, due care should be exercised in the selection and use of the coating. FOR INDUSTRIAL USE ONLY. TNEMEC COMPANY INCORPORATED PRINTED IN USA 6800 CORPORATE DRIVE, KANSAS CITY, MISSOURI 64120-1372 TEL: 1 800 TNEMEC 1 www.tnemec.com (YDAT161) 161 � Tnemec Company, Inc. 123 West 23rd Avenue, Kansas City, MO 64116-3064 WWEmergency Telephone: 800-535-5053 (INFOTRAC) Telephone: 816-474-3400 PREPARED DATE: 11/27/2006 Series: F161-11WHA SECTION 2 - HAZARDOUS INGREDIENTS Material Safety Data Sheet (MSDS) Product Class: POLYAMIDE VAPOR PRESS. MMHG INGREDIENTS CAS# % By Wt. @ 68 °F TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 11-20 TALC (RESPIRABLE DUST) 14807-96-6 11-20 AMORPHOUS SILICA 7631-86-9 1-5 BARIUM SULFATE (TOTAL DUST) 7727-43-7 26.14 ALUMINUM OXIDES 1344-28-1 1-5 MODIFIED ALIPHATIC AMINE 1-5 POLYAMIDE RESIN 11-20 N-BUTANOL (SKIN)** 71-36-3 8.60 4.400 XYLENE** 1330-20-7 10,07 5.100 ** SARA Reportable Product TNEME-FASCURE WHITE For coatings, resins and related materials, approved by the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part 1910.1200, OSHA'S hazard communication standard. NPCA 1-84 Page 1 of 2 OCCUPATIONAL EXPOSURE LIMITS ACGIH OSHA TLV - TWA TLV - STEL TLV - C PEL -TWA PEL - STEL PEL - C 0010.000 0010.000 MG/M3 MG/M3 0002.000 MG/M3 0010.000 0006.000 MG/M3 MG/M3 0010.000 0010.000 MG/M3 MG/M3 0010.000 MG/M3 0020.000 0050.000 0100.000 0050.000 PPM PPM PPM PPM 0100.000 0150.000 0100.000 PPM PPM PPM This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. May result in permanent visual loss. Corrosive responses, burns. May result in permanent injury. SKIN: Corrosive skin responses. Allergic skin responses. Can be a skin sensitizer. INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Severe nasal and respiratory tract irritation. Burns. INHALATION -OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. Corrosive responses and possible burns to the gastrointestinal tract. CHRONIC EFFECTS: NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). TARGET ORGANS: Can be corrosive to skin. Can cause lung damage. Can be corrosive to respiratory tract. Can cause eye damage. Can cause liver damage. Can cause gastrointestinal tract damage. Can cause kidney damage. Can cause nervous system effects. Can cause cancer. Risk of cancer depends on duration and level of exposure. Can cause skin sensitization. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. PREPARED DATE: 11/27/2006 Series: F161-11WHA Product Class: POLYAMIDE TNEME-FASCURE WHITE Page 2 of 2 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 82.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous. ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations, consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 6.00 -N/A 241.0 °F 288.0 °F 13.9859 LB/GL 2.938 19.600 (Ether = 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Bases. Acids. Water, alcohols, amines, strong bases, metal components, surface active materials. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Nitrogen monoxide, nitrogen dioxide Aldehydes. CONDITIONS TO AVOID: Epoxy compounds under uncontrolled conditions. Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 3 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health information pertinent to the complete product series. Physical constants such as M./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safely and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. %VOLATILE BY WEIGHT 41.847 Tnemec Company, Inc. t-or coatings, resins ana reiatea matenais, approvea oy 123 West 23rd Avenue, Kansas City, MO 64116-3064 Material Safety Data Sheet (MSDS) the U.S. Department of Labor as essentially similar to form OSHA-20, meets requirements of CFR 29 Part Emergency Telephone: 800-535-5053 (INFOTRAC) 1910.1200, OSHA'S hazard communication standard. Telephone: 816-474-3400 NPCA 1-84 PREPARED DATE: 11/27/2006 Series: B066-0066B Product Class: EPDXY F65/66/160/161 CONVERTER Page 1 of 2 SECTION 2 - HAZARDOUS INGREDIENTS VAPOR PRESS. MMHG INGREDIENTS CAS# % By Wt. @ 68 ° F OCCUPATIONAL EXPOSURE LIMITS ACGIH TLV - TWA TLV - STEL TLV - C TALC (RESPIRABLE DUST) 14807-96-6 31-40 0002.000 MG/M3 BISPHENOL A TYPE EPDXY RESIN 11-20 BISPHENOL A TYPE EPDXY RESIN 21-30 ETHYL BENZENE** 100-41-4 .40 6.000 0100.000 0125.000 PPM PPM XYLENE** 1330-20-7 10.69 5.100 0100.000 0150.000 PPM PPM METHYL ISOBUTYL KETONE** 108-10-1 15.33 16.000 0050.000 0075.000 PPM PPM ** SARA Reportable Product OSHA PEL-TWA PEL-STEL PEL-C 0100.000 PPM 0100.000 PPM 0100.000 PPM This product contains one or more reported carcinogens or suspected carcinogens which are noted NTP, IARC, or OSHA-Z in the other limits recommended column. This substance contains a material classified as a hazardous air pollutant. This product contains pigment dusts which may be released when subjected to abrasive blasting, sanding, or grinding. The information contained in this section is considered confidential and proprietary and should be used only for safety and health purposes. SECTION 3 - HEALTH HAZARD INFORMATION EMERGENCY OVERVIEW: POTENTIAL HEALTH EFFECTS: EYE: Severe irritation. Redness, tearing, blurred vision. SKIN: Moderate irritation, drying of skin, defatting and possible dermatitis. Allergic skin responses. Can be a skin sensitizer. INHALATION -OVEREXPOSURE TO SOLVENT VAPORS OR SPRAY MIST: Nasal and respiratory irritation, anesthetic effects, dizziness, possible unconsciousness and asphyxiation, stupor, weakness, fatigue, nausea, and headache. INHALATION - OVEREXPOSURE TO FREE PIGMENT DUST: Coughing, wheezing, shortness of breath, restricted nasal passages, lung injury. INGESTION: Gastrointestinal irritation, nausea, vomiting, diarrhea, death, aspiration into the lungs which can be fatal. CHRONIC EFFECTS: Prolonged contactor repeated overexposure to some epoxy compounds may result in permanent skin sensitization in susceptible individuals. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the vapors may be harmful or fatal. Based on an International Agency for Research on Cancer (IARC) conclusion that there is "sufficient evidence in experimental animals for the carcinogenicity of ethyl benzene and inadequate evidence of carcinogenicity in humans, IARC's overall evaluation is that ethyl benzene is possibly carcinogenic to humans" (Group 2B). Prolonged or repeated contact with skin may cause primary irritation, dermatitis, or allergic skin reactions. TARGET ORGANS: Can cause eye irritation. Can cause respiratory tract irritation. Can cause lung damage. Can cause skin sensitization. Can cause skin irritation. Can cause gastrointestinal tract irritation. Can cause liver damage. Can cause nervous system effects. Can cause kidney damage. Can cause cancer. Risk of cancer depends on duration and level of exposure. OTHER: This product when mixed with other components acquires the hazards of all components. PRIMARY ROUTES OF ENTRY: Dermal and Inhalation. PROPOSITION 65: Pigments and/or other raw materials present in this product contain trace amounts of a chemical or chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush immediately with large amounts of clean water under low pressure for at least 15 minutes. Consult a physician. SKIN CONTACT: Wash affected area with soap and water. Remove contaminated clothing. Dispose of or launder accordingly. Consult a physician if skin irritation persists. INHALATION: Remove affected individual to fresh air. Treat symptomatically. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Consult a physician. INGESTION: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult a physician or poison control center IMMEDIATELY. Treat symptomatically. NOTE TO PHYSICIAN: Exposure may aggravate persons with eczema, skin sensitization, or other chronic skin disorders and allergies. PREPARED DATE: 11/27/2006 Series: B066-0066B Product Class: EPDXY F65/66/160/161 CONVERTER Page 2 of 2 SECTION 5 - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASHPOINT EXPLOSION LEVEL LOW EXPLOSION LEVEL HIGH FLAMMABILITY LIMITS LOWER FLAMMABILITY LIMITS HIGHER 64.0 °F 1.0 -N/A -N/A -N/A EXTINGUISHING MEDIA: Foam, carbon dioxide, and dry chemical. FIRE -FIGHTING PROCEDURES AND EQUIPMENTS: Keep away from heat, open flames, sparks, and areas where static charge may be generated. Do not apply to hot surfaces due to possible fire and explosion risk. For closed containers, pressure build-up and possible explosion might occur due to extreme heat exposure. Solvent vapors are heavier than air and may travel considerable distance to a source of ignition and flash back. Water may be used to cool unruptured containers. Wear self -contain- ed breathing apparatus with a full facepiece operated in pressure- demand or other positive pressure mode to prevent inhalation of hazardous decomposition products. Use appropriate extinguishing media to control fire. Water may cause violent frothing if sprayed directly into containers of burning liquid. SECTION 6 - SPILL OR LEAK PROCEDURES CLEAN-UP: Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non -sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. SECTION 7 - SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in dry area. Keep closures tight and upright to prevent leakage. Do not store in high temperature areas or near fire or open flame. Refer to product data sheet for recommended storage temperatures. SPECIAL COMMENTS: Prevent prolonged breathing of airborne contaminants such as vapor, spray mists, or dusts. Prevent contact with skin and eyes. Do not take internally. Keep out of reach of children. Do not reuse or alter containers without proper industrial cleaning. Do not weld or flame cut empty, uncleaned containers due to potential fire and explosion hazard. Consult product data sheet for proper application instructions. SECTION 8 - SAFE HANDLING AND USE INFORMATION HYGIENIC PRACTICES: Wash hands and other contaminated skin areas with warm soap and water before eating. EYE PROTECTION: Use chemical resistant splash type goggles. RESPIRATORY PROTECTION: Respiratory protective devices must be used when engineering and administration controls are not adequate to maintain Threshold Limit Values (TLV) and Permissible Exposure Limits (PEL) of airborne contaminants below the listed values for those hazardous. ingredients identified in Section II of this MSDS. Observe OSHA regulations for respirator use (CFR 29, 1910.134) whenever a respirator is used. Particulate, chemical cartridge, air purifying half -mask respirators can be used within certain limitations; consult the respirator manufacturer for specific uses and limitations. Where airborne contaminant concentrations are unknown, the use of a NIOSH/MSHA approved fresh -air supplied respirator is mandatory. OTHER PROTECTION: Use Chemical resistant gloves. Use chemical resistant coveralls or apron to protect against skin and clothing contamination. Use protective cream where skin contact is likely. VENTILATION: Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH's Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Heavier than air solvent vapors should be removed from lower levels of work area due to potential explosion hazard and all ignition sources (non -explosion proof equipment) should be eliminated if flammable mixtures will be encountered. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES LOWER HIGHER FORMULA WEIGHT VOC IN LBS PER EVAPORATION VAPOR PRESSURE VAPOR DENSITY BOILING RANGE BOILING RANGE BY VOLUME GALLON RATE 16.00 -N/A 237.0 °F 288.0 °F 10.6706 LB/GL 2.895 9.400 (Ether= 1) SECTION 10 - STABILITY AND REACTIVITY INCOMPATIBILITIES: Strong oxidizing agents. Acids. Bases. DECOMPOSITION: Carbon monoxide, carbon dioxide, hydrocarbon fragments Aldehydes. CONDITIONS TO AVOID: Heat, sparks, open flames. POLYMERIZATION: Will not occur. STABILITY: Stable. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Dispose of in accordance with Federal, state, and local regulations regarding pollution. SECTION 16 - HMIS INFORMATION Health: 2 Flammability: 3 Reactivity: 1 This is a condensed MSDS, providing safety and health Information pertinent to the complete product series. Physical constants such as VtR./Gal., VOC content and chemical constituents will vary with color. Safety and health information may also vary with color. Certain colors may contain Carbon Black and Crystalline Silica, which have been identified as reported or suspected carcinogens. Prolonged inhalation of respirable dusts containing Crystalline Silica may result in the development of a lung disease known as silicosis. For a complete, color -specific MSDS, please contact your local Tnemec representative listed at www.tnemec.com. For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. Al materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. %VOLATILE BY WEIGHT 42.010